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1. 发明专利

JP2010144035A Method of manufacturing high molecular weight olefin polymer 有权
标题翻译：制备高分子量烯烃聚合物的方法
公开(公告)号：JP2010144035A
公开(公告)日：2010-07-01
申请号：JP2008322484
申请日：2008-12-18
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： YUKITA TAKASHI , YAMASHITA MASAHIRO , YAMADA KO , KANEYOSHI HIROMU
IPC分类号： C08F4/6592 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a method of manufacturing an olefin polymer, having a sufficiently high molecular weight and a low melting point even under the high temperature condition, at excellent polymerization activity.
SOLUTION: In the method of manufacturing the olefin polymer, an α-olefin is polymerized in the presence of a catalyst for olefin polymerization containing (A) a crosslinked metallocene compound represented by general formula (1) and (B) a compound such as (b-1) an organic aluminum oxy compound. In the formula (1), R
1 -R
12 each independently represent a hydrogen atom or the like, and at least one of R
1 and R
5 and at least one of R
8 and R
12 represent a hydrocarbon group, and R
13 and R
14 each independently represent an organic group represented by general formula (2).
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：即使在高温条件下，提供具有足够高分子量和低熔点的烯烃聚合物的制备方法，具有优异的聚合活性。解决方案：在制备烯烃聚合物的方法中，在烯烃聚合催化剂存在下聚合α-烯烃，该催化剂含有（A）由通式（1）表示的交联金属茂化合物和（B）化合物例如（b-1）有机铝氧基化合物。在式（1）中，R 1和R 2各自独立地表示氢原子等，并且R 1 SP / 和R 5 ，R SP＆lt; SP＆gt;和＆lt; SP＆gt; 12＆lt; SP＆gt;中的至少一个表示烃基，R 13和 R 14各自独立地表示由通式（2）表示的有机基团。版权所有（C）2010，JPO＆INPIT

2. 发明专利

JP2010047629A Manufacturing method for high melting point olefin polymer 审中-公开
标题翻译：高熔点烯烃聚合物的制造方法
公开(公告)号：JP2010047629A
公开(公告)日：2010-03-04
申请号：JP2008210482
申请日：2008-08-19
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： YAMASHITA MASAHIRO , YUKITA TAKASHI
IPC分类号： C08F4/6592
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method for an olefin polymer using a polymerization catalyst capable of performing polymerization at a high temperature, being excellent in polymerization activity and indicating a high melting point and a high molecular weight by the obtained polymer. SOLUTION: In the manufacturing method for the olefin polymer, 2C or more α-olefin is polymerized in the presence of the catalyst containing a crosslinked metallocene compound (A) represented by general formula [1]: and one kind or more of the compound (B) selected from an organic aluminumoxy compound (b-1), etc. (wherein M is Ti, Zr or Hf). COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种使用能够在高温下进行聚合的聚合催化剂的烯烃聚合物的制造方法，聚合活性优异，通过所得聚合物表现出高熔点和高分子量。解决方案：在烯烃聚合物的制造方法中，在含有由通式[1]表示的交联金属茂化合物（A）的催化剂存在下，将2种以上的α-烯烃聚合：选自有机铝氧化合物（b-1）等的化合物（B）（其中M为Ti，Zr或Hf）。版权所有（C）2010，JPO＆INPIT

3. 发明专利

JP2013189525A Catalyst for olefin polymerization, and method for manufacturing olefin polymer using the same 有权
标题翻译：用于烯烃聚合的催化剂和使用其制备烯烃聚合物的方法
公开(公告)号：JP2013189525A
公开(公告)日：2013-09-26
申请号：JP2012055779
申请日：2012-03-13
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： YUKITA TAKASHI , YAMASHITA MASAHIRO , KANEYOSHI HIROMU
IPC分类号： C08F4/6592 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for olefin polymerization that manufactures an olefin polymer having high stereoregularity, high molecular weight, and wide molecular weight distribution even under a high temperature condition that can be industrialized, and to provide a method for manufacturing an olefin polymer.SOLUTION: A catalyst for olefin polymerization contains: a metallocene compound (A) having two specific fluorene ligands; and at least one compound (B) selected from (b-1) an organic aluminumoxy compound, (b-2) a compound forming an ion pair by reacting with the metallocene compound (A), and (b-3) an organoaluminum compound.
摘要翻译：要解决的问题：为了提供即使在可工业化的高温条件下制造具有高立构规整性，高分子量和宽分子量分布的烯烃聚合物的烯烃聚合催化剂，并且提供一种制备烯烃的方法聚合物。溶液：用于烯烃聚合的催化剂包含：具有两个特定芴配体的茂金属化合物（A）和（b-1）有机铝氧化合物，（b-2）通过与茂金属化合物（A）反应形成离子对的化合物和（b-3）有机铝化合物的至少一种化合物（B）。

4. 发明专利

JP2011102366A Method for producing olefin polymer 审中-公开
标题翻译：生产烯烃聚合物的方法
公开(公告)号：JP2011102366A
公开(公告)日：2011-05-26
申请号：JP2009258122
申请日：2009-11-11
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： YUKITA TAKASHI , YAMASHITA MASAHIRO , YAMADA KO , KANEYOSHI HIROMU
IPC分类号： C08F4/6592 , C08F10/06
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an olefin polymer by which the olefin polymer is produced with excellent polymerization activity without lowering the melting point thereof under an industrializable high-temperature condition when olefin such as propylene is polymerized. SOLUTION: Olefin is polymerized in the presence of an olefin polymerization catalyst including a cross-linked metallocene compound shown by general formula [1] (wherein R 1 -R 12 are each independently a hydrogen atom, a halogen atom, a hydrocarbon group, a halogen-substituted hydrocarbon group, a nitrogen-containing group, an oxygen-containing group or a silicon-containing group; at least one pair of two mutually-adjacent groups selected from R 1 -R 5 and R 8 -R 12 can be bonded to each other to form a ring on condition that at least one of R 1 , R 2 , R 4 , R 5 , R 8 , R 9 , R 11 and R 12 is a halogen atom or a halogen-substituted hydrocarbon group; R 13 and R 14 are each independently a hydrogen atom, a halogen atom, a hydrocarbon group, a halogen-substituted hydrocarbon group, a nitrogen-containing group, an oxygen-containing group or a silicon-containing group and can be bonded to each other to form a ring; M is Ti, Zr or Hf; Y is a carbon atom or a silicon atom; Q is a halogen atom, a hydrocarbon group, a ≤10C neutral conjugated or non-conjugated diene, an anionic ligand or a neutral ligand which can be coordinated by a lone electron pair; j is an integer of 1-4; when j is ≥2, a plurality of Qs can be the same or different from one another). COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：解决的问题：提供一种生产烯烃聚合物的方法，其中当烯烃如丙烯聚合时，在可工业化的高温条件下，在不降低其熔点的情况下制备具有优异聚合活性的烯烃聚合物。解决方案：烯烃在包含通式[1]所示的交联的茂金属化合物的烯烃聚合催化剂存在下聚合（其中R 1 = SP SP 2 -R SP 12 >各自独立地为氢原子，卤素原子，烃基，卤素取代的烃基，含氮基，含氧基或含硅基;至少一对相互相邻的两个选自R 1 -R 5 和R 8 -R 12 的基团可以彼此键合形成条件是R 1 ，R 2 ，R 4 ，R 5 ，R R SP＆lt; SP＆gt;，＆lt; SP＆gt;＆lt; SP＆gt;和＆lt; SP＆gt; 12＆lt; SP＆gt;是卤素原子或卤素取代的烃基; R 13和R 14各自独立地为氢原子，卤素原子，烃基，卤素取代的烃基，含氮基，氧原子，含有基团或含硅基团彼此结合形成环; M是Ti，Zr或Hf; Y是碳原子或硅原子; Q是卤素原子，烃基，≤10C中性共轭或非共轭二烯，阴离子配位体或可通过单电子对配位的中性配体; j为1-4的整数; 当j为≥2时，多个Q可以相同或不同）。版权所有（C）2011，JPO＆INPIT

5. 发明专利

JP2010144036A Method of manufacturing high melting point olefin polymer 审中-公开
标题翻译：制备高熔点烯烃聚合物的方法
公开(公告)号：JP2010144036A
公开(公告)日：2010-07-01
申请号：JP2008322485
申请日：2008-12-18
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： YUKITA TAKASHI , YAMASHITA MASAHIRO , YAMADA KO , KANEYOSHI HIROMU
IPC分类号： C08F4/6592 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a method of manufacturing an olefin polymer capable of manufacturing the olefin polymer having a sufficiently high melting point at excellent polymerization activity.
SOLUTION: In the method of manufacturing the high melting point olefin polymer, an α-olefin is polymerized in the presence of a catalyst for olefin polymerization, containing (A) a crosslinked metallocene compound represented by general formula (1) and (B) a compound such as (b-1) an organic aluminum oxy compound, under the condition of 0.2 MPa-G or more at 40°C or higher.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种制备能够以优异聚合活性制备具有足够高熔点的烯烃聚合物的烯烃聚合物的方法。解决方案：在制备高熔点烯烃聚合物的方法中，α-烯烃在烯烃聚合催化剂存在下聚合，其中含有（A）由通式（1）表示的交联的茂金属化合物和（ B）化合物如（b-1）有机铝氧基化合物，在40℃以上的条件下为0.2MPa-G以上。版权所有（C）2010，JPO＆INPIT

6. 发明专利

JP2014073983A Novel metallocene compound, olefin polymerization catalyst, and production process of olefin polymer 审中-公开
标题翻译：新型金属化合物，烯烃聚合催化剂和烯烃聚合物的生产工艺
公开(公告)号：JP2014073983A
公开(公告)日：2014-04-24
申请号：JP2012221368
申请日：2012-10-03
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： YAMASHITA MASAHIRO , HIBARA MAYUMI , SHIMAZAKI TOSHIYUKI , YUKITA TAKASHI , KANEYOSHI HIROMU
IPC分类号： C07F17/00 , C07F7/00 , C08F4/6592 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a novel metallocene compound having a catalytic activity capable of producing an olefin polymer having high melting point and high molecular weight even under high temperature conditions which are advantageous in industrial production processes.SOLUTION: There is provided a metallocene compound represented by following formula for example. There are provided a catalyst for olefin polymerization containing the novel metallocene compound, and a production process of olefin polymers using the catalyst.
摘要翻译：要解决的问题：提供具有能够生产具有高熔点和高分子量的烯烃聚合物的催化活性的新颖的茂金属化合物，即使在有利于工业生产方法的高温条件下也是有利的。提供了茂金属化合物以下列公式表示。提供了含有新型金属茂化合物的烯烃聚合催化剂和使用该催化剂的烯烃聚合物的生产方法。

7. 发明专利

JP2011122118A Method of manufacturing olefin polymer 审中-公开
标题翻译：制备烯烃聚合物的方法
公开(公告)号：JP2011122118A
公开(公告)日：2011-06-23
申请号：JP2009283038
申请日：2009-12-14
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： YUKITA TAKASHI , YAMADA KO , YAMASHITA MASAHIRO , KANEYOSHI HIROMU
IPC分类号： C08F4/6592 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide a method of manufacturing polymer which has a fully wide molecular weight distribution and a high melting point of the polymer in a high-temperature condition which can be industrialized when polymerizing olefins such as propylene. SOLUTION: The method of manufacturing an olefin polymer is characterized in that at least one monomer chosen from two or more-carbon number α-olefins is polymerized at least at 40°C under the presence of an olefin polymerization catalyst containing (A) a crosslinking metallocene compound expressed by formula [1], and (B) a compound chosen from (b-1) an organoaluminumoxy compound or the like. R 1 -R 12 each independently denote a hydrogen atom, halogen atom, hydrocarbon group or the like, and at least a pair mutually adjacent two groups chosen from R 1 -R 5 and R 8 -R 12 may be jointed to form a ring. However, at least one of R 1 , R 2 , R 3 , R 4 , R 5 , R 8 , R 9 , R 10 , R 11 , and R 12 denotes a fluorine atom. R 13 and R 14 each independently denote a hydrogen atom, halogen atom, hydrocarbon group or the like, and R 13 and R 14 may be jointed to form a ring. M denotes Ti, Zr or Hf; Y denotes a carbon atom or silicon atom; and Q denotes a halogen atom, hydrocarbon group, at most 10C neutral conjugated or nonconjugated diene, anion ligand or neutral ligand in which coordination is possible by a lone electron pair. j denotes an integer of 1-4, and two or more Q may be the same or different mutually when j is two or more. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种在聚合烯烃如丙烯时可以工业化的高温条件下聚合物具有完全宽分子量分布和高熔点的聚合物的方法。解决方案：制备烯烃聚合物的方法的特征在于，至少一种选自两个或多个碳数α-烯烃的单体在至少40℃下在含有（A ）由式[1]表示的交联茂金属化合物和（B）选自（b-1）有机铝氧化合物等的化合物。 R“SP”12各自独立地表示氢原子，卤素原子，烃基等，以及至少一对相互相邻的两个选自R“ 1 -R 5 和R 8 -R 12 可以连接形成环。然而，R 1 ，R 2 ，R 3 ，R 4 ，R 5 ，R 8 ，R 9 ，R 10 ，R SP SP 11， > 12 表示氟原子。 R 13和R 14各自独立地表示氢原子，卤素原子，烃基等，R 13和R 14均为氢， 14 可以连接成环。 M表示Ti，Zr或Hf; Y表示碳原子或硅原子; Q表示卤素原子，烃基，至多10个中性共轭或非共轭二烯，阴离子配位体或中性配体，其中可通过单电子对进行配位。 j表示1-4的整数，当j为2以上时，两个以上的Q可以相同或不同。版权所有（C）2011，JPO＆INPIT

8. 发明专利

JP2010120878A Method for producing fluorene derivative 有权
标题翻译：生产氟代衍生物的方法
公开(公告)号：JP2010120878A
公开(公告)日：2010-06-03
申请号：JP2008295828
申请日：2008-11-19
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： YAMADA KO , YUKITA TAKASHI , YAMASHITA MASAHIRO , KANEYOSHI HIROMU
IPC分类号： C07C1/32 , B01J31/04 , B01J31/24 , C07B61/00 , C07C15/60 , C07C17/263 , C07C22/08 , C07C25/22 , C07C41/30 , C07C43/205
CPC分类号： Y02P20/52
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a fluorene derivative in excellent reactivity with good yield. SOLUTION: The method for producing the fluorene derivative is the one for producing a specific fluorene derivative by reacting a specified fluorene compound (A) with a specific boron compound (B) in the presence of a base (C), and includes carrying out the reaction in a water-containing solvent (F) by using a phosphorus compound (D) represented by formula [6] and a palladium compound (E) as catalysts. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：提供以良好的收率产生优异的反应性的芴衍生物的方法。解决方案：用于制备芴衍生物的方法是通过在碱（C）的存在下使指定的芴化合物（A）与特定的硼化合物（B）反应制备特定的芴衍生物的方法，并且包括通过使用由式[6]表示的磷化合物（D）和钯化合物（E）作为催化剂，在含水溶剂（F）中进行反应。版权所有（C）2010，JPO＆INPIT

9. 发明专利

JP2010047628A Manufacturing method for olefin polymer by highly active catalyst 审中-公开
标题翻译：通过高活性催化剂制备烯烃聚合物的制备方法
公开(公告)号：JP2010047628A
公开(公告)日：2010-03-04
申请号：JP2008210481
申请日：2008-08-19
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： YAMASHITA MASAHIRO , YUKITA TAKASHI , NAKAMURA TATSUYA
IPC分类号： C08F4/6592
摘要： PROBLEM TO BE SOLVED: To provide a manufacturing method for an olefin polymer using a polymerization catalyst being excellent in polymerization activity, indicating a high melting point and a high molecular weight by the obtained polymer and capable of performing polymerization at a high temperature.
SOLUTION: In the manufacturing method for the olefin polymer, 2C or more α-olefin is polymerized in the presence of the catalyst containing a crosslinked metallocene compound (A) represented by general formula [1]: and compound (B) selected from an organic aluminumoxy compound (b-1), etc. (wherein M is Ti, Zr or Hf).
COPYRIGHT: (C)2010,JPO&INPIT

10. 发明专利

JP2009144148A Olefin polymerization catalyst and method for producing ethylene polymer using the same 有权
标题翻译：烯烃聚合催化剂及其制备使用乙烯聚合物的方法
公开(公告)号：JP2009144148A
公开(公告)日：2009-07-02
申请号：JP2008295947
申请日：2008-11-19
申请人： Mitsui Chemicals Inc , Prime Polymer Co Ltd , 三井化学株式会社 , 株式会社プライムポリマー
发明人： BANDO HIDEKI , SATO YASUO , YUKITA TAKASHI , SONOBE YOSHIO , HARADA YASUYUKI
IPC分类号： C08F4/646
摘要： PROBLEM TO BE SOLVED: To provide an olefin polymerization catalyst capable of producing an olefin polymer having a high melt tension, excellent mechanical strength and excellent particle characteristics with high polymerization activity. SOLUTION: The olefin polymerization catalyst comprises component (A) (a bridged metallocene compound represented by general formula (I)), component (B) (a bridged metallocene compound represented by general formula (II)), and component (C) (an organoaluminum oxy-compound or the like). COPYRIGHT: (C)2009,JPO&INPIT

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