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    • 1. 发明申请
    • Polymer Electrolyte Fuel Cell
    • 聚合物电解质燃料电池
    • US20070298304A1
    • 2007-12-27
    • US11791679
    • 2005-11-01
    • Atsushi OhmaShinji Yamamoto
    • Atsushi OhmaShinji Yamamoto
    • H01M8/10
    • H01M4/92H01M4/8835H01M4/921H01M4/926H01M8/04223H01M8/1004H01M8/241H01M8/2457
    • For a combination of a solid polymer electrolyte membrane 107, catalytic layers 111 and 113 disposed on both sides of the solid polymer electrolyte membrane 107, gas diffusion layers 112 and 114 disposed outside the catalytic layers 111 and 113, and separators 103 and 104 disposed outside the gas diffusion layers 112 and 114, the catalytic layer 113 to be cathode-sided includes a carbon carrier 117 composed of carbon having a mean lattice plane spacing d002 of [002] planes calculated from an X-ray diffraction within a range of 0.343 nm to 0.358 nm, a crystallite size Lc within a range of 3 nm to 10 nm, and a specific surface area within a range of 200 m2/g to 300 m2/g, catalyst particlers 115 containing platinum supported on the carbon carrier 117, and an electrolyte 116. According to the invention, a polymer electrolyte fuel cell is allowed to prevent a corroding deterioration of carbon carriers in the cathode catalytic layer in start and stop of the fuel cell, allowing for an enhanced stable output over a long term.
    • 对于固体高分子电解质膜107,设置在固体高分子电解质膜107两侧的催化剂层111和113,设置在催化剂层111和113外部的气体扩散层112和114以及设置在外部的隔板103和104的组合 气体扩散层112和114,作为阴极侧的催化剂层113包括由X表示的由002表示的平均晶格面间隔d 002的碳载体117, 在0.343nm至0.358nm的范围内的光线衍射,在3nm至10nm的范围内的微晶尺寸Lc,在200m 2 / g至300μm的范围内的比表面积 含有负载在碳载体117上的铂的催化剂分散器115和电解质116.根据本发明,允许固体高分子型燃料电池防止碳载体上的碳载体的腐蚀劣化 阴极催化层起始和停止f 能够长期保持稳定的输出。
    • 2. 发明授权
    • Polymer electrolyte fuel cell
    • 聚合物电解质燃料电池
    • US07901836B2
    • 2011-03-08
    • US11791679
    • 2005-11-01
    • Atsushi OhmaShinji Yamamoto
    • Atsushi OhmaShinji Yamamoto
    • H01M4/02
    • H01M4/92H01M4/8835H01M4/921H01M4/926H01M8/04223H01M8/1004H01M8/241H01M8/2457
    • For a combination of a solid polymer electrolyte membrane 107, catalytic layers 111 and 113 disposed on both sides of the solid polymer electrolyte membrane 107, gas diffusion layers 112 and 114 disposed outside the catalytic layers 111 and 113, and separators 103 and 104 disposed outside the gas diffusion layers 112 and 114, the catalytic layer 113 to be cathode-sided includes a carbon carrier 117 composed of carbon having a mean lattice plane spacing d002 of [002] planes calculated from an X-ray diffraction within a range of 0.343 nm to 0.358 nm, a crystallite size Lc within a range of 3 nm to 10 nm, and a specific surface area within a range of 200 m2/g to 300 m2/g, catalyst particles 115 containing platinum supported on the carbon carrier 117, and an electrolyte 116. According to the invention, a polymer electrolyte fuel cell is allowed to prevent a corroding deterioration of carbon carriers in the cathode catalytic layer in start and stop of the fuel cell, allowing for an enhanced stable output over a long term.
    • 对于固体高分子电解质膜107,设置在固体高分子电解质膜107两侧的催化剂层111和113,设置在催化剂层111和113外部的气体扩散层112和114以及设置在外部的隔板103和104的组合 气体扩散层112和114,作为阴极侧的催化剂层113包括碳载体117,其由具有由0.333nm范围内的X射线衍射计算出的[002]面的平均晶格面间距d002的碳构成 至0.358nm,在3nm至10nm的范围内的微晶尺寸Lc,200m 2 / g至300m 2 / g范围内的比表面积,载于碳载体117上的载有铂的催化剂颗粒115,以及 电解质116.根据本发明,允许聚合物电解质燃料电池防止燃料电池开始和停止时阴极催化剂层中碳载体的腐蚀变坏,从而增强 长期稳定的产量。
    • 3. 发明授权
    • Polymer electrolyte fuel cell
    • 聚合物电解质燃料电池
    • US08329359B2
    • 2012-12-11
    • US13020998
    • 2011-02-04
    • Atsushi OhmaShinji Yamamoto
    • Atsushi OhmaShinji Yamamoto
    • H01M4/02
    • H01M4/92H01M4/8835H01M4/921H01M4/926H01M8/04223H01M8/1004H01M8/241H01M8/2457
    • For a combination of a solid polymer electrolyte membrane 107, catalytic layers 111 and 113 disposed on both sides of the solid polymer electrolyte membrane 107, gas diffusion layers 112 and 114 disposed outside the catalytic layers 111 and 113, and separators 103 and 104 disposed outside the gas diffusion layers 112 and 114, the catalytic layer 113 to be cathode-sided includes a carbon carrier 117 composed of carbon having a mean lattice plane spacing d002 of [002] planes calculated from an X-ray diffraction within a range of 0.343 nm to 0.358 nm, a crystallite size Lc within a range of 3 nm to 10 nm, and a specific surface area within a range of 200 m2/g to 300 m2/g, catalyst particles 115 containing platinum supported on the carbon carrier 117, and an electrolyte 116. According to the invention, a polymer electrolyte fuel cell is allowed to prevent a corroding deterioration of carbon carriers in the cathode catalytic layer in start and stop of the fuel cell, allowing for an enhanced stable output over a long term.
    • 对于固体高分子电解质膜107,设置在固体高分子电解质膜107两侧的催化剂层111和113,设置在催化剂层111和113外部的气体扩散层112和114以及设置在外部的隔板103和104的组合 气体扩散层112和114,作为阴极侧的催化剂层113包括碳载体117,其由具有由0.333nm范围内的X射线衍射计算出的[002]面的平均晶格面间距d002的碳构成 至0.358nm,在3nm至10nm的范围内的微晶尺寸Lc,200m 2 / g至300m 2 / g范围内的比表面积,载于碳载体117上的载有铂的催化剂颗粒115,以及 电解质116.根据本发明,允许聚合物电解质燃料电池防止燃料电池开始和停止时阴极催化剂层中碳载体的腐蚀变坏,从而增强 长期稳定的产量。
    • 6. 发明授权
    • Electrolyte membrane-electrode assembly and production method thereof
    • 电解质膜电极组件及其制造方法
    • US08026018B2
    • 2011-09-27
    • US12064989
    • 2006-08-17
    • Atsushi OhmaYozo OkuyamaYasuhiro Numao
    • Atsushi OhmaYozo OkuyamaYasuhiro Numao
    • H01M2/08H01M4/86B32B37/12
    • H01M8/0286H01M4/881H01M8/0273H01M8/0284H01M2008/1095Y02P70/56Y10T156/10
    • An electrolyte membrane-electrode assembly of the present invention includes: an electrolyte membrane; an anode-side electrode including an anode-side catalyst layer disposed on one side of the electrolyte membrane and an anode-side gas diffusion layer formed on the anode-side catalyst layer beyond a surface-direction end of the anode-side catalyst layer; an anode-side adhesive layer disposed on at least a part of a periphery of the anode-side catalyst layer; and an anode-side gasket layer disposed in contact with the anode-side adhesive layer, wherein a surface-direction inner end of the anode-side adhesive lay is located inside beyond a surface-direction inner end of the anode-side gasket layer, and a part of the anode-side adhesive layer is located to overlap with a part of the anode-side gas diffusion layer with respect to a thickness direction. Further, on the other side of the electrolyte membrane, cathode-side respective layers having the same constructions as above are disposed.
    • 本发明的电解质膜 - 电极组件包括:电解质膜; 阳极侧电极,其包括设置在所述电解质膜的一侧的阳极侧催化剂层和在所述阳极侧催化剂层上形成的阳极侧气体扩散层,超过所述阳极侧催化剂层的表面方向端; 设置在所述阳极侧催化剂层的周围的至少一部分上的阳极侧粘合剂层; 阳极侧粘合剂层的表面方向内端位于阳极侧垫片层的表面方向内侧的内侧, 并且阳极侧粘合剂层的一部分位于与阳极侧气体扩散层的一部分相对于厚度方向重叠。 此外,在电解质膜的另一侧,设置具有与上述相同结构的阴极侧各自的层。