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    • 1. 发明专利
    • Mercury recovery system and recovery method from cement kiln dust
    • 水泥钻屑回收系统和回收方法
    • JP2014058699A
    • 2014-04-03
    • JP2012202688
    • 2012-09-14
    • Taiheiyo Cement Corp太平洋セメント株式会社
    • WADACHI HITOSHITAWARA YUTASAITO SHINICHIRO
    • C22B43/00B07B4/08B09B3/00B09B5/00C04B7/60C22B7/02
    • Y02P10/212
    • PROBLEM TO BE SOLVED: To efficiently recover mercury from a dust contained in a cement kiln combustion exhaust gas at a low cost.SOLUTION: A mercury recovery system 1 from a cement kiln dust is equipped with a mixing device 2 for heating a cement kiln dust KD by a sensible heat of a duct for heating with mixing with a high temperature dust (dust for heating) HD, and a mercury recovery device 7 for recovering mercury vaporized by mixing heating. A vibration fluidized bed type classifying machine 3 for fluidizing a mixture M of the cement kiln dust and the dust for heating, and separating a coarse powder D1 and a gas G1 containing a coarse powder D2 can be arranged after the mixing device and mercury contained in the gas containing the coarse powder separated by the vibration fluidized bed type classifying machine is recovered with the mercury recovery system. The dust for heating can be a cement raw material fractionated from a pre-heater of a cement firing device and/or a coarse powder of a chlorine bypass dust.
    • 要解决的问题:以低成本有效地从水泥窑燃烧废气中的灰尘中回收汞。解决方案:来自水泥窑灰的汞回收系统1配备有用于加热水泥窑粉尘的混合装置2 KD通过用于与高温粉尘(用于加热的粉尘)混合进行加热的管道的显热,以及用于回收通过混合加热而蒸发的汞的汞回收装置7。 在混合装置和含有汞的混合装置之后,可以配置用于使混合物M流化的振动流化床型分选机3,该混合装置M将水泥窑灰和粉尘的混合物M进行流化,并分离粗粉末D1和含有粗粉末D2的气体G1 含有由振动流化床型分选机分离的粗粉末的气体用汞回收系统回收。 用于加热的灰尘可以是从水泥烧制装置的预热器和/或氯旁路粉尘的粗粉末分级的水泥原料。
    • 3. 发明专利
    • Method and apparatus of treating flyash and dust present in combustion gas extracted from cement kiln
    • 在水泥窑提取的燃烧气中处理飞灰和粉尘的方法和装置
    • JP2012035168A
    • 2012-02-23
    • JP2010175971
    • 2010-08-05
    • Taiheiyo Cement Corp太平洋セメント株式会社
    • TERASAKI JUNICHISAITO SHINICHIRO
    • B09B3/00B01D53/50B01D53/62B01D53/77C02F1/42C02F1/44C04B7/60
    • PROBLEM TO BE SOLVED: To provide a method and an apparatus that can make the supervision of operation and maintenance easier upon treating flyash and dust present in a combustion gas extracted from a cement kiln, and can make the installation area thereof smaller.SOLUTION: The method of treating flyash and/or dust present in a combustion gas extracted from a cement kiln, comprising introducing wastewater (a filtrate) L1 generated upon water-washing flyash and/or dust present in a combustion gas extracted from a kiln-exhaust flow path starting from the tail end of the cement kiln up to the lowermost-stage cyclone into an ion exchange resin 31, and removing calcium from the wastewater by virtue of the ion exchange resin 31, is characterized by further subjecting the wastewater having been removed of calcium to a wastewater treatment. Slurry wherein the flyash and/or the dust are dissolved is allowed to contact a SOgas and/or a COgas and is subsequently subjected to solid/liquid separation to obtain a filtrate, which filtrate may be introduced into the ion exchange resin 31 as well, whereupon the exhaust coming out of the cement kiln and/or exhaust coming out of a chlorine bypass system may be used as well. The wastewater removed of calcium is preferably treated by a membrane.
    • 要解决的问题:提供一种方法和装置,其可以在处理从水泥窑提取的燃烧气体中存在的飞灰和粉尘时更容易地进行操作和维护的监督,并且可以使安装面积更小。 解决方案:处理从水泥窑提取的燃烧气体中存在的飞灰和/或粉尘的方法,包括引入在从水中提取的燃烧气体中存在的水洗飞灰和/或粉尘产生的废水(滤液)L1 从水泥窑的尾端直到最下阶段的旋风分离器为离子交换树脂31,并且通过离子交换树脂31从废水中除去钙的窑尾废气流路的特征在于, 废水已经将钙除去废水处理。 其中使粉煤灰和/或粉尘溶解的浆料允许接触气体和/或CO气体和/或气体的CO 2 气体 然后进行固/液分离以获得滤液,该滤液也可以被引入到离子交换树脂31中,从而从氯旁路系统出来的水泥窑和/或排气出来的排气可以是 也用。 除去钙的废水优选用膜处理。 版权所有(C)2012,JPO&INPIT
    • 4. 发明专利
    • Method for recovering thallium from cement manufacturing process
    • 从水泥制造工艺回收THALIUM的方法
    • JP2009292691A
    • 2009-12-17
    • JP2008149253
    • 2008-06-06
    • Taiheiyo Cement Corp太平洋セメント株式会社
    • TAMURA NORITOSHISAITO SHINICHIRO
    • C01G15/00C04B7/60C22B7/02C22B61/00
    • Y02P20/129
    • PROBLEM TO BE SOLVED: To provide a method for recovering thallium from a cement manufacturing process by which thallium is recovered at low cost and the potential heat of cement kiln combustion gas can be effectively utilized. SOLUTION: Combustion exhaust gas G discharged from a top cyclone 12a of a preheater 12 in a cement firing step is passed through a first bag filter 2 to collect dust, the combustion exhaust gas passed through the first bag filter is introduced into a waste heat boiler 3, dust D2 in which thallium contained in the combustion exhaust gas passed through the waste heat boiler is contained in a solidified state is recovered with a second bag filter 4, and the thallium is recovered from the dust. Alternatively, dust in which thallium contained in combustion exhaust gas G discharged from the top cyclone is present in a solidified state and which deposits on a surface of an evaporating tube of a waste heat boiler or the like is recovered without disposing the fist bag filter, and the thallium is recovered from the dust. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种从低成本回收铊的水泥制造工艺中回收铊的方法,并且可以有效地利用水泥窑燃烧气体的潜在热量。 解决方案:在水泥烧制步骤中从预热器12的顶部旋风器12a排出的燃烧废气G通过第一袋式过滤器2以收集灰尘,通过第一袋式过滤器的燃烧废气被引入 废热锅炉3,通过废热锅炉包含的燃烧废气中所含的铊含有固化状态的粉尘D2用第二袋式过滤器4回收,铊从粉尘中回收。 或者,从顶部旋风分离器排出的燃烧废气G中所含的铊的灰尘以固化状态存在并且沉积在废热锅炉等的蒸发管的表面上的灰尘被回收,而不必设置第一袋式过滤器, 并且从灰尘中回收铊。 版权所有(C)2010,JPO&INPIT
    • 5. 发明专利
    • Automatic coating removal device of combustion gas bleeding probe
    • 燃气喷射探头的自动涂层去除装置
    • JP2009228984A
    • 2009-10-08
    • JP2008074942
    • 2008-03-24
    • Taiheiyo Cement Corp太平洋セメント株式会社
    • SAKAMOTO YUKINORISAITO SHINICHIRO
    • F27D25/00C04B7/60F27D17/00
    • Y02P10/283
    • PROBLEM TO BE SOLVED: To improve the operation rate of a facility having a probe installed therein such as a chlorine bypass facility in cement baking that does not require a coating attached on an inner wall facing bleeding gas of a probe that bleeds combustion gas to be manually removed. SOLUTION: The automatic coating removal device 1 of a combustion gas bleeding probe for automatically removing the coating C attached on the inner wall 12b of the probe 11 for bleeding the combustion gas G includes a removal means 3 for removing the coating C by closely contacting or slidingly contacting the inner wall 12b of the probe 11 while moving to a combustion gas bleeding side end of the probe 11 during operation of the removal device 1. When the removing device 1 is in a stationary state, the removal means 3 becomes stationary in a position away from the combustion gas bleeding side end of the probe 11. As the removal means 3, four scraping chains fixed so as to have a cross shape when seen from the axial direction of a rotary shaft 2 pivotally moving in the axial direction of the probe 11 during operation of the removal device 1, is used. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提高其中安装有探头的设备的操作速度,例如水泥烘烤中的氯旁路设备,其不需要附着在面向出口燃烧的探针的渗出气体的内壁的内壁 气体被手动取出。 解决方案:用于自动除去附着在用于排出燃烧气体G的探针11的内壁12b上的涂层C的燃烧气体排出探针的自动涂层去除装置1包括:去除装置3,用于通过 在移除装置1的操作期间移动到探头11的燃烧气体排出侧端部时紧密接触或滑动地接触探针11的内壁12b。当移除装置1处于静止状态时,移除装置3变为 在离开探头11的燃烧气体排出侧端部的位置固定。作为移除装置3,从旋转轴2的轴向观察到的四个刮板固定成十字形状,该旋转轴2以轴向方向 使用在移除装置1的操作期间探针11的方向。 版权所有(C)2010,JPO&INPIT
    • 6. 发明专利
    • Treatment system of combustible waste containing metals and chlorine
    • 含有金属和氯化物的可燃废物处理系统
    • JP2009165919A
    • 2009-07-30
    • JP2008004463
    • 2008-01-11
    • Taiheiyo Cement Corp太平洋セメント株式会社
    • TERASAKI JUNICHISAITO SHINICHIROHANADA TAKASHI
    • B09B3/00B09B5/00C04B7/38C04B7/44
    • PROBLEM TO BE SOLVED: To reduce the content of heavy metals in cement by accelerating the volatilization of heavy metals such as lead or the like in a cement kiln while efficiently subjecting combustible waste, which contains metals such as ASR or the like and chlorine, to recycling treatment.
      SOLUTION: This treatment system 1 of the combustible waste containing metals and chlorine is equipped with grinding means 4 and 5 for grinding the combustible waste containing the metals and chlorine or a combustible component obtained by removing foreign matter containing a predetermined metal from the combustible waste, foreign matter removing means 2 and 3 for removing the foreign matter containing the predetermined metal from the combustible waste before ground by the grinding means or the combustible waste after ground by the grinding means to obtain the combustible component and a charging means 10 for charging the combustible component obtained through the grinding means and the foreign matter removing means in the cement kiln 11 or a calcination furnace 16, and is further equipped with a particle size adjusting means for adjusting the particle size of the combustible component obtained through the grinding means and the foreign matter removing means and the combustible component of which the particle size is adjusted by the particle size adjusting means can be charged in the cement kiln or the like by the charging means.
      COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:通过在水泥窑中加速重金属如铅等的挥发来降低水泥中重金属的含量,同时有效地对含有诸如ASR等的金属的可燃废物和 氯,回收处理。 解决方案:含有金属和氯的可燃废物的处理系统1装备有用于研磨含有金属和氯的可燃废物的研磨装置4和5,或通过从含有预定金属的物质中除去含有预定金属的异物获得的可燃组分 可燃废物,异物移除装置2和3,用于通过研磨装置或研磨装置接地后的可燃废物从研磨前的可燃废物或研磨装置接地后的可燃废物中除去含有预定金属的异物,以获得可燃组分和用于 将通过研磨装置获得的可燃组分和异物移除装置装入水泥窑11或煅烧炉16中,并且还装备有调节通过研磨装置获得的可燃组分的颗粒尺寸的粒度调节装置 和异物去除装置和可燃组合物 其粒径可以通过粒度调节装置进行调整,可以通过充电装置装入水泥窑等中。 版权所有(C)2009,JPO&INPIT
    • 7. 发明专利
    • Treating method and treating device for asbestos-containing material
    • 含有物质的材料的处理方法和处理装置
    • JP2008272561A
    • 2008-11-13
    • JP2006306193
    • 2006-11-13
    • Taiheiyo Cement Corp太平洋セメント株式会社
    • SUZUKI TAKAHIKOSAITO SHINICHIRO
    • B09B3/00A62D3/40A62D101/41C04B7/44
    • Y02P40/121Y02P40/126
    • PROBLEM TO BE SOLVED: To detoxify an asbestos-containing material while ensuring safety to workers and make the effective use of fuel energy used for the detoxification and the detoxification processing-received asbestos. SOLUTION: After an asbestos-containing material is pulverized to be 90 μm or larger and 5 mm or smaller in size, the pulverized material is mixed with liquid fuel to generate slurry, and then the slurry is sprayed into a cement kiln through a main burner or a slurry-exclusive burner. After the asbestos-containing material is mixed with the liquid fuel, the material is pulverized to be 90 μm or larger and 5 mm or smaller in size, and the slurry thus generated can be sprayed into the cement kiln. As the asbestos-containing material is handled in a slurry state, the asbestos is prevented from scattering to ensure safety to workers, and the liquid fuel itself contained in the slurry burns to form a high-temperature frame, and the asbestos is denatured to be a harmless material. A waste oil as the liquid fuel is added at a rate of 20 mass% or larger and 500 mass% or smaller to the asbestos-containing material. The slurry is preferably sprayed at a speed of 10 m/s or larger and 50 m/s or smaller. COPYRIGHT: (C)2009,JPO&INPIT
    • 要解决的问题:在确保工人安全的同时解毒含石棉材料,并有效利用用于解毒和解毒处理的石油。 解决方案:将含有石棉的材料粉碎成90μm以上且5mm以下的尺寸时,将粉碎物与液体燃料混合以产生浆料,然后将浆料喷射到水泥窑中 主燃烧器或浆液专用燃烧器。 在将含石棉材料与液体燃料混合后,将其粉碎成90μm以上且5mm以下,由此生成的浆料能够喷射到水泥窑内。 由于含石棉材料以浆液状态处理,所以防止石棉飞散以确保工人的安全,并且包含在浆料中的液体燃料本身燃烧形成高温框架,石棉变性为 一种无害的材料。 作为液体燃料的废油以相对于含石棉材料为20质量%以上且500质量%以下的速度添加。 浆料优选以10m / s或更大且50m / s或更小的速度喷涂。 版权所有(C)2009,JPO&INPIT
    • 8. 发明专利
    • Method of removing unburned carbon from fly ash
    • 从飞灰除去未燃烧的碳的方法
    • JP2007007485A
    • 2007-01-18
    • JP2003350449
    • 2003-10-09
    • Mitsui Eng & Shipbuild Co LtdTaiheiyo Cement Corp三井造船株式会社太平洋セメント株式会社
    • SAITO SHINICHIROABE KAZUOKIMOTO KOSUKEMURATA TOSHIAKI
    • B03D1/02B03D1/10B03D1/12B09B3/00
    • B03D1/02C04B18/08Y02W30/92C04B20/02
    • PROBLEM TO BE SOLVED: To efficiently remove unburned carbon from fly ash and to attain effective utilization of the fly ash and removed unburned carbon. SOLUTION: Water is added to the fly ash to obtain a slurry. A collector is added to the slurry and shearing force is applied to the slurry and the collector to attain surface modification. Then the mixture is subjected to flotation operation at which the unburned carbon of the fly ash is attached to froth and is surfaced. Application of the shearing force to the slurry and the collector can be carried out by means of a submerged agitator whereby agitation power of 0.7 to 10kWh/m 3 per unit quantity of slurry is applied. Fly ash concentration of the slurry is in a range of 3 to 50 wt.% and amount of the added collector is in a range of 5 to 100 wt.% based on the amount of the unburned carbon of the fly ash. The unburned carbon separated by flotation can be used as fuel and the fly ash (a product) having its unburned carbon content reduced to 1 wt.% or below can be used as a cement mixing material or a raw material for production of lightweight aggregate. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:有效地从飞灰中去除未燃烧的碳,并且有效地利用飞灰和去除未燃烧的碳。 解决方案:向飞灰中加入水以获得浆料。 向浆料中加入收集器,并将剪切力施加到浆料和收集器以获得表面改性。 然后将混合物进行浮选操作,在该浮选操作中,飞灰的未燃烧碳附着在泡沫上并露出。 施加剪切力到浆料和收集器可以通过浸没式搅拌器进行,由此施加每单位量浆料的0.7至10kWh / m 3 / SP的搅拌功率。 浆料的飞灰浓度在3〜50重量%的范围内,添加的收集器的量相对于飞灰的未燃烧碳的量为5〜100重量%。 通过浮选分离的未燃炭可以用作燃料,并且其未燃烧碳含量降低至1重量%以下的飞灰(产品)可以用作水泥混合材料或用于生产轻骨料的原料。 版权所有(C)2007,JPO&INPIT
    • 9. 发明专利
    • Chlorination method and treatment apparatus
    • 氯化方法和处理装置
    • JP2005289708A
    • 2005-10-20
    • JP2004106018
    • 2004-03-31
    • Taiheiyo Cement Corp太平洋セメント株式会社
    • OKAMURA SOICHIROMATSUYOSHI TAKESHISAITO SHINICHIRO
    • C04B7/60
    • PROBLEM TO BE SOLVED: To provide a chlorination apparatus etc., by which a target value for management of a chlorine concentration in cement can be set high and an amount of activation of recycling resources can be increased.
      SOLUTION: The chlorination apparatus for adding and treating the chlorine included in the combustion gas extracted from a kiln exhaust gas flow passage from the kiln hip of a cement kiln 1 down to a cyclone of the lowermost stage as a slurry or brine to a rear stage of a cement firing process is equipped with a feeder 25 for the slurry or the brine and a concentration meter 21 for measuring the chlorine concentration in the slurry or the brine or/and a flow meter 26 for measuring the flow rate thereof and a controller for controlling the feeding rate of the slurry etc., by the feeder 25 according to the chlorine concentration measured by the concentration meter 21 or/and the flow rate of the slurry or the brine measured by the flow meter 26. The fluctuation in the chlorine concentration in the cement is suppressed and the target value for management is set high by controlling the feeding rate etc., of the slurry containing the chlorine in correspondence to the chlorine concentration in the cement.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 待解决的问题:为了提供氯化装置等,通过该装置可以将用于管理水泥中的氯浓度的目标值设定得高并且可以增加再循环资源的活化量。 解决方案:用于添加和处理从窑废气流动通道中提取的燃烧气体中的氯从氯化窑1的窑1下降到最下阶段的旋流器为浆料或盐水, 水泥烧制工艺的后段配备有用于浆料或盐水的进料器25和用于测量浆料或盐水中的氯浓度的浓度计21和/或用于测量其流量的流量计26, 通过进料器25根据由浓度计21测量的氯浓度和/或由流量计26测量的浆料或盐水的流量来控制浆料等的进料速度的控制器。 通过控制与氯浓度相对应的含有氯的浆料的进料速度等,可以抑制水泥中的氯浓度,将目标管理值设定得较高 在水泥中。 版权所有(C)2006,JPO&NCIPI