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1. 发明申请

US20100255378A1 VINYLIDENE FLUORIDE COPOLYMER FUNCTIONALIZED BY RADIATION GRAFTING OF AN UNSATURATED POLAR MONOMER 审中-公开
标题翻译：通过不饱和极性单体的辐射功能功能化的乙烯基氟化物共聚物
公开(公告)号：US20100255378A1
公开(公告)日：2010-10-07
申请号：US12376654
申请日：2007-07-07
申请人： Anthony Bonnet , Aude Lapprand , Pascal Sebire
发明人： Anthony Bonnet , Aude Lapprand , Pascal Sebire
IPC分类号： H01M4/58 , C08F214/22 , B32B27/08 , B32B1/08 , B32B1/00
CPC分类号： B32B27/08 , B32B27/16 , C08F259/08 , C08L27/16 , C08L51/003 , H01M4/13 , H01M4/621 , H01M4/623 , H01M10/052 , Y10T428/1352 , Y10T428/1393 , Y10T428/31507 , Y10T428/3154 , C08L2666/24
摘要： The invention relates to a copolymer of VDF and at least one monomer that is copolymerizable with VDF, having a VDF weight content of at least 50%, preferably at least 75%, onto which at least one unsaturated polar monomer is radiation grafted, characterized in that the VDF copolymer has, before grafting, the following characteristics: a crystallization temperature Tc (measured by DSC according to the standard ISO 11357-3) ranging from 50 to 120° C., preferably from 85 to 110° C.; a yield strength σY ranging from 10 to 40 MPa, preferably from 10 to 30 MPa; and a melt viscosity η (measured with a capillary rheometre at 230° C. and 100 s−1) ranging from 100 to 1500 Pa·s, preferably from 400 to 1200 Pa·s. The invention also relates to a blend comprising this modified copolymer and a PVDF.This modified copolymer or the blend may be combined with a thermoplastic polymer, an elastomer or an inorganic material.
摘要翻译：本发明涉及VDF和至少一种可与VDF共聚的单体的共聚物，VDF的重量含量为至少50％，优选至少75％，其中至少一种不饱和极性单体被辐射接枝，其特征在于 VDF共聚物在接枝之前具有以下特征：结晶温度Tc（根据标准ISO 11357-3通过DSC测量）为50至120℃，优选85至110℃。屈服强度Y为10〜40MPa，优选为10〜30MPa，和熔体粘度＆（用230℃和100s-1的毛细管流变仪测量）为100〜1500Pa·s，优选为400〜1200Pa·s。本发明还涉及包含该改性共聚物和PVDF的共混物。该改性共聚物或共混物可与热塑性聚合物，弹性体或无机材料组合。

2. 发明申请

US20110094612A1 MULTILAYER TUBE FOR TRANSPORTING WATER OR GAS 审中-公开
标题翻译：用于运输水或气的多层管
公开(公告)号：US20110094612A1
公开(公告)日：2011-04-28
申请号：US12376658
申请日：2007-08-07
申请人： Anthony Bonnet , Aude Lapprand , Pascal Sebire
发明人： Anthony Bonnet , Aude Lapprand , Pascal Sebire
IPC分类号： F16L9/14
CPC分类号： B32B27/30 , B32B1/08 , B32B27/32 , C08L27/12 , F24D3/146 , Y02B30/24 , C08L2666/24
摘要： The invention relates to a multilayer tube comprising (in the order from the inside to the outside of the tube), layers arranged one on top of the other: an optional layer L1 comprising at least one fluorinated polymer, preferably a PVDF; a layer L2 comprising at least one functionalized PVDF, obtained by radiation-grafting of at least one unsaturated polar monomer onto a PVDF; an optionally layer L3 of an adhesion binder; a layer L4 comprising at least one polyolefin optionally mixed with at least one functionalized polyolefin; an optional barrier layer L5; an optional layer L6 comprising at least one polyolefin, optionally in a mixture with at least one functionalized polyolefin; characterized in that the PVDF onto which the unsaturated polar monomer is grafted is a VDF copolymer those weight content is at least 50%, preferably at least 75%, and at least one monomer copolymerizable with the VDF, having the following characteristics: a crystallization temperature Tc (measured by DSC as per the ISO Standard 11357-3) ranging from 50 to 120° C., preferably 85 to 110° C.; a yield strength σY ranging from 10 to 40 MPa, preferably 10 to 30 MPa; and a melt viscosity η (measured with a capillary rheometer at 230° C. at 100 s−1) ranging from 100 to 1500 Pa·s, preferably 400 to 1200 Pa·s.”
摘要翻译：本发明涉及一种多层管，其包括（从管的内侧到外侧的顺序），一个彼此排列的层：包含至少一种氟化聚合物，优选PVDF的任选层L1; 包含至少一种官能化PVDF的层L2，其通过将至少一种不饱和极性单体辐射接枝到PVDF上获得; 粘合粘合剂的任选层L3; 包含任选与至少一种官能化聚烯烃混合的至少一种聚烯烃的层L4; 可选的阻挡层L5; 任选的层L6，其包含至少一种聚烯烃，任选地与至少一种官能化聚烯烃的混合物; 其特征在于不饱和极性单体接枝在其上的PVDF是VDF共聚物，其重量含量为至少50％，优选至少75％，和至少一种可与VDF共聚的单体，具有以下特征：结晶温度 Tc（根据ISO标准11357-3通过DSC测量）的范围为50至120℃，优选为85至110℃。屈服强度Y为10〜40MPa，优选为10〜30MPa，和熔体粘度＆（用毛细管流变仪在230℃下在100s -1下测量）为100〜1500Pa·s，优选为400〜1200Pa·s。

3. 发明授权

US08697214B2 Multi-layered structure containing a barrier polymer optionally reinforced against impacts 失效
标题翻译：含有阻挡聚合物的多层结构，任选地加强抵抗冲击
公开(公告)号：US08697214B2
公开(公告)日：2014-04-15
申请号：US12513747
申请日：2007-11-07
申请人： Anthony Bonnet , Aude Lapprand
发明人： Anthony Bonnet , Aude Lapprand
IPC分类号： B32B1/08 , B32B27/06
CPC分类号： B32B27/08 , F16L2011/047 , Y10T428/1352 , Y10T428/1383 , Y10T428/1393 , Y10T428/3154
摘要： The invention relates to a multi-layer structure containing from the inside towards the outside: a layer C1 comprising at least one functionalized fluorinated polymer optionally mixed with at least one compatible fluorinated polymer; a layer C2 containing at least one adhesive binder; a layer C3 containing at least one polyolefin, preferably a polyethylene; a layer C4 containing at least one adhesive binder; a barrier layer C5 containing at least one barrier polymer, optionally reinforced against impacts; the layers are arranged against each other in the above mentioned order. The invention also relates to the use of this mull-layered structure for storing or transferring fuel.
摘要翻译：本发明涉及从内部向外部包含的多层结构：包含至少一种官能化氟化聚合物的层C1，任选地与至少一种相容的氟化聚合物混合; 含有至少一种粘合剂粘合剂的层C2; 含有至少一种聚烯烃，优选聚乙烯的层C3; 含有至少一种粘合剂粘合剂的层C4; 包含至少一种阻挡聚合物的阻挡层C5，任选地加强抵抗冲击; 这些层按照上述顺序相互排列。本发明还涉及这种用于储存或转移燃料的该层状结构的用途。

4. 发明申请

US20100112256A1 MULTI-LAYERED STRUCTURE CONTAINING A BARRIER POLYMER OPTIONALLY REINFORCED AGAINST IMPACTS 失效
标题翻译：包含阻挡聚合物的多层结构对增强的影响有所增强
公开(公告)号：US20100112256A1
公开(公告)日：2010-05-06
申请号：US12513747
申请日：2007-11-07
申请人： Anthony Bonnet , Aude Lapprand
发明人： Anthony Bonnet , Aude Lapprand
IPC分类号： B32B27/18 , B32B27/08 , B32B1/02 , B32B1/08
CPC分类号： B32B27/08 , F16L2011/047 , Y10T428/1352 , Y10T428/1383 , Y10T428/1393 , Y10T428/3154
摘要： The invention relates to a multi-layer structure containing from the inside towards the outside: a layer C1 comprising at least one functionalized fluorinated polymer optionally mixed with at least one compatible fluorinated polymer; a layer C2 containing at least one adhesive binder; a layer C3 containing at least one polyolefin, preferably a polyethylene; a layer C4 containing at least one adhesive binder; a barrier layer C5 containing at least one barrier polymer, optionally reinforced against impacts; the layers are arranged against each other in the above mentioned order. The invention also relates to the use of this mull-layered structure for storing or transferring fuel.
摘要翻译：本发明涉及从内部向外部包含的多层结构：包含至少一种官能化氟化聚合物的层C1，任选地与至少一种相容的氟化聚合物混合; 含有至少一种粘合剂粘合剂的层C2; 含有至少一种聚烯烃，优选聚乙烯的层C3; 含有至少一种粘合剂粘合剂的层C4; 包含至少一种阻挡聚合物的阻挡层C5，任选地加强抵抗冲击; 这些层按照上述顺序相互排列。本发明还涉及这种用于储存或转移燃料的该层状结构的用途。

5. 发明授权

US08878054B2 Three-layer film for a photovoltaic cell 有权
标题翻译：用于光伏电池的三层膜
公开(公告)号：US08878054B2
公开(公告)日：2014-11-04
申请号：US12532573
申请日：2009-02-06
申请人： Stephane Bizet , Anthony Bonnet , Nicolas Devaux , Johann Laffargue , Aude Lapprand
发明人： Stephane Bizet , Anthony Bonnet , Nicolas Devaux , Johann Laffargue , Aude Lapprand
IPC分类号： H01L31/00 , B32B27/28 , B32B27/08 , B32B27/30 , C08L27/16 , C08L33/12 , H01L31/048
CPC分类号： B32B27/28 , B32B7/12 , B32B27/08 , B32B27/18 , B32B27/30 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/322 , B32B2250/03 , B32B2250/40 , B32B2264/02 , B32B2307/30 , B32B2307/306 , B32B2307/308 , B32B2307/41 , B32B2307/50 , B32B2307/546 , B32B2307/71 , B32B2307/712 , B32B2307/714 , B32B2457/12 , C08L27/16 , C08L33/12 , H01L31/048 , H01L31/0481 , H01L31/049 , Y02E10/50 , Y10T428/24231 , Y10T428/24975 , Y10T428/25 , Y10T428/265 , Y10T428/3154 , C08L2666/04
摘要： The invention relates to a multilayer film of A/B/C structure comprising: a first layer of composition A, comprising a fluoropolymer; a second layer of composition B, comprising a filled fluoropolymer; and a third layer of composition C, comprising a fluoropolymer, characterized in that the first and third layers have a melting point above 150° C., measured by DSC, and in that the transmittance in visible light is less than 30% for a multilayer film thickness of 25 μm. The invention also relates to the use of a fluoropolymer-based film preferably for a photovoltaic cell back panel, a high-performance textile or a metal, the film adhering to the substrate by means of an adhesive layer placed between the substrate and the film.
摘要翻译：本发明涉及一种A / B / C结构的多层膜，其包括：第一层组合物A，其包含含氟聚合物; 组合物B的第二层，包含填充的含氟聚合物; 以及包含含氟聚合物的组合物C的第三层，其特征在于，通过DSC测量，第一层和第三层的熔点高于150℃，并且对于多层膜，可见光的透射率小于30％膜厚25微米。本发明还涉及优选用于光伏电池背板，高性能织物或金属的氟聚合物基膜的使用，所述膜通过设置在基板和膜之间的粘合剂层粘附到基板。

6. 发明申请

US20110232735A1 THREE-LAYER FILM FOR A PHOTOVOLTAIC CELL 有权
标题翻译：三层细胞膜三膜
公开(公告)号：US20110232735A1
公开(公告)日：2011-09-29
申请号：US12532573
申请日：2009-02-06
申请人： Stephane Bizet , Anthony Bonnet , Nicholas Devaux , Johann Laffargue , Aude Lapprand
发明人： Stephane Bizet , Anthony Bonnet , Nicholas Devaux , Johann Laffargue , Aude Lapprand
IPC分类号： H01L31/0216 , B32B27/28 , B32B27/30 , B32B5/16 , B32B5/00 , B32B7/02
CPC分类号： B32B27/28 , B32B7/12 , B32B27/08 , B32B27/18 , B32B27/30 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/322 , B32B2250/03 , B32B2250/40 , B32B2264/02 , B32B2307/30 , B32B2307/306 , B32B2307/308 , B32B2307/41 , B32B2307/50 , B32B2307/546 , B32B2307/71 , B32B2307/712 , B32B2307/714 , B32B2457/12 , C08L27/16 , C08L33/12 , H01L31/048 , H01L31/0481 , H01L31/049 , Y02E10/50 , Y10T428/24231 , Y10T428/24975 , Y10T428/25 , Y10T428/265 , Y10T428/3154 , C08L2666/04
摘要： The invention relates to a multilayer film of A/B/C structure comprising: a first layer of composition A, comprising a fluoropolymer; a second layer of composition B, comprising a filled fluoropolymer; and a third layer of composition C, comprising a fluoropolymer, characterized in that the first and third layers have a melting point above 150° C., measured by DSC, and in that the transmittance in visible light is less than 30% for a multilayer film thickness of 25 μm. The invention also relates to the use of a fluoropolymer-based film preferably for a photovoltaic cell back panel, a high-performance textile or a metal, the film adhering to the substrate by means of an adhesive layer placed between the substrate and the film.
摘要翻译：本发明涉及一种A / B / C结构的多层膜，其包括：第一层组合物A，其包含含氟聚合物; 组合物B的第二层，包含填充的含氟聚合物; 以及包含含氟聚合物的组合物C的第三层，其特征在于，通过DSC测量，第一层和第三层的熔点高于150℃，并且对于多层膜，可见光的透射率小于30％膜厚25微米。本发明还涉及优选用于光伏电池背板，高性能织物或金属的氟聚合物基膜的使用，所述膜通过设置在基板和膜之间的粘合剂层粘附到基板。

7. 发明申请

US20090301595A1 MULTI-LAYER STRUCTURE BASED ON FLUORIDE POLYMER FUNCTIONALISED BY IRRADIATION AND PVC 审中-公开
标题翻译：基于氟化聚合物的多层结构通过IRRADIATION和PVC功能化
公开(公告)号：US20090301595A1
公开(公告)日：2009-12-10
申请号：US12297402
申请日：2007-03-20
申请人： Anthony Bonnet , Francois Beaume , Aude Lapprand , Frank Vandekerckhove
发明人： Anthony Bonnet , Francois Beaume , Aude Lapprand , Frank Vandekerckhove
IPC分类号： F16L9/14 , B32B27/30 , B32B1/08 , B32B1/02
CPC分类号： F16L11/04 , B32B1/02 , B32B1/08 , B32B27/08 , B32B27/28 , B32B27/304 , B32B27/322 , B32B2250/24 , B32B2439/40 , B32B2439/60 , Y10T428/1352 , Y10T428/3154
摘要： The invention relates to a multi-layer structure including placed one against the other, at least one layer of fluoride polymer onto which at least one unsaturated monomer has been grafted by irradiation, and at least one layer of PVC. According to a 1st form, the multi-layer structure may include in order placed against one another: possibly a layer of fluoride polymer; a layer of fluoride polymer grafted by irradiation; and layer of PVC. According to a 2nd form, the multi-layer structure includes in order placed against one another: possibly, a layer of fluoride polymer; a layer of fluoride polymer grafted by irradiation; a layer of PVC; a layer of fluoride polymer grafted by irradiation; and possibly a layer of a fluoride polymer. According to a 3rd form, the multi-layer structure includes in order placed against one another: a layer of PVC; a layer of fluoride polymer grafted by irradiation; a layer of PVC. Said structure may be shaped into films, bottles, tanks, containers, pipes and containers of all kinds.
摘要翻译：本发明涉及一种多层结构，其包括彼此相对放置的至少一层氟化物聚合物，至少一种不饱和单体通过照射被接枝到其上，以及至少一层PVC。根据第一种形式，多层结构可以按照彼此排列的顺序包括：可能是一层氟化物聚合物; 通过辐射接枝的氟化物聚合物层; 和PVC层。根据第二种形式，多层结构按顺序相互排列：可能是一层氟化物聚合物; 通过辐射接枝的氟化物聚合物层; 一层PVC; 通过辐射接枝的氟化物聚合物层; 并且可能是一层氟化物聚合物。根据第三种形式，多层结构按顺序相互排列：一层PVC; 通过辐射接枝的氟化物聚合物层; 一层PVC。所述结构可以成型为各种薄膜，瓶，罐，容器，管和容器。

8. 发明申请

US20050170121A1 Use of a hose based on an irradiation-grafted fluoropolymer for transporting petrol in a service station 审中-公开
标题翻译：使用基于照射嫁接的含氟聚合物的软管在服务站中运输汽油
公开(公告)号：US20050170121A1
公开(公告)日：2005-08-04
申请号：US11000163
申请日：2004-11-30
申请人： Anthony Bonnet , Fabrice Chopinez , Pascal Sebire , Michael Werth , Gregory O'Brien , Saeid Zerafati
发明人： Anthony Bonnet , Fabrice Chopinez , Pascal Sebire , Michael Werth , Gregory O'Brien , Saeid Zerafati
IPC分类号： B67D7/04 , B32B1/08 , B32B27/08 , B32B27/30 , B32B27/32 , B67D7/06 , B67D7/38 , C08L51/06 , F16L11/00 , F16L11/04 , F16L58/02
CPC分类号： B32B27/08 , B32B1/08 , B32B27/20 , B32B27/304 , B32B27/32 , B32B2250/03 , B32B2250/04 , B32B2250/05 , B32B2250/24 , B32B2262/106 , B32B2264/108 , B32B2307/21 , B32B2597/00 , B82Y30/00 , F16L11/00 , F16L11/06 , Y10T428/1393
摘要： The present invention relates to a hose having a layer consisting of a fluoropolymer onto which an unsaturated monomer has been irradiation-grafted and, a polyolefin outer layer. The hose is useful for transporting petrol in a service station. In one embodiment a fluoropolymer, preferably PDVF, layer is placed beside the irradiation-grafted fluoropolymer. The hose may consist of a irradiation-grafted fluoropolymer inner layer and a polyolefin outer layer, or multilayer hose with either a central irradiation-grafted fluoropolymer layer and polyolefin inner and outer layers, or a polyolefin central layer and irradiation-grafted fluoropolymer inner and outer layers. The irradiation-grafted fluoropolymer layer may be replaced with a layer of a blend of a fluoropolymer, preferably PVDF, and of an irradiation-grafted fluoropolymer. It may also be covered with a fluoropolymer.
摘要翻译：本发明涉及一种软管，其具有由不饱和单体被照射接枝到其上的含氟聚合物组成的层和聚烯烃外层。软管可用于在维修站内运输汽油。在一个实施方案中，将含氟聚合物，优选PDVF层放置在照射接枝的含氟聚合物旁边。软管可以由辐射接枝的含氟聚合物内层和聚烯烃外层组成，或者具有中心辐射接枝的含氟聚合物层和聚烯烃内外层的多层软管，或聚烯烃中心层和内外辐射接枝氟聚合物层。照射接枝的氟聚合物层可以用含氟聚合物，优选PVDF和辐照接枝的含氟聚合物的共混物层代替。也可以用含氟聚合物覆盖。

9. 发明申请

US20050118372A1 Use of a structure based on a grafted fluoropolymer for storing and transporting chemicals 审中-公开
标题翻译：使用基于接枝的含氟聚合物的结构来储存和运输化学品
公开(公告)号：US20050118372A1
公开(公告)日：2005-06-02
申请号：US11001823
申请日：2004-12-02
申请人： Anthony Bonnet , Fabrice Chopinez , Pascal Sebire , Michael Werth
发明人： Anthony Bonnet , Fabrice Chopinez , Pascal Sebire , Michael Werth
IPC分类号： B32B27/28 , B32B27/32 , B32B1/08 , B32B27/30
CPC分类号： B32B27/08 , B32B27/28 , B32B27/304 , B32B27/32 , B32B2307/714 , B32B2439/00 , B82Y30/00 , Y10T428/1352 , Y10T428/3154 , Y10T428/31935 , Y10T428/31938
摘要： The present invention relates to the use for storing or transporting chemicals of a structure comprising an inner layer in contact with the fluid to be stored or transported, consisting of a fluoropolymer onto which an unsaturated monomer has been grafted by irradiation and, directly attached to the latter, a polyolefin outer layer. According to a variant, the structure comprises a fluoropolymer, preferably PDVF, layer placed beside the radiation-grafted fluoropolymer. The invention also relates to a structure having a central layer consisting of a radiation-grafted fluoropolymer and, directly attached to the latter, a polyolefin outer layer and a polyolefin inner layer. The polyolefin inner layer is the layer in contact with the chemicals. According to a variant, the radiation-grafted fluoropolymer layer is replaced with a layer of a blend of a fluoropolymer, preferably PVDF, and of a radiation-grafted fluoropolymer.
摘要翻译：本发明涉及用于储存或运输结构的用途，所述结构包括与待储存或运输的流体接触的内层，所述内层由其中通过照射接枝不饱和单体的含氟聚合物组成，并直接附着于后者是聚烯烃外层。根据一个变体，该结构包括位于辐射接枝的含氟聚合物旁边的含氟聚合物，优选PDVF层。本发明还涉及一种具有由辐射接枝的含氟聚合物组成的中心层并直接与其连接的聚烯烃外层和聚烯烃内层的结构。聚烯烃内层是与化学品接触的层。根据一个变型，辐射接枝的含氟聚合物层被氟聚合物，优选PVDF和辐射接枝的含氟聚合物的共混物层代替。

10. 发明申请

US20050065229A1 Process for oxidizing a fluoropolymer and multilayer structures comprising this oxidized fluoropolymer 审中-公开
标题翻译：用于氧化含氟聚合物和包含该氧化的含氟聚合物的多层结构的方法
公开(公告)号：US20050065229A1
公开(公告)日：2005-03-24
申请号：US10900940
申请日：2004-07-28
申请人： Anthony Bonnet , Barbara Ramfel , Pascal Sebire , Michael Werth , Thierry Pascal
发明人： Anthony Bonnet , Barbara Ramfel , Pascal Sebire , Michael Werth , Thierry Pascal
IPC分类号： C08F8/06 , C08J3/28
CPC分类号： B82Y30/00 , B32B7/10 , B32B7/12 , B32B27/08 , B32B27/304 , B32B27/32 , C08F8/06 , C08J3/28 , C08J7/123 , C08J2327/16 , C08F114/22
摘要： The present invention relates to a process for oxidizing a fluoropolymer, comprising the steps of: a) forming a fluoropolymer is into a film, a sheet, granules or powder; b) exposing the products from step a), in the presence of oxygen, to photon (γ) or electron (β) irradiation with a dose of between 1 and 15 Mrad; and c) optionally treating the product obtained in b) in order to remove all or some of the by-product impurities. The oxidized fluoropolymer thus obtained may be used as such or in a blend with at least one polymer. Structures comprising at least one layer of this oxidized fluoropolymer and at least one layer of another material may be formed into bottles, tanks, containers, pipes, hoses and vessels of all sorts. They may also be converted into films with which packaging is made. The invention also relates to the oxidized fluoropolymer.
摘要翻译：本发明涉及一种氧化含氟聚合物的方法，包括以下步骤：a）将含氟聚合物形成薄膜，片，颗粒或粉末; b）以1至15Mrad的剂量将来自步骤a）的产物在氧的存在下暴露于光子（γ）或电子（β）照射; 和c）任选地处理b）中获得的产物以除去所有或一些副产物杂质。由此获得的氧化含氟聚合物可以原样使用或与至少一种聚合物共混使用。包含至少一层该氧化含氟聚合物和至少一层其它材料的结构可以形成为各种瓶，罐，容器，管，软管和各种容器。它们也可以转换为制成包装的薄膜。本发明还涉及氧化的含氟聚合物。

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