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    • 4. 发明申请
    • Production method of polyimide solution and fluorinated polyimide solution
    • 聚酰亚胺溶液和氟化聚酰亚胺溶液的生产方法
    • US20100284664A1
    • 2010-11-11
    • US11886073
    • 2006-03-10
    • Go MasudaKozo TajiriTomomi MakinoYoko Matsui
    • Go MasudaKozo TajiriTomomi MakinoYoko Matsui
    • G02B6/00C08G69/08
    • C08G73/1039
    • The invention aims to provide a method by which a solution of polyimide can be easily obtained. Further, the invention aims to provide a fluorinated polyimide solution by which fluorinated polyimide excellent especially as an optical material and an electronic functional material can easily be produced. The production method of the soluble polyimide solution according to invention is characterized by mixing a mixture containing a polyamide acid, a cyclodehydration reagent, and a solvent by a rotation-revolution mixing method. Further, the fluorinated polyimide solution of the invention is a solution of polyimide defined by the following formula (II): wherein, X and Y independently represent divalent organic groups; Z represents chlorine atom, bromine atom, or iodine atom; p represents an integer of 1 to 3; q represents an integer of 0 to 2; and p+q=3.
    • 本发明的目的在于提供一种容易得到聚酰亚胺溶液的方法。 此外,本发明的目的在于提供一种氟化聚酰亚胺溶液,通过该氟化聚酰亚胺溶液,可以容易地制造出特别优选作为光学材料和电子功能材料的氟化聚酰亚胺。 根据本发明的可溶性聚酰亚胺溶液的制备方法的特征在于通过旋转 - 旋转混合法混合含有聚酰胺酸,环化脱水剂和溶剂的混合物。 此外,本发明的氟化聚酰亚胺溶液是由下式(II)定义的聚酰亚胺溶液:其中,X和Y独立地表示二价有机基团; Z表示氯原子,溴原子或碘原子; p表示1〜3的整数, q表示0〜2的整数, 和p + q = 3。
    • 6. 发明授权
    • Production method of polyimide solution and fluorinated polyimide solution
    • 聚酰亚胺溶液和氟化聚酰亚胺溶液的生产方法
    • US08470917B2
    • 2013-06-25
    • US11886073
    • 2006-03-10
    • Go MasudaKozo TajiriTomomi MakinoYoko Matsui
    • Go MasudaKozo TajiriTomomi MakinoYoko Matsui
    • C08K5/17
    • C08G73/1039
    • The invention aims to provide a method by which a solution of polyimide can be easily obtained. Further, the invention aims to provide a fluorinated polyimide solution by which fluorinated polyimide excellent especially as an optical material and an electronic functional material can easily be produced. The production method of the soluble polyimide solution according to invention is characterized by mixing a mixture containing a polyamide acid, a cyclodehydration reagent, and a solvent by a rotation-revolution mixing method. Further, the fluorinated polyimide solution of the invention is a solution of polyimide defined by the following formula (II): wherein, X and Y independently represent divalent organic groups; Z represents chlorine atom, bromine atom, or iodine atom; p represents an integer of 1 to 3; q represents an integer of 0 to 2; and p+q=3.
    • 本发明的目的在于提供一种容易得到聚酰亚胺溶液的方法。 此外,本发明的目的在于提供一种氟化聚酰亚胺溶液,通过该氟化聚酰亚胺溶液,可以容易地制造出特别优选作为光学材料和电子功能材料的氟化聚酰亚胺。 根据本发明的可溶性聚酰亚胺溶液的制备方法的特征在于通过旋转 - 旋转混合法混合含有聚酰胺酸,环化脱水剂和溶剂的混合物。 此外,本发明的氟化聚酰亚胺溶液是由下式(II)定义的聚酰亚胺溶液:其中,X和Y独立地表示二价有机基团; Z表示氯原子,溴原子或碘原子; p表示1〜3的整数, q表示0〜2的整数, 和p + q = 3。
    • 7. 发明授权
    • Dispersion of silica particle agglomerates and process for producing the same
    • 二氧化硅颗粒附聚物的分散体及其制造方法
    • US06569908B2
    • 2003-05-27
    • US09764910
    • 2001-01-16
    • Tetsuro NoguchiKozo Tajiri
    • Tetsuro NoguchiKozo Tajiri
    • B01F312
    • C01B33/1465
    • The present invention also provides a process for producing a colloidal dispersion of silica particle agglomerates having a specific surface area, as determined by nitrogen adsorption method, of 100 m2/g to 400 m2/g, an average secondary particle diameter of 20 nm to 300 nm and a pore volume of 0.5 ml/g to 2.0 ml/g, which comprises using a colloidal dispersion of silica particle agglomerates having a specific surface area, as determined by nitrogen adsorption method, of 300 m2/g to 1,000 m2/g and a pore volume of 0.4 ml/g to 2.0 ml/g as a seed dispersion, adding a feed solution comprising at least one of an aqueous active silicic acid solution and alkoxysilanes to the seed dispersion in small portions in the presence of an alkali to grow silica particle agglomerates.
    • 本发明还提供了通过氮吸附法测定的比表面积为100m 2 / g〜400m 2 / g,平均二次粒径为20nm〜300μm的二氧化硅粒子聚集体的胶体分散体的制造方法 nm,孔体积为0.5ml / g至2.0ml / g,其包括使用通过氮吸附法测定的具有比表面积的二氧化硅颗粒附聚物的胶态分散体为300m 2 / g至1,000m 2 / g,以及 将孔体积为0.4ml / g至2.0ml / g作为种子分散体,在碱存在下,将少量含有活性硅酸水溶液和烷氧基硅烷中的至少一种的进料溶液加入到种子分散体中以生长 二氧化硅颗粒附聚物。
    • 9. 发明申请
    • HIGHLY WATER-REPELLENT POLYIMIDE FOR COPIER MEMBER, AND POLYAMIC ACID COMPOSITION
    • 用于复合成员的高水性聚酰亚胺和聚氨酯组合物
    • US20120101213A1
    • 2012-04-26
    • US13379840
    • 2010-06-28
    • Kozo TajiriGo MasudaTomomi MakinoAtsushi Okada
    • Kozo TajiriGo MasudaTomomi MakinoAtsushi Okada
    • C08G73/10C08K3/04C08L79/08
    • G03G15/0233C08G73/1039C08G73/1046C08G73/1064C08L79/08C08L2203/20G03G5/0571G03G5/14765G03G15/0818G03G15/1685G03G15/2057G03G15/751
    • Provided are a polyimide which is inexpensive, has various excellent material properties including strength, heat resistance, low moisture absorption, mold releasability (detachability), dielectric properties, electrical properties, and optical properties, and can exhibit a high level of water repellency, and a polyamic acid composition useful as a raw material therefor. Also provided are the polyimide which can give a polyimide composition that, besides having such excellent material properties, is capable of having a controlled surface resistivity, and a polyamic acid composition useful as a raw material therefor. The polyimide is a highly water-repellent polyimide for copier members which is obtained using one or more acid dianhydrides and one or more diamine compounds, and is characterized in that at least one of the acid dianhydrides and the diamine compounds is a compound having an ether bond and/or a thioether bond in the molecule and that the total number of ether bonds and thioether bonds in the repeating unit constituting the polyimide and derived from the acid dianhydrides and the diamine compounds is 2 or larger.
    • 提供廉价的聚酰亚胺,具有强度,耐热性,低吸湿性,脱模性(剥离性),介电特性,电性能和光学性能等各种优异的材料性能,并且可以表现出高水平的拒水性, 可用作原料的聚酰胺酸组合物。 还可以提供聚酰亚胺,其可以得到除了具有这样优异的材料性能之外还能够具有受控表面电阻率的聚酰亚胺组合物和可用作原料的聚酰胺酸组合物。 聚酰亚胺是使用一种或多种酸二酐和一种或多种二胺化合物获得的复印机构件的高度疏水性聚酰亚胺,其特征在于,酸酐和二胺化合物中的至少一种是具有醚 键和/或硫醚键,并且构成聚酰亚胺并衍生自酸性二酸酐和二胺化合物的重复单元中的醚键和硫醚键的总数为2以上。
    • 10. 发明授权
    • Ink-jet recording sheet and process for producing the same
    • 喷墨记录纸及其制造方法
    • US06146712A
    • 2000-11-14
    • US199781
    • 1998-11-25
    • Masayo MaedaKozo Tajiri
    • Masayo MaedaKozo Tajiri
    • B41M5/00B41M5/50B41M5/52B05D3/06
    • B41M5/52B41M5/508B41M5/5209B41M5/5236B41M5/5245B41M5/5254
    • The present invention provides an ink-jet recording sheet which is excellent in water resistance, capable of providing excellent ink-drying property and image quality, substantially free from blurring, and suitable for use as OHP sheets of which a high transparency is necessitated. The present process for producing an ink-jet recording sheet comprises applying to a base sheet, an aqueous solution of a water-soluble resin having no radically polymerizable double bond in the molecule and selected from the group consisting of polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylamide, polyacryloyl morpholine, water-soluble polyvinyl acetal, poly-N-vinyl acetamide, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, hydroxypropyl methyl cellulose, hydroxyethyl methyl cellulose, gelatin, casein and derivatives of them, irradiating the resultant coating layer with electron beam before the coating layer is dried, to form a hydrogel, and drying the hydrogel. In the present invention, the water-soluble resin is usable in combination with a polyalkylene oxide compatible with the water-soluble resin.
    • 本发明提供一种喷墨记录纸,其耐水性优异,能够提供优异的油墨干燥性和图像质量,基本上没有模糊,并且适用于需要高透明度的OHP片材。 本发明的喷墨记录纸的制造方法包括向基片施加在分子中不具有自由基聚合性双键的水溶性树脂的水溶液,选自聚乙烯醇,聚乙烯吡咯烷酮,聚丙烯酰胺 ,聚丙烯酰吗啉,水溶性聚乙烯醇缩醛,聚-N-乙烯基乙酰胺,羟乙基纤维素,羟丙基纤维素,甲基纤维素,羟丙基甲基纤维素,羟乙基甲基纤维素,明胶,酪蛋白及其衍生物, 在涂层干燥之前,形成水凝胶,并干燥水凝胶。 在本发明中,水溶性树脂可与与水溶性树脂相容的聚环氧烷结合使用。