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1. 发明授权

US06537500B1 Process for the detection of a product in the discharge of a catalytic material of a plurality of catalytic materials 失效
标题翻译：用于在多种催化材料的催化材料的排出中检测产品的方法
公开(公告)号：US06537500B1
公开(公告)日：2003-03-25
申请号：US09350459
申请日：1999-07-09
申请人： Armin Brenner , Armin Lange de Oliveira , Ferdi Schuth , Stephan Schunk , Wolfram Stichert , Klaus Unger
发明人： Armin Brenner , Armin Lange de Oliveira , Ferdi Schuth , Stephan Schunk , Wolfram Stichert , Klaus Unger
IPC分类号： G01N3096
CPC分类号： G01N21/17 , B01J19/0046 , B01J2219/00286 , B01J2219/00313 , B01J2219/00333 , B01J2219/00423 , B01J2219/00495 , B01J2219/00585 , B01J2219/0059 , B01J2219/00704 , B01J2219/00745 , B01J2219/00747 , C40B30/08 , C40B40/18 , Y10T436/255 , Y10T436/25875
摘要： Process for the detection of a product in the discharge of a catalytic material of a plurality of catalytic materials which are exposed to a reaction gas, whereby an adsorbent selective for the product to be determined is disposed in the discharge of each catalytic material, which changes at least one of its properties through the contact with the product to be determined and the change in the property of the adsorbent is then ascertained. The process serves in particular to determine the selectivity and activity of catalytic materials.
摘要翻译：用于检测在暴露于反应气体中的多种催化材料的催化材料的排出中的产物的检测方法，由此在每种催化材料的排出中设置对待测产物有选择性的吸附剂，然后确定通过与要测定的产物的接触和吸附剂的性质变化的其性质中的至少一种。该方法尤其用于确定催化材料的选择性和活性。

2. 发明授权

US08691181B2 Method for producing synthesis gas 有权
标题翻译：合成气的制造方法
公开(公告)号：US08691181B2
公开(公告)日：2014-04-08
申请号：US12599748
申请日：2008-05-09
申请人： Stephan Schunk , Armin Lange De Oliveira
发明人： Stephan Schunk , Armin Lange De Oliveira
IPC分类号： C01B3/24 , C01B3/38
CPC分类号： C01B3/46 , C01B2203/0233 , C01B2203/0238 , C01B2203/0261 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/0844 , C01B2203/86 , Y02P20/133 , Y02P20/134 , Y02P30/30
摘要： A process for preparing and converting synthesis gas, which has a plurality of different operating states which consist essentially of mutually alternating (i) daytime operation and (ii) nighttime operation, daytime operation (i) comprising principally dry reforming and steam reforming with supply of renewable energy, and nighttime operation (ii) comprising principally the partial oxidation of hydrocarbons, and the synthesis gas produced being used to produce products of value.
摘要翻译：一种用于制备和转化合成气的方法，其具有多个不同的运行状态，其基本上由相互交替的（i）白天操作和（ii）夜间操作，白天操作（i）组成，主要包括干重整和蒸汽重整，可再生能源和夜间操作（ii）主要包括烃的部分氧化，以及所生产的合成气用于产生有价值的产品。

3. 发明申请

US20100305221A1 METHOD FOR PRODUCING SYNTHESIS GAS 有权
标题翻译：生产合成气的方法
公开(公告)号：US20100305221A1
公开(公告)日：2010-12-02
申请号：US12599748
申请日：2008-05-09
申请人： Stephan Schunk , Armin Lange De Oliveira
发明人： Stephan Schunk , Armin Lange De Oliveira
IPC分类号： C07C27/00
CPC分类号： C01B3/46 , C01B2203/0233 , C01B2203/0238 , C01B2203/0261 , C01B2203/06 , C01B2203/061 , C01B2203/062 , C01B2203/0844 , C01B2203/86 , Y02P20/133 , Y02P20/134 , Y02P30/30
摘要： A process for preparing and converting synthesis gas, which has a plurality of different operating states which consist essentially of mutually alternating (i) daytime operation and (ii) nighttime operation, daytime operation (i) comprising principally dry reforming and steam reforming with supply of renewable energy, and nighttime operation (ii) comprising principally the partial oxidation of hydrocarbons, and the synthesis gas produced being used to produce products of value.
摘要翻译：一种用于制备和转化合成气的方法，其具有多个不同的运行状态，其基本上由相互交替的（i）白天操作和（ii）夜间操作，白天操作（i）组成，主要包括干重整和蒸汽重整，可再生能源和夜间操作（ii）主要包括烃的部分氧化，以及所生产的合成气用于产生有价值的产品。

4. 发明申请

US20050143934A1 Method and device for the continuous testing of materials 审中-公开
标题翻译：用于连续测试材料的方法和装置
公开(公告)号：US20050143934A1
公开(公告)日：2005-06-30
申请号：US10497435
申请日：2002-11-15
申请人： Stephan Schunk , Torsten Zech , Alexander Cross , Uwe Vietze , Jens Klein , Andreas Sundermann , Wolfram Stichert
发明人： Stephan Schunk , Torsten Zech , Alexander Cross , Uwe Vietze , Jens Klein , Andreas Sundermann , Wolfram Stichert
IPC分类号： B01J19/00 , C40B30/08 , C40B40/18 , C40B60/14 , G06F19/00
CPC分类号： B01J19/0046 , B01J2219/00317 , B01J2219/00326 , B01J2219/00328 , B01J2219/00416 , B01J2219/00418 , B01J2219/00459 , B01J2219/00461 , B01J2219/00468 , B01J2219/00495 , B01J2219/005 , B01J2219/00502 , B01J2219/00587 , B01J2219/0059 , B01J2219/00689 , B01J2219/00693 , B01J2219/00695 , B01J2219/00702 , B01J2219/00745 , B01J2219/00747 , C40B30/08 , C40B40/18 , C40B60/14
摘要： The present invention relates to a method for testing building blocks, which are identical or different, of a library of materials, comprising at least two building blocks, for performance characteristics, comprising a sequence of the following steps: 4) testing of at least one library building block for at least one performance characteristic; 5) detecting at least one measurable quantity, to which at least one performance characteristic of the at least one library building block can be assigned by at least one sensor, wherein at least one of the steps (4) and (5) is performed continuously.
摘要翻译：本发明涉及一种用于测试构件块的方法，该构件相同或不同，包括至少两个构件，用于性能特征，包括以下步骤的顺序：4）至少测试一个图书馆建筑块至少有一个性能特征; 5）检测至少一个可测量的量，所述至少一个文库构建块的至少一个性能特征可以由至少一个传感器分配给至少一个可测量量，其中步骤（4）和（5）中的至少一个被连续地执行。

5. 发明申请

US20060116523A1 Silver-containing catalysts for the reaction of substrates with c-c-double bonds 审中-公开
标题翻译：含有底物与c-c-双键反应的含银催化剂
公开(公告)号：US20060116523A1
公开(公告)日：2006-06-01
申请号：US10541561
申请日：2004-01-09
申请人： Wolfram Stichert , Jens Klein , Stephan Schunk , Dirk Demuth , Andreas Sundermann , Ewald Gallei , Harmut Hibst , Sebastian Storck
发明人： Wolfram Stichert , Jens Klein , Stephan Schunk , Dirk Demuth , Andreas Sundermann , Ewald Gallei , Harmut Hibst , Sebastian Storck
IPC分类号： C07D301/10 , B01J23/50 , B01J23/48
CPC分类号： B01J23/66 , B01J21/04 , B01J23/50 , B01J37/0203 , B01J37/16 , C07D301/10 , C07D303/04
摘要： The present invention relates to a silver-containing catalyst system, which can be applied for the reaction of substrates with at least one C—C-double bond with at least one oxygen-containing or oxygen-supplying component with formation of at least one epoxide. The silver-containing catalyst according to the invention is characterized in that its activity as well as its selectivity is significantly increased with respect to the target product compared with the silver-containing catalysts of the state of the art, as a consequence of the process for the manufacture according to the invention, in which the synthesis of a silver-amine complex is carried out in absence of light and at temperatures below room temperature.
摘要翻译：本发明涉及一种含银催化剂体系，其可以应用于具有至少一个C-C-双键的底物与至少一种含氧或供氧组分的反应，形成至少一种环氧化物。根据本发明的含银催化剂的特征在于，与现有技术的含银催化剂相比，其活性及其选择性相对于目标产物显着增加，这是由于根据本发明的制造，其中银 - 胺络合物的合成在不存在光和低于室温的温度下进行。

6. 发明授权

US08916491B2 Process for producing a methanation catalyst and a process for the methanation of synthesis gas 有权
标题翻译：用于生产甲烷化催化剂的方法和合成气的甲烷化方法
公开(公告)号：US08916491B2
公开(公告)日：2014-12-23
申请号：US13670815
申请日：2012-11-07
申请人： Claudia Querner , Andrian Milanov , Stephan Schunk , Andreas Strasser , Guido Wasserschaff , Thomas Roussiere
发明人： Claudia Querner , Andrian Milanov , Stephan Schunk , Andreas Strasser , Guido Wasserschaff , Thomas Roussiere
IPC分类号： B01J21/10 , B01J23/02 , B01J23/78 , B01J37/04 , B01J37/08 , B01J37/14 , B01J23/755 , C10L3/06 , C10L3/08 , C07C1/04 , C07C1/12 , B01J35/00 , B01J35/10 , B01J23/00 , B01J37/00 , B01J37/02 , B01J35/02 , B01J27/236
CPC分类号： B01J21/10 , B01J23/005 , B01J23/02 , B01J23/755 , B01J23/78 , B01J27/236 , B01J35/0006 , B01J35/002 , B01J35/006 , B01J35/023 , B01J35/1014 , B01J35/1038 , B01J35/1061 , B01J35/1085 , B01J35/109 , B01J37/0009 , B01J37/0036 , B01J37/0201 , B01J37/04 , B01J37/08 , B01J37/14 , C07C1/04 , C07C1/12 , C10L3/06 , C10L3/08
摘要： The present invention relates to a process for producing a catalyst for carrying out methanation reactions. The production of the catalyst is based on contacting of a hydrotalcite-comprising starting material with a fusible metal salt. The compounds brought into contact with one another are intimately mixed, thermally treated so that the metal salt fraction melts and subsequently subjected to a low-temperature calcination step and a high-temperature calcination step. The metal salt melt comprises at least one metal selected from the group consisting of K, La, Fe, Co, Ni, Cu and Ce, preferably Ni. The metal salt melt more preferably comprises/contains nickel nitrate hexahydrate. The hydrotalcite-comprising starting material is preferably hydrotalcite or a hydrotalcite-like compound as starting material, and the hydrotalcite-comprising starting material preferably comprises magnesium and aluminum as metal species.The catalyst of the invention is preferably used for carrying out methanation reactions at elevated pressures (from 10 to 50 bar) and elevated temperatures.
摘要翻译：本发明涉及一种用于进行甲烷化反应的催化剂的制备方法。催化剂的生产基于含水滑石的原料与可熔金属盐的接触。使彼此接触的化合物紧密混合，热处理，使金属盐部分熔融，随后进行低温煅烧步骤和高温煅烧步骤。金属盐熔体包含选自K，La，Fe，Co，Ni，Cu和Ce中的至少一种金属，优选为Ni。金属盐熔体更优选包含/含有硝酸镍六水合物。含水滑石的起始原料优选为水滑石或类水滑石化合物作为起始原料，含水滑石的原料优选包含镁和铝作为金属物质。本发明的催化剂优选用于在升高的压力（10至50巴）和升高的温度下进行甲烷化反应。

7. 发明申请

US20130116116A1 PROCESS FOR PRODUCING A REFORMING CATALYST AND THE REFORMING OF METHANE 有权
标题翻译：生产改性催化剂的方法和甲烷的改性
公开(公告)号：US20130116116A1
公开(公告)日：2013-05-09
申请号：US13671159
申请日：2012-11-07
申请人： Ekkehard SCHWAB , Andrian Milanov , Stephan Schunk , Thomas Roussiere , Guido Wasserschaff , Andreas Strasser
发明人： Ekkehard SCHWAB , Andrian Milanov , Stephan Schunk , Thomas Roussiere , Guido Wasserschaff , Andreas Strasser
IPC分类号： B01J23/755 , B01J21/10 , C01B3/26 , B01J23/75
CPC分类号： B01J23/78 , B01J23/005 , B01J35/0013 , B01J35/002 , B01J35/0026 , B01J35/006 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1061 , B01J35/1066 , B01J35/1071 , B01J35/109 , B01J35/1095 , B01J37/0009 , B01J37/0201 , B01J37/08 , C01B3/40 , C01B2203/0233 , C01B2203/0238 , C01B2203/1058 , Y02P20/142 , Y02P20/52
摘要： The present invention relates to a process for producing a catalyst for the reforming of hydrocarbons, preferably methane, in the presence of CO2, water and/or hydrogen. The production of the catalyst is based on contacting of a hydrotalcite-comprising starting material with a fusible metal salt. The compounds which have been brought into contact with one another are intimately mixed and treated thermally, resulting in the fusible metal salt forming a melt. After molding, the material is subjected to a high-temperature calcination step. The metal salt melt comprises at least one metal selected from the group consisting of K, La, Fe, Co, Ni, Cu and Ce, preferably Ni. The metal salt melt more preferably comprises nickel nitrate hexahydrate. In addition, the invention relates to the use of the catalyst of the invention for the reforming of hydrocarbons, preferably methane, in the presence of CO2, water and/or hydrogen at elevated pressures which are greater than 5 bar, preferably greater than 10 bar, particularly preferably greater than 20 bar. The catalyst according to the invention is distinguished from the prior art by particular, preferred physicochemical properties.
摘要翻译：本发明涉及用于在CO 2，水和/或氢气存在下重整烃，优选甲烷的催化剂的方法。催化剂的生产基于含水滑石的原料与可熔金属盐的接触。已经彼此接触的化合物被充分混合并热处理，导致易熔金属盐形成熔体。在成型之后，对材料进行高温煅烧步骤。金属盐熔体包含选自K，La，Fe，Co，Ni，Cu和Ce中的至少一种金属，优选为Ni。金属盐熔体更优选包含硝酸镍六水合物。此外，本发明涉及本发明的催化剂在CO 2，水和/或氢气存在下，在高于5巴，优选大于10巴的升高的压力下重整烃，优选甲烷的用途，特别优选大于20巴。根据本发明的催化剂通过特定的优选的物理化学性质与现有技术不同。

8. 发明申请

US20060127287A1 Combinatorial preparation and testing of heterogeneous catalysts 审中-公开
标题翻译：组合制备和非均相催化剂的试验
公开(公告)号：US20060127287A1
公开(公告)日：2006-06-15
申请号：US11336843
申请日：2006-01-23
申请人： Hartmut Hibst , Andreas Tenten , Dirk Demuth , Ferdi Schueth , Stephan Schunk
发明人： Hartmut Hibst , Andreas Tenten , Dirk Demuth , Ferdi Schueth , Stephan Schunk
IPC分类号： D21C11/00
CPC分类号： B01J19/0046 , B01J37/0215 , B01J37/0217 , B01J2219/00286 , B01J2219/00306 , B01J2219/00511 , B01J2219/00585 , B01J2219/0059 , B01J2219/00599 , B01J2219/00747
摘要： The array of heterogeneous catalysts and/or their precursors, is made up of a body which has, preferably parallel, through-channels and in which at least n channels comprise n different heterogeneous catalysts and/or their precursors, where n is 2, preferably 10, particularly preferably 100, in particular 1000, especially 10,000. A process for preparing arrays comprising the following steps: a1) preparing solutions, emulsions and/or dispersions of elements and/or element compounds of the elements present in the catalyst and/or catalyst precursor and, if appropriate preparing dispersions of inorganic support materials, a2) if appropriate introducing adhesion promoters, binders, viscosity regulators, pH regulators and/or solid inorganic supports into the solutions, emulsions and/or dispersions, a3) simultaneously or successively coating the channels of the body with the solutions, emulsions and/or dispersions, a predetermined amount of the solutions, emulsions and/or dispersions being introduced into each channel to obtain a predetermined composition and a4) if appropriate heating the coated body in the presence or absence of inert gases or reactive gases to a temperature in the range from 20 to 1500° C. to dry, with or without sintering or calcining, the catalysts and/or catalyst precursors.
摘要翻译：非均相催化剂和/或其前体的阵列由具有优选平行的通道的主体组成，其中至少n个通道包含n个不同的非均相催化剂和/或其前体，其中n为2，优选为 10，特别优选100，特别是1000，特别是10,000。一种制备阵列的方法，包括以下步骤：a1）制备存在于催化剂和/或催化剂前体中的元素和/或元素化合物的溶液，乳液和/或分散体，以及如果合适的话，制备无机载体材料的分散体， a2）如果合适，将粘合促进剂，粘合剂，粘度调节剂，pH调节剂和/或固体无机载体引入溶液，乳液和/或分散体中，a3）用溶液，乳液和/或分散体同时或连续地涂覆身体的通道分散体，预定量的溶液，乳液和/或分散体被引入每个通道以获得预定的组合物和a）如果在存在或不存在惰性气体或反应气体的情况下适当地加热涂覆体到达该范围内的温度 20至1500℃，用或不用烧结或煅烧来干燥催化剂和/或催化剂前体。

9. 发明申请

US20050037426A1 Combinatorial preparation and testing of heterogeneous catalysts 审中-公开
标题翻译：组合制备和非均相催化剂的试验
公开(公告)号：US20050037426A1
公开(公告)日：2005-02-17
申请号：US10726185
申请日：2003-12-03
申请人： Stephan Schunk , Dirk Demuth , Hartmut Hibst
发明人： Stephan Schunk , Dirk Demuth , Hartmut Hibst
IPC分类号： B01J19/00 , B01J35/04 , B01J37/02 , C40B30/08 , C40B40/18 , G01N33/53 , G01N33/543
CPC分类号： B01J37/02 , B01J19/0046 , B01J35/04 , B01J2219/0052 , B01J2219/00585 , B01J2219/00603 , B01J2219/00659 , B01J2219/00704 , B01J2219/00745 , B01J2219/00747 , C40B30/08 , C40B40/18 , Y10T436/175383 , Y10T436/18 , Y10T436/20 , Y10T436/205831 , Y10T436/25875
摘要： A process for preparing arrays of heterogeneous catalysts and/or their precursors, made up of a body which has, preferably parallel, through-channels and in which at least n channels comprise n different heterogeneous catalysts and/or their precursors, where n is 2, preferably 10, particularly preferably 100, comprises the following steps: a1) preparing solutions, emulsions and/or dispersions of elements and/or element compounds of the chemical elements present in the catalyst and/or catalyst precursor and, if appropriate preparing dispersions of inorganic support materials, a2) if appropriate introducing adhesion promoters, binders, viscosity regulators, pH regulators and/or solid inorganic supports into the solutions, emulsions and/or dispersions, a3) simultaneously or successively coating the channels of the body with the solutions, emulsions and/or dispersions, a predetermined amount of the solutions, emulsions and/or dispersions being introduced into each channel to obtain a predetermined composition, a4) treating and reacting with one or more reactive gases the freshly impregnated moist channels obtained after the coating, and a5) if appropriate heating the coated body in the presence or absence of inert gases or reactive gases to a temperature in the range from 20 to 1500° C. to dry, with or without sintering or calcining, the catalysts and/or catalyst precursors.
摘要翻译：一种制备非均相催化剂和/或其前体阵列的方法，其由具有优选平行通过通道并且其中至少n个通道包含n个不同的非均相催化剂和/或其前体的主体组成，其中n为2 ，优选10，特别优选100，包括以下步骤：a1）制备催化剂和/或催化剂前体中存在的化学元素的元素和/或元素化合物的溶液，乳液和/或分散体，并且如果合适，制备无机载体材料，a2）如果合适的话，将粘合促进剂，粘合剂，粘度调节剂，pH调节剂和/或固体无机载体引入溶液，乳液和/或分散体中，a3）用溶液同时或连续地涂覆身体的通道，乳液和/或分散体，将预定量的溶液，乳液和/或分散体引入每个通道以获得预 a4）在涂覆后获得的新鲜浸渍的湿通道处理和反应一种或多种反应性气体，以及a）如果在存在或不存在惰性气体或反应性气体的情况下适当地加热涂覆体到达该范围内的温度 20至1500℃，用或不用烧结或煅烧来干燥催化剂和/或催化剂前体。

10. 发明授权

US08933262B2 Process for preparing polyisocyanates from biomass 有权
标题翻译：从生物质制备多异氰酸酯的方法
公开(公告)号：US08933262B2
公开(公告)日：2015-01-13
申请号：US13479961
申请日：2012-05-24
申请人： Eckhard Stroefer , Otto Machhammer , Stefan Bitterlich , Roman Prochazka , Mario Emmeluth , Julia Leschinski , Emmanouil Pantouflas , Dirk Klingler , Stephan Deuerlein , Stephan Schunk , Jochem Henkelmann , Dieter Stützer
发明人： Eckhard Stroefer , Otto Machhammer , Stefan Bitterlich , Roman Prochazka , Mario Emmeluth , Julia Leschinski , Emmanouil Pantouflas , Dirk Klingler , Stephan Deuerlein , Stephan Schunk , Jochem Henkelmann , Dieter Stützer
IPC分类号： C07C263/00 , C07C263/10
CPC分类号： C07C263/10 , C07C265/14
摘要： The present invention relates to a process for preparing polyisocyanates from natural raw material sources, in which a composition comprising low molecular weight aromatics which comprise at least one hydroxy group or at least one alkoxy group per molecule (oxyaromatics) is produced from a biomass material, these oxyaromatics are converted into the corresponding aromatic amines and, optionally after condensation with formaldehyde, reacted further with phosgene to give compounds comprising isocyanate groups.
摘要翻译：本发明涉及一种由天然原料来制备多异氰酸酯的方法，其中包括每分子含有至少一个羟基或至少一个烷氧基的含低分子量芳族化合物的组合物（氧化芳族化合物）由生物质材料制备，这些氧化芳烃转化为相应的芳族胺，并且任选地在与甲醛缩合后，与光气进一步反应，得到包含异氰酸酯基团的化合物。

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