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    • 9. 发明授权
    • Top antireflective coating material and its process for DUV and VUV
lithography systems
    • 顶级抗反射涂层材料及其DUV和VUV光刻系统的工艺
    • US5879853A
    • 1999-03-09
    • US588085
    • 1996-01-18
    • Tsukasa Azuma
    • Tsukasa Azuma
    • G03F7/09G03F7/023G03C1/825
    • G03F7/091
    • This invention relates to a top antireflective layer (TAR) which is preferably transparent to some extent and has high-etch resistance and low reflectivity at the photoresist/TAR interface. The TAR also significantly reduces CD variation in exposed photoresist film. The TAR of the present invention comprises an indanone or glutarimide copolymer, a solvent, and an additive sensitizer having an orthodiazonaphthoquinone structure. The present invention is also related to a process of forming a semiconductor by applying a photoresist layer to the surface of a substrate, forming a top antireflection layer on the photoresist layer, and selectively exposing the substrate to ultraviolet light, wherein the TAR comprises an indanone or glutarimide copolymer, a solvent, and an additive sensitizer with an orthodiazonaphthoquinone structure.
    • 本发明涉及顶部抗反射层(TAR),其优选在一定程度上是透明的,并且在光致抗蚀剂/ TAR界面处具有高抗蚀刻性和低反射率。 TAR还显着降低了曝光光刻胶膜中的CD变化。 本发明的TAR包括具有正辛基萘醌结构的茚酮或戊二酰亚胺共聚物,溶剂和添加剂敏化剂。 本发明还涉及通过在基板的表面上施加光致抗蚀剂层形成半导体的方法,在光致抗蚀剂层上形成顶部抗反射层,并将基板选择性地暴露于紫外光下,其中TAR包括茚满酮 或戊二酰亚胺共聚物,溶剂和具有正萘醌结构的添加剂敏化剂。