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1. 发明申请

WO2017076956A1 A PROCESS FOR PREPARING FURAN-2,5-DICARBOXYLIC ACID 审中-公开
标题翻译：一种制备呋喃-2,5-二羧酸的方法
公开(公告)号：WO2017076956A1
公开(公告)日：2017-05-11
申请号：PCT/EP2016/076525
申请日：2016-11-03
申请人： BASF SE
发明人： GORDILLO, Alvaro , BOHN, Martin Alexander , SCHUNK, Stephan A. , JEVTOVIKJ, Ivana , WERHAN, Holger , DÜFERT, Svenia , PIEPENBRINK, Markus , BACKES, René , DEHN, Richard
IPC分类号： C07D307/68 , C07D307/46
CPC分类号： C07D307/68 , C07D307/46
摘要： The present invention relates to a process for preparing furan-2,5-dicarboxylic acid, the process comprising the following steps: (A-1) preparing or providing a starting mixture comprising one, two or more carbohydrate compounds selected from the group consisting of hexoses, oligosaccharides comprising hexose units, and polysaccharides comprising hexose units, and as the solvent or as a co-solvent for said carbohydrate compounds an amount of one or more carboxylic acid esters of formula (II) (A-2) subjecting said starting mixture to reaction conditions so that at least one of said one, two or more carbohydrate compounds reacts, and a fraction of said amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, so that a mixture results comprising 5-(hydroxymethyl)furfural and/or said one or more HMF esters of formula (I), one or more carboxylic acids of formula (III) and a remaining fraction of said amount of one or more carboxylic acid esters of formula (II).
摘要翻译：本发明涉及制备呋喃-2,5-二羧酸的方法，所述方法包括以下步骤：（A-1）制备或提供包含一种，两种或更多种选自己糖，包含己糖单元的寡糖和包含己糖单元的多糖的碳水化合物化合物，以及作为用于所述碳水化合物的溶剂或作为共溶剂的一定量的一种或多种式（II）的羧酸酯（ A-2）使所述起始混合物经历反应条件以使所述一种，两种或更多种碳水化合物中的至少一种起反应，并且将一部分所述量的式（II）的一种或多种羧酸酯水解，从而包含5-（羟甲基）糠醛和/或所述一种或多种式（I）的HMF酯，一种或多种式（III）的羧酸和所述量的一种或多种羧酸酯的剩余部分的混合物公式（I I）。

2. 发明申请

WO2016207025A1 VERFAHREN ZUM HERSTELLEN UND ABTRENNEN VON HMF 审中-公开
标题翻译：用于生产和分离HMF
公开(公告)号：WO2016207025A1
公开(公告)日：2016-12-29
申请号：PCT/EP2016/063613
申请日：2016-06-14
申请人： BASF SE
发明人： BLANK, Benoit , HOECKER, Johannes David , WERHAN, Holger , LANG, Ortmund , SON, Sunghee , PIEPENBRINK, Markus , BACKES, René , KINDLER, Alois
IPC分类号： C07D307/46
CPC分类号： C07D307/46
摘要： Beschrieben wird ein Verfahren umfassend das Herstellen einer Mischung umfassend 5-Hydroxymethylfurfural (HMF, Verbindung der Formel (I)) und das Abtrennen von 5-Hydroxymethylfurfural aus der hergestellten Mischung. Das erfindungsgemäße Verfahren umfasst die Schritte (A) Herstellen der Mischung umfassend eine oder mehrere ionische Flüssigkeiten und 5-Hydroxymethylfurfural in einer Menge von 5 bis 50 Gew.-% und (B) Abtrennen von 5-Hydroxymethylfurfural aus der in Schritt (A) hergestellten Mischung mittels Kurzwegverdampfung.
摘要翻译：描述了一种方法，其包括制备包含混合物5-羟甲基糠醛（HMF，式化合物（I））和5-羟甲基糠醛的从制备的混合物中分离。本发明的方法包括（A）制备的混合物中的步骤来制备，其包括一种或多种离子液体和5-羟甲基糠醛在的量为5至50重量％，和（B）从5-羟甲基糠醛分离在步骤（A）中通过快速蒸发的手段混合物。

3. 发明申请

WO2016206909A1 VERFAHREN ZUR HERSTELLUNG VON 5-HYDROXYMETHYLFURFURAL UND HUMINEN 审中-公开
标题翻译：用于生产5-羟甲基糠醛和腐殖物
公开(公告)号：WO2016206909A1
公开(公告)日：2016-12-29
申请号：PCT/EP2016/061971
申请日：2016-05-27
申请人： BASF SE
发明人： BLANK, Benoit , HOECKER, Johannes David , WERHAN, Holger , FRANK, Jürgen , KINDLER, Alois , PIEPENBRINK, Markus , BACKES, René , STAAL, Bastiaan Bram Pieter
IPC分类号： C07D307/46 , B01J19/24
CPC分类号： C07D307/46 , B01J19/245
摘要： Die vorliegende Erfindung betrifft ein Verfahren zur Herstellungvon 5-Hydroxymethylfurfural (nachfolgend auch als „HMF" bezeichnet, Verbindung der Formel (I)) und Huminenumfassend Schritte (a), (b), (c), (d), (e) und (f) (vgl. Figur 1 und den beigefügten Anspruch 1). Die vorliegende Erfindung betrifft zudem eine Anlage zur Durchführung des beschriebenen Verfahrens, sowie die Verwendung der beschriebenen Anlage zur Durchführung des beschriebenen Verfahrens.
摘要翻译：本发明涉及一种制备5-羟甲基糠醛（以下，也称为 “HMF” 是指式（I）的化合物）和Huminenumfassend步骤（a），（B），（C），（D），（e）和（F）（参见图1和所附权利要求1）。本发明还涉及用于执行所描述的方法，以及用于执行所描述的方法中的用途描述植物的植物。

4. 发明申请

WO2021032519A1 METHOD FOR PURIFICATION OF ISOSORBIDE 审中-公开
公开(公告)号：WO2021032519A1
公开(公告)日：2021-02-25
申请号：PCT/EP2020/072356
申请日：2020-08-10
申请人： BASF SE
发明人： RUETHER, Feelly , BACKES, Rene , STOER, Claudia , DUEFERT, Svenia , WERHAN, Holger , MADER, Steffen , KUEHNE, Benjamin, Bernhard
IPC分类号： C07D493/04
摘要： The invention relates to a process for purifying a crude isosorbide, in which the crude isosorbide is melted and converted, by cooling, into a crude isosorbide melt suspension consisting of isosorbide crystals and residual melt, the amount by weight of impurities in the isosorbide crystals being less than the amount by weight of impurities in the residual melt, optionally a part of the residual melt is separated off mechanically from the crude isosorbide suspension, further the isosorbide crystals in the melt isosorbide suspension are purified from residual melt by washing with a washing isosorbide melt, the amount by weight of impurities in the washing isosorbide melt being less than the amount by weight of impurities in the residual melt.

5. 发明申请

WO2017076947A1 PROCESS FOR PREPARING FURAN-2,5-DICARBOXYLIC ACID 审中-公开
标题翻译：制备呋喃-2,5-二羧酸的方法
公开(公告)号：WO2017076947A1
公开(公告)日：2017-05-11
申请号：PCT/EP2016/076510
申请日：2016-11-03
申请人： BASF SE
发明人： DEHN, Richard , WERHAN, Holger , DÜFERT, Svenia , BACKES, René , GORDILLO, Alvaro
IPC分类号： C07D307/68
CPC分类号： C07D307/68
摘要： The invention relates to a process for preparing furan-2,5-dicarboxylic acid comprising the following steps: (a) preparing or providing a starting material mixture comprising 5-(hydroxymethyl)furfural (HMF) as a first reactant and one or more second reactants selected from the group consisting of esters of 5-(hydroxymethyl)furfural and ethers of 5-(hydroxymethyl)furfural, (b) subjecting said starting material mixture to first oxidation conditions at a temperature in the range TR1 of from 110 to 140 °C so that an amount of said 5-(hydroxymethyl)furfural (HMF) present in the starting material mixture is oxidised to furan-2,5-dicarboxylic acid and a first product mixture results comprising furan-2,5-dicarboxylic acid and an unreacted amount of said one or more second reactants, and (c) subjecting the first product mixture obtained in step (b) or a mixture obtained from the first product mixture obtained in step (b) by additional treatment steps to second oxidation conditions at an increased temperature in the range TR2 of from above 140 to 200 °C so that said at least a fraction of said unreacted amount of said one or more second reactants present in the first product mixture is oxidised and a second product mixture results comprising furan-2,5-dicarboxylic acid.
摘要翻译：本发明涉及一种制备呋喃-2,5-二羧酸的方法，其包括以下步骤：（a）制备或提供包含5-（羟甲基）糠醛（HMF）的原料混合物，其为第一反应物和一种或多种选自5-（羟甲基）糠醛的酯和5-（羟甲基）糠醛的醚的第二反应物，（b）使所述起始原料混合物在第范围TR1为110-140℃，使得存在于原料混合物中的所述5-（羟甲基）糠醛（HMF）的量被氧化成呋喃-2,5-二羧酸，并且得到包含呋喃的第一产物混合物（c）将步骤（b）中获得的第一产物混合物或步骤（b）中获得的第一产物混合物获得的混合物用对第二氧化条件的附加处理步骤离子在高于140-200℃的范围TR2的升高温度下反应，使得存在于第一产物混合物中的所述至少一部分所述未反应量的所述一种或多种第二反应物被氧化，并且第二产物混合物得到包含呋喃-2,5-二羧酸。

6. 发明申请

WO2017076942A1 A PROCESS FOR PREPARING A MIXTURE COMPRISING 5-(HYDROXYMETHYL)FURFURAL AND SPECIFIC HMF ESTERS 审中-公开
标题翻译：制备包含5-（羟甲基）糠醛和特定HMF酯的混合物的方法
公开(公告)号：WO2017076942A1
公开(公告)日：2017-05-11
申请号：PCT/EP2016/076499
申请日：2016-11-03
申请人： BASF SE
发明人： GORDILLO, Alvaro , BOHN, Martin Alexander , SCHUNK, Stephan A. , JEVTOVIKJ, Ivana , WERHAN, Holger , DÜFERT, Svenia , PIEPENBRINK, Markus , BACKES, René , DEHN, Richard
IPC分类号： C07D307/46
CPC分类号： C07D307/46
摘要： The present invention relates to a process for preparing a mixture comprising 5-(hydroxy- methyl)furfural (HMF) and one or more HMF esters of formula (I, the process comprising the following steps: (A-1) preparing or providing a starting mixture comprising one, two or more carbohydrate compounds selected from the group consisting of hexoses, oligosaccharides comprising hexose units, and polysaccharides comprising hexose units, and as the solvent or as a co-solvent for said carbohydrate compounds an amount of one or more carboxylic acid esters of formula (II) (A-2) subjecting said starting mixture to reaction conditions so that at least one of said one, two or more carbohydrate compounds reacts, and a fraction of said amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, so that a mixture results comprising 5-(hydroxymethyl)furfural and/or said one or more HMF esters of formula (I), one or more carboxylic acids of formula (III) and a remaining fraction of said amount of one or more carboxylic acid esters of formula (II) wherein the starting mixture prepared or provided in step (A-1) comprises a total amount of carboxylic acid esters of formula (II) of at least 50 wt.-%, based on the total weight of the starting mixture.
摘要翻译：本发明涉及制备包含5-（羟基 - 甲基）糠醛（HMF）和一种或多种式（I）的HMF酯的混合物的方法，所述方法包括以下步骤:( A-1）制备或提供包含一种，两种或更多种选自己糖，包含己糖单元的寡糖和包含己糖单元的多糖的碳水化合物的起始混合物，以及作为所述碳水化合物的溶剂或共溶剂使一定量的一种或多种式（II）的羧酸酯（A-2）与所述起始混合物接触反应条件，使得所述一种，两种或更多种碳水化合物中的至少一种起反应，并且所述量的一部分将一种或多种式（II）的羧酸酯水解，从而得到包含5-（羟甲基）糠醛和/或所述一种或多种式（I）的HMF酯，一种或多种式（III））和剩余分数 n所述量的一种或多种式（II）的羧酸酯，其中在步骤（A-1）中制备或提供的起始混合物包含总量为式（II）的羧酸酯的至少50重量％％，基于起始混合物的总重量。

7. 发明申请

WO2017012842A1 PROCESS FOR PREPARING FURAN-2,5-DICARBOXYLIC ACID 审中-公开
标题翻译：制备FURAN-2,5-DICARBOXYLIC酸的方法
公开(公告)号：WO2017012842A1
公开(公告)日：2017-01-26
申请号：PCT/EP2016/065494
申请日：2016-07-01
申请人： BASF SE
发明人： GORDILLO, Alvaro , WERHAN, Holger , DEHN, Richard , BLANK, Benoit , TELES, Joaquim Henrique , SCHUNK, Stephan , PIEPENBRINK, Markus , BACKES, René , ZHANG, Lei
IPC分类号： C07D307/46
CPC分类号： C07D307/46
摘要： The present invention relates to a process forpreparingfuran-2,5-dicarboxylic acid, comprising the following steps: preparing or providing a starting mixture comprising5-(hydroxymethyl)furfural (HMF),5,5'-[oxy-bis(methylene)]bis-2-furfural (di-HMF), and water,subjecting said starting mixture to oxidation conditions in the presence of an oxygen-containing gas and a catalytically effective amount of a heterogeneous catalyst comprising one or more noble metals on a support so that both HMF and di-HMF react to give furane-2,5-dicarboxylic acid in a product mixture also comprising water and oxidation by-products. Moreover the present invention relates to the use of a catalyst comprising one or more noble metals on a support as an heterogeneous oxidation catalyst for catalyzing in an aqueous starting mixture the reaction of both HMF and di-HMF to furane-2,5-dicarboxylic acid.
摘要翻译：本发明涉及一种制备呋喃-2,5-二羧酸的方法，包括以下步骤：制备或提供起始混合物，其包含5-（羟甲基）糠醛（HMF），5,5' - [氧 - 双（亚甲基）] 二 - 糠醛（二-HMF）和水，在含氧气体和催化有效量的包含一种或多种贵金属的非均相催化剂的存在下在载体上使所述起始混合物经受氧化条件，使得 HMF和二-HFF都可以在还含有水和氧化副产物的产物混合物中反应得到呋喃-2,5-二羧酸。此外，本发明涉及包含一种或多种贵金属的催化剂在载体上作为非均相氧化催化剂在水性起始混合物中催化的用途，HMF和二HMF两者与呋喃-2,5-二羧酸的反应。

8. 发明申请

WO2015197699A1 PROCESS FOR PREPARING FURAN-2,5-DICARBOXYLIC ACID 审中-公开
标题翻译：制备FURAN-2,5-DICARBOXYLIC酸的方法
公开(公告)号：WO2015197699A1
公开(公告)日：2015-12-30
申请号：PCT/EP2015/064265
申请日：2015-06-24
申请人： BASF SE
发明人： BLANK, Benoit , GORDILLO, Alvaro , BOHN, Martin Alexander , KINDLER, Alois , SCHUNK, Stephan A. , ZHANG, Lei , FUTTER, Cornelia , DEHN, Richard , WERHAN, Holger , TELES, Joaquim Henrique , PIEPENBRINK, Markus , BACKES, René
IPC分类号： C07D307/68
CPC分类号： C07D307/68
摘要： The present invention relates to a process of making furan-2,5-dicarboxylic acid, comprising the following steps: (a) subjecting a starting mixture comprising 5-(hydroxymethyl)furfural and water to oxidation conditions in the presence of a heterogeneous oxidation catalyst and an oxygen-containing gas so that a first product mixture results comprising furan-2,5-dicarboxylic acid, water and by-products, (b) subjecting a mixture comprising water, said furan-2,5-dicarboxylic acid and said by-products to hydrogenation conditions in the presence of a heterogeneous hydrogenation catalyst so that a second product mixture results comprising furan-2,5-dicarboxylic acid, water and hydrogenated by-products, and subsequently (c) separating said furan-2,5-dicarboxylic acid from said hydrogenated by-products so that isolated furan-2,5-dicarboxylic acid results, wherein said first product mixture resulting from step (a) is heated and/or diluted with water to give said mixture subjected to hydrogenation conditions in step (b).
摘要翻译：本发明涉及一种制备呋喃-2,5-二羧酸的方法，包括以下步骤：（a）在异相氧化催化剂存在下使包含5-（羟甲基）糠醛和水的起始混合物经历氧化条件和含氧气体，使得第一产物混合物产生包含呋喃-2,5-二羧酸，水和副产物，（b）将包含水，所述呋喃-2,5-二羧酸和所述呋喃-2,5-二羧酸的混合物 - 在异相氢化催化剂存在下产生氢化条件，使得第二产物混合物产生包含呋喃-2,5-二羧酸，水和氢化副产物，随后（c）分离所述呋喃-2,5-二羧酸，二羧酸，从而得到分离的呋喃-2,5-二羧酸，其中由步骤（a）得到的所述第一产物混合物用水加热和/或稀释，得到所述混合物经受氢气在步骤（b）中的n条件。

9. 发明公开

EP3371161A1 A PROCESS FOR PREPARING FURAN-2,5-DICARBOXYLIC ACID 审中-公开
公开(公告)号：EP3371161A1
公开(公告)日：2018-09-12
申请号：EP16790374.9
申请日：2016-11-03
申请人： BASF SE
发明人： GORDILLO, Alvaro , BOHN, Martin Alexander , SCHUNK, Stephan A. , JEVTOVIKJ, Ivana , WERHAN, Holger , DÜFERT, Svenia , PIEPENBRINK, Markus , BACKES, René , DEHN, Richard
IPC分类号： C07D307/68 , C07D307/46
CPC分类号： C07D307/46 , C07D307/68
摘要： Provided herein is a process for preparing furan-2,5-dicarboxylic acid. The process includes the following steps: (A-1) preparing a starting mixture comprising one, two or more carbohydrate compounds selected from the group consisting of: hexoses, oligosaccharides comprising hexose units, and polysaccharides including hexose units, and as a solvent or as a co-solvent for the carbohydrate compounds an amount of one or more carboxylic acid esters of a formula (II) and (A-2) subjecting the starting mixture to reaction conditions so that at least one of the one, two or more carbohydrate compounds reacts, and a fraction of the amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, resulting in a mixture including 5-(hydroxymethyl)furfural and/or the one or more HMF esters of a formula (I), one or more carboxylic acids of a formula (III) and a remaining fraction of the amount of one or more carboxylic acid esters of formula (II).

10. 发明公开

EP3371158A1 A PROCESS FOR PREPARING A MIXTURE COMPRISING 5-(HYDROXYMETHYL)FURFURAL AND SPECIFIC HMF ESTERS 审中-公开
公开(公告)号：EP3371158A1
公开(公告)日：2018-09-12
申请号：EP16791378.9
申请日：2016-11-03
申请人： BASF SE
发明人： GORDILLO, Alvaro , BOHN, Martin Alexander , SCHUNK, Stephan A. , JEVTOVIKJ, Ivana , WERHAN, Holger , DÜFERT, Svenia , PIEPENBRINK, Markus , BACKES, René , DEHN, Richard
IPC分类号： C07D307/46
CPC分类号： C07D307/50 , C07D307/46
摘要： Provided herein is a process for preparing a mixture including 5-(hydroxy-methyl)furfural (HMF) and one or more HMF esters of formula (I), the process including the following steps: (A-1) preparing or providing a starting mixture which includes one, two or more carbohydrate compounds and as the solvent or as a co-solvent for the carbohydrate compounds an amount of one or more carboxylic acid esters of formula (II); (A-2) subjecting the starting mixture to reaction conditions so that at least one of the one, two or more carbohydrate compounds reacts, and a fraction of the amount of one or more carboxylic acid esters of formula (II) is hydrolyzed, so that a mixture results that includes 5-(hydroxy-methyl)furfural and/or the one or more HMF esters of formula (I), one or more carboxylic acids of formula (III) and a remaining fraction of the amount of one or more carboxylic acid esters of formula (II).

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