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1. 发明授权

US5274071A Wholly aromatic polyamide 失效
标题翻译：全芳香族聚酰胺
公开(公告)号：US5274071A
公开(公告)日：1993-12-28
申请号：US649575
申请日：1991-02-01
申请人： Toshihiro Santa , Tsutomu Kiriyama
发明人： Toshihiro Santa , Tsutomu Kiriyama
IPC分类号： C08G69/32 , C08G69/12
CPC分类号： C08G69/32 , Y10T428/31725
摘要： A wholly aromatic polyamide capable of being dissolved in organic solvents to form an isotropic dope solution and having an excellent chemical resistance, heat resistance, processability and mechanical strength and a high modulus, comprises recurring aromatic dicarbonyl units of the formulae: ##STR1## and recurring aromatic diamine units of the formulae: ##STR2## wherein R and R' are a hydrogen or halogen atom or an alkyl or alkoxyl radical, n is 1 to 3, and p and q are 1 to 4.

2. 发明授权

US5006629A Wholly aromatic polyamide copolymer 失效
标题翻译：全芳香族聚酰胺共聚物
公开(公告)号：US5006629A
公开(公告)日：1991-04-09
申请号：US428898
申请日：1989-10-30
申请人： Toshihiro Santa , Tsutomu Kiriyama
发明人： Toshihiro Santa , Tsutomu Kiriyama
IPC分类号： C08G69/32
CPC分类号： C08G69/32
摘要： A wholly aromatic polyamide copolymer having excellent heat, flame and chemical resistances, solubility in organic solvents and shaping property and useful for shaped article having a high mechanical strength and modulus of elasticity, comprising the repeating units of the formulae: ##STR1## and at least one member selected from ##STR2## wherein X=a halogen atom, n, or m=1 to 4 and n+m=1 to 8.

3. 发明授权

US4526735A Process for producing fibrous assembly 失效
标题翻译：纤维集合体的制造方法
公开(公告)号：US4526735A
公开(公告)日：1985-07-02
申请号：US465339
申请日：1983-02-09
申请人： Susumu Norota , Yasuhiko Segawa , Tsutomu Kiriyama , Shingo Emi , Tadasi Imoto , Tetsuo Yamauchi
发明人： Susumu Norota , Yasuhiko Segawa , Tsutomu Kiriyama , Shingo Emi , Tadasi Imoto , Tetsuo Yamauchi
IPC分类号： B29C47/12 , B29C47/86 , D01D4/02 , D01D5/08 , D01D13/00 , D01F1/02 , D01F6/60 , B29F3/08
CPC分类号： B29C47/86 , B29C47/0014 , B29C47/12 , B29C47/862 , B29C47/90 , B29C47/908 , D01D13/00 , D01D4/02 , D01D5/08 , D01F1/02 , D01F6/605 , B29C47/0016 , Y10S264/46
摘要： A process and apparatus for producing a fibrous assembly. At least one fiber-forming polymer is extruded through a spinneret having numerous small openings. The process uses a die equipped with a spinneret having numerous closely spaced small openings and an opening ratio (.alpha.) of at least 30%. At least one fiber-forming polymer in the form of a shaped mass having a specified compression resistance is continuously stuffed into said die. Said shaped mass has a shape such that it measures more in one direction than in another. There is passed through the spinneret an electric current sufficient to give said fiber-forming polymer Joule heat required for cutting said polymer by partitioning members defining the numerous small openings of the spinneret. The cut fiber-forming polymer is taken up as fine streams.The present invention provides ultrathick aromatic polyamide fibers having an average cross-sectional area of about 0.01 mm.sup.2 to about 5 mm.sup.2 and comprising at least one fiber-forming aromatic polyamide and an inorganic or metallic fine powder or a fibrous material.
摘要翻译：用于生产纤维集合体的方法和设备。至少一种纤维形成聚合物通过具有许多小孔的喷丝头挤出。该方法使用装备有具有多个紧密间隔的小开口的喷丝头的模具和至少30％的开口率（α）。将具有特定抗压性的成形块形式的至少一种纤维形成聚合物连续地填充到所述模具中。所述成形块具有使得其在一个方向上比另一个方向更多的形状。通过喷丝头使电流足以使所述纤维形成聚合物焦耳热通过限定喷丝头的许多小开口的分隔构件切割所述聚合物所需的热量。切割的纤维形成聚合物被吸收为细小的流。本发明提供平均横截面积为约0.01mm 2至约5mm 2的超薄芳族聚酰胺纤维，并且包含至少一种成纤芳香族聚酰胺和无机或金属细粉或纤维材料。

4. 发明授权

US4429006A Filament-like fibers and bundles thereof, and novel process and apparatus for production thereof 失效
标题翻译：丝状纤维及其束，以及其生产方法和设备
公开(公告)号：US4429006A
公开(公告)日：1984-01-31
申请号：US394892
申请日：1982-07-02
申请人： Susumu Norota , Tsutomu Kiriyama , Tadashi Imoto , Toshinori Azumi
发明人： Susumu Norota , Tsutomu Kiriyama , Tadashi Imoto , Toshinori Azumi
IPC分类号： D01D5/20 , D01D5/253 , D02G3/00
CPC分类号： D01D5/30 , D01D5/20 , D01D5/253 , Y10T428/2913 , Y10T428/2922 , Y10T428/2929 , Y10T428/2973 , Y10T428/2976 , Y10T428/2978
摘要： A novel filament composed of at least one thermoplastic synthetic polymer, said filament being characterized by having (1) an irregular variation in the size of its cross section along its longitudinal direction, and (2) a coefficient of intrafilament cross-sectional area variation [CV(F)] of 0.05 to 1.0; and a novel bundle of said filament. The bundle of filament-like fibers can be produced by extruding a melt of a thermoplastic synthetic polymer through a spinneret having numerous small openings, which comprises extruding said melt from said spinneret, said spinneret having such a structure that discontinuous elevations are provided between adjacent small openings on the extruding side of the spinneret, and the melt extruded from one opening can move to and from the melt extruded from another opening adjacent thereto or vice versa through a depression existing between said elevation; and taking up the extrudates from the small openings while cooling them by supplying a cooling fluid to the extrusion surface of said spinneret or its neighborhood, whereby said extrudates are converted into numerous separated fine fibrous streams and solidified.

5. 发明授权

US4568506A Process for producing an assembly of many fibers 失效
标题翻译：用于生产许多纤维的组件的方法
公开(公告)号：US4568506A
公开(公告)日：1986-02-04
申请号：US500229
申请日：1983-06-01
申请人： Tsutomu Kiriyama , Susumu Norota , Yasuhiko Segawa , Shingo Emi , Tadasi Imoto , Toshinori Azumi
发明人： Tsutomu Kiriyama , Susumu Norota , Yasuhiko Segawa , Shingo Emi , Tadasi Imoto , Toshinori Azumi
IPC分类号： B01F5/06 , D01D5/30 , D01D5/32 , B29C47/30 , D01D4/02 , D01D5/40
CPC分类号： D01D5/253 , B01F5/0604 , D01D5/30 , Y10S264/75 , Y10T428/2931 , Y10T428/2973 , Y10T428/2976 , Y10T428/2978 , Y10T428/298
摘要： An assembly of fibers composed of at least two dissimilar fiber-forming polymers, characterized by the fact that(1) it consists of numerous fibers,(2) at least 90% of said fibers have a non-circular cross-sectional shape,(3) the cross-sections of at least 50% of said fibers differ from each other in at least one of shape and size, and(4) at least 50% of said fibers each have in their cross-section taken at right angles to the fiber axis at least two side-by-side coalesced blocks of at least two dissimilar fiber-forming polymer phases with at least a part thereof being exposed to the peripheral surface of the fiber, at least one of the number, shape and size of the blocks varying from fiber to fiber. The assembly of fibers can be produced by extruding a molten macroblend composed of many molten phases of at least two dissimilar fiber-forming polymers through a mesh spinneret having many small openings; and taking up the extrudates from the small openings while cooling them by supplying a cooling fluid to the extrusion surface of said spinneret or to its neighborhood, whereby said extrudates are converted into numerous separated fine fibrous streams and solidified.

6. 发明授权

US4355075A Novel filament-like fibers and bundles thereof, and novel process and apparatus for production thereof 失效
标题翻译：新颖的丝状纤维及其束，以及用于生产它的新颖工艺和装置
公开(公告)号：US4355075A
公开(公告)日：1982-10-19
申请号：US133288
申请日：1980-03-24
申请人： Susumu Norota , Tsutomu Kiriyama , Tadashi Imoto , Toshinori Azumi
发明人： Susumu Norota , Tsutomu Kiriyama , Tadashi Imoto , Toshinori Azumi
IPC分类号： D01D5/20 , D01D5/253 , D02G3/00
CPC分类号： D01D5/30 , D01D5/20 , D01D5/253 , Y10T428/2913 , Y10T428/2922 , Y10T428/2929 , Y10T428/2973 , Y10T428/2976 , Y10T428/2978
摘要： A novel filament composed of at least one thermoplastic synthetic polymer, said filament being characterized by having (1) an irregular variation in the size of its cross section along its longitudinal direction, and (2) a coefficient of intrafilament cross-sectional area variation [CV(F)] of 0.05 to 1.0; and a novel bundle of said filament. The bundle of filament-like fibers can be produced by extruding a melt of a thermoplastic synthetic polymer through a spinneret having numerous small openings, which comprises extruding said melt from said spinneret, said spinneret having such a structure that discontinuous elevations are provided between adjacent small openings on the extruding side of the spinneret, and the melt extruded from one opening can move to and from the melt extruded from another opening adjacent thereto or vice versa through a depression existing between said elevation; and taking up the extrudates from the small openings while cooling them by supplying a cooling fluid to the extrusion surface of said spinneret or its neighborhood, whereby said extrudates are converted into numerous separated fine fibrous streams and solidified.
摘要翻译：一种由至少一种热塑性合成聚合物组成的新型细丝，所述长丝的特征在于具有（1）沿着其纵向方向的横截面尺寸的不规则变化，和（2）内部纱线横截面积变化系数[ CV（F）]为0.05〜1.0; 和所述细丝的新颖的束。长丝状纤维束可以通过将热塑性合成聚合物的熔体挤出通过具有许多小孔的喷丝板来制造，该喷丝头包括从所述喷丝头挤出所述熔体，所述喷丝头具有这样的结构，即在相邻的小孔之间设置不连续的高度在喷丝头的挤出侧上的开口，从一个开口挤出的熔体可以移动到从与其相邻的另一开口挤出的熔体或反之亦然，通过存在于所述高度之间的凹陷; 并且通过向所述喷丝头或其附近的挤出表面供应冷却流体来冷却它们从小开口处取出挤出物，由此将所述挤出物转化成许多分离的细纤维流并固化。

7. 发明授权

US4288484A Novel fibrous assembly and process for production thereof 失效
标题翻译：新型纤维集合体及其制造方法
公开(公告)号：US4288484A
公开(公告)日：1981-09-08
申请号：US46753
申请日：1979-06-08
申请人： Susumu Norota , Tsutomu Kiriyama , Tadasi Imoto
发明人： Susumu Norota , Tsutomu Kiriyama , Tadasi Imoto
IPC分类号： B01D39/08 , D04H13/00 , B32B5/12
CPC分类号： B01D39/1623 , B01D39/08 , D04H13/00 , B01D2239/04 , B01D2239/0457 , B01D2239/0464 , B01D2239/0636 , B01D2239/065 , B01D2239/0654 , B01D2239/0668 , B01D2239/0681 , B01D2239/1233 , Y10S264/08 , Y10T428/24124 , Y10T428/24479 , Y10T428/24612 , Y10T428/24802 , Y10T428/2922 , Y10T428/2929 , Y10T428/2973
摘要： A fibrous assembly of many fibers, the individual constituent fibers being interconnected at random in a spaced-apart relationship so that when spread in a direction at right angles to the longitudinal axes of the fibers, said assembly can form a continuous integral reticulated structure; said individual fibers having asymmetrical irregularly-shaped cross sections of substantially different profiles and sizes from one another when said assembly is cut at right angles to the longitudinal axes of the fibers at an arbitrary point therealong; at least 40% of the entire cross-sectional area of each fiber consisting of at least two different polymer phases which are coalesced side-by-side as at least two irregular blocks; and each of the individual fibers of said assembly having a non-uniform cross-sectional shape along its longitudinal axis; fibrous structures prepared from a plurality of such fibrous assemblies; and a process for producing such fibrous assembly.
摘要翻译：许多纤维的纤维集合体，各个构成纤维以间隔的关系随机地相互连接，使得当沿与纤维的纵向轴线成直角的方向扩展时，所述组件可以形成连续的整体网状结构; 所述单根纤维具有不对称的不规则形状的横截面，当所述组件在与所述纤维的纵向轴线成直角的任意点被切割时，彼此具有基本不同的轮廓和尺寸; 由至少两个不同的聚合物相组成的每个纤维的整个横截面积的至少40％，其至少两个不规则块并排聚结; 并且所述组件的各个纤维沿其纵向轴线具有不均匀的横截面形状; 由多个这样的纤维集合体制备的纤维结构; 以及这种纤维集合体的制造方法。

8. 发明授权

US5177175A Fiber of wholly aromatic copolyamide from 2,6-naphthalene dicarboxylic acid and 3,4'-diaminodiphenylether 失效
标题翻译：来自2,6-萘二甲酸二异氰酸酯和3,4'-二氨基二苯基甲烷的芳香族芳族酰胺纤维
公开(公告)号：US5177175A
公开(公告)日：1993-01-05
申请号：US604061
申请日：1990-10-26
申请人： Tsutomu Kiriyama , Toshihiro Santa
发明人： Tsutomu Kiriyama , Toshihiro Santa
IPC分类号： C08G69/26 , C08G69/32 , D01F6/80
CPC分类号： C08G69/32 , C08G69/265 , D01F6/805
摘要： A wholly aromatic copolymer and a shaped article thereof having an excellent mechanical property, high resistances to heat and chemicals, and a satisfactory processability, is composed of (1) an aromatic dicarbonyl moiety consisting of recurring dicarbonyl units (A) and (B): ##STR1## and (2) an aromatic diamine moiety consisting of recurring diamine units (C) and (D): ##STR2## and the recurring dicarbonyl units (B) being in an amount of 0.01 molar % or more but less than 20 molar % based on the total molar amount of the dicarbonyl moiety (1), and the recurring diamine units (D) being in an amount of 60 molar % or less but more than 20 molar % based on the total molar amount of the diamine moiety (2).
摘要翻译：具有优异的机械性能，高耐热性和耐化学性，以及令人满意的加工性的全芳香族共聚物及其成型体由（1）由二羰基单元（A）和（B）构成的芳香族二羰基部分组成：（A）和图像（B）和（2）由重复二胺单元（C）和（D）组成的芳族二胺部分：（C）和（D）二羰基单元（B）的量相对于二羰基部分（1）的总摩尔量为0.01摩尔％以上且小于20摩尔％，重复二胺单元（D）为60摩尔％或更少但大于20摩尔％，基于二胺部分（2）的总摩尔量。

9. 发明授权

US4619869A Biaxially oriented polyester film 失效
公开(公告)号：US4619869A
公开(公告)日：1986-10-28
申请号：US755142
申请日：1985-07-15
申请人： Tsutomu Kiriyama , Shigeru Horie , Tetsuo Ichihashi , Masahiro Oshida
发明人： Tsutomu Kiriyama , Shigeru Horie , Tetsuo Ichihashi , Masahiro Oshida
IPC分类号： C08J5/18 , G11B5/73 , B32B27/06
CPC分类号： C08J5/18 , G11B5/7305 , C08J2367/02 , Y10S428/90 , Y10T428/31786
摘要： A biaxially oriented film of a film-forming aromatic polyester derived from an aromatic dicarboxylic acid as a main acid component and an aliphatic glycol as a main glycol component, said film having surface properties such that(1) it has a surface flatness, R.sub.CLA, of from 0.001 to 0.016 micron,(2) it has a coefficient of travelling friction, .mu.k, of from 0.01 to 0.20, and(3) the following relation is established between R.sub.CLA and .mu.k,0.10.ltoreq.10.times.R.sub.CLA +.mu.k.ltoreq.0.31.Preferably, said film has many minute protrusions on its surface which are attributed to fine particles of titanium dioxide or of both titanium dioxide and calcium carbonate, and has such further surface property that(4) a distribution curve showing the relation between the heights of said many protrusions on the film surface and the numbers of the protrusions having the respective heights does not cross a straight line represented by the following equation (1)log.sub.10 y=-8.0x+4.34 (1)where x and y are as defined above, within the range of log.sub.10 >1.

10. 发明授权

US4521364A Filament-like fibers and bundles thereof, and novel process and apparatus for production thereof 失效
标题翻译：丝状纤维及其束，以及其生产方法和设备
公开(公告)号：US4521364A
公开(公告)日：1985-06-04
申请号：US394891
申请日：1982-07-02
申请人： Susumi Norota , Tsutomu Kiriyama , Tadashi Imoto , Toshinori Azumi
发明人： Susumi Norota , Tsutomu Kiriyama , Tadashi Imoto , Toshinori Azumi
IPC分类号： D01D5/20 , D01D5/253 , D01D5/088
CPC分类号： D01D5/30 , D01D5/20 , D01D5/253 , Y10T428/2913 , Y10T428/2922 , Y10T428/2929 , Y10T428/2973 , Y10T428/2976 , Y10T428/2978
摘要： A novel filament composed of at least one thermoplastic synthetic polymer, said filament being characterized by having (1) an irregular variation in the size of its cross section along its longitudinal direction, and (2) a coefficient of intrafilament cross-sectional area variation [CV(F)] of 0.05 to 1.0; and a novel bundle of said filament. The bundle of filament-like fibers can be produced by extruding a melt of a thermoplastic synthetic polymer through a spinneret having numerous small openings, which comprises extruding said melt from said spinneret, said spinneret having such a structure that discontinuous elevations are provided between adjacent small openings on the extruding side of the spinneret, and the melt extruded from one opening can move to and from the melt extruded from another opening adjacent thereto or vice versa through a depression existing between said elevation; and taking up the extrudates from the small openings while cooling them by supplying a cooling fluid to the extrusion surface of said spinneret or its neighborhood, whereby said extrudates are converted into numerous separated fine fibrous streams and solidified.

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