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    • 3. 发明申请
    • POLYMERIZABLE COMPOSITIONS, POLYMERIZED COMPOSITIONS, AND METHODS OF MAKING AND USING THE SAME
    • 聚合性组合物,聚合组合物及其制造方法和使用方法
    • WO2017044704A1
    • 2017-03-16
    • PCT/US2016/050895
    • 2016-09-09
    • 3M INNOVATIVE PROPERTIES COMPANY
    • CLOUGH, Robert S.DEMOSS, Susan E.KROPP, MIchael A.
    • C08G75/045
    • C08G75/045
    • A polymerizable composition includes an organoborane-base complex that is a complex of an organoborane and a base, a decomplexing agent that at least partially liberates the organoborane from the organoborane-base complex, a polymerizable thiol-containing component comprising at least one polymerizable thiol-containing compound having a plurality of thiol groups in which the sulfur atom of the thiol group is covalently bonded to carbon, a hydroperoxide, and a polymerizable ethylenically-unsaturated component comprising at least one polymerizable ethylenically-unsaturated compound having a plurality of ethylenically-unsaturated groups. The combined amounts of the thiol-containing and ethylenically-unsaturated compounds total at least 50 percent by weight of all polymerizable material in the polymerizable composition. The composition may be provide as a two-part composition. Polymerized reaction product of the composition and methods of making the composition are also disclosed.
    • 可聚合组合物包括有机硼烷碱络合物,其是有机硼烷和碱的络合物,至少部分地从有机基硼烷碱络合物中释放有机硼烷的解络剂,包含至少一种可聚合硫醇 - 含有硫醇基的硫原子与碳共价结合的多个硫醇基的含硫化合物,氢过氧化物和可聚合的烯属不饱和成分,所述成分含有至少一个具有多个烯属不饱和基团的可聚合的烯属不饱和化合物 。 含硫醇和烯属不饱和化合物的总量相对于可聚合组合物中的所有可聚合材料的总重量至少为50重量%。 组合物可以作为两部分组合物提供。 还公开了组合物的聚合反应产物和制备组合物的方法。