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    • 1. 发明申请
    • PROCESS FOR PRODUCING ALDEHYDE
    • 生产二氢呋喃的方法
    • WO1983000484A1
    • 1983-02-17
    • PCT/JP1982000303
    • 1982-08-04
    • MITSUBISHI CHEMICAL INDUSTRIES LIMITEDTANO, KazuoSATO, KeiichiTANAKA, Hiroo
    • MITSUBISHI CHEMICAL INDUSTRIES LIMITED
    • C07C47/00
    • C07C45/50C07C47/02
    • A process for producing aldehyde by reacting an olefinic compound with carbon monoxide and hydrogen in a catalyst solution containing a rhodium compound and a tertiary phosphine, which process comprises using as the tertiary phosphine a diphenylphosphino group-containing styrene oligomer having 5 to 100 mol % of a structural unit represented by the following formula: and having a fundamental skeletal styrene oligomer of number-average polymerization degree of 3 to 350, controlling the amount of the phosphorus atom in the diphenylphosphino group-containing styrene oligomer in the range of at least 5 mols per mol of the rhodium atom in the catalyst solution, and conducting the reaction under such a condition that the catalyst solution is in a substantially uniform system.
    • 一种通过在含有铑化合物和叔膦的催化剂溶液中使烯烃化合物与一氧化碳和氢气反应来生产醛的方法,该方法包括使用具有5至100摩尔%的含二苯基膦基的苯乙烯低聚物作为叔膦 由下式表示的结构单元:< IMAGE>并且具有数均聚合度为3〜350的基本骨架苯乙烯低聚物,将含二苯基膦基的苯乙烯低聚物中的磷原子的量控制在 在催化剂溶液中每摩尔铑原子至少5摩尔,并在催化剂溶液处于基本均匀的系统的条件下进行反应。
    • 4. 发明专利
    • TRANSPORT DEVICE FOR HAND BAGGAGE AND BAG WITH THE SAME
    • JP2001087028A
    • 2001-04-03
    • JP26369199
    • 1999-09-17
    • TANAKA HIROO
    • TANAKA HIROO
    • A45C13/38A45C5/14
    • PROBLEM TO BE SOLVED: To provide a transport device which can facilitate the transportation of, a hand baggage. SOLUTION: This transport device comprises a case 7 having on its upper surface an upper opening 8 and on its lower surface a lower opening 9, a handle member 16 which is provided in a case so as to be drawn out of the upper opening, a holder member 21 which is slidably provided in the case so that a connection hole formed at its lower end can be projected out of the lower end, a mount member 22 slidably provided in the case 7, the upper end parts of which are bendably connected to the holder member in such a manner that the member 22 is drawn out of the lower opening together with the member 21 so that the upper end parts are connected to connection holes 26, 28 projecting from the lower opening, whereby the member 22 projects sideward at a predetermined angles relative to the member 21, and casters 48 provided in the case 7 to support the case 7 in its running state.
    • 5. 发明专利
    • METHOD FOR DECIDING CATION DEMAND IN SUSPENSION SYSTEM
    • JP2000258407A
    • 2000-09-22
    • JP10160099
    • 1999-03-04
    • TANAKA HIROO
    • TANAKA HIROO
    • B01D21/30B01D21/01C02F1/00C02F1/56G01N21/64G01N21/78G01N33/00
    • PROBLEM TO BE SOLVED: To measure a cation demand even under the condition of coexisting with salts of high concentration by labeling fluorescence, ultraviolet ray, or visible ray to the macromolecule itself of titration reagent. SOLUTION: A label cationic macromolecule such as fluoroscence is prepared so that cationic macromolecule containing at least a primary or secondary amino group is dissolved in a mixed system of water and organic solvent, and while stirring, labeling agent such as 5-dimethylamino-1-naphthalenesulfonyl chloride is added to it. While stirring a fixed quantity of sample, a fixed quantity of labeling cationic macromolecule water solution is added, and fluoroscence intensity or the like of the supernatant liquid or filtered liquid is measured. While increasing the addition quantity, similar operation is executed until fluorescence or the like appears, and from the addition quantity and concentration of porescribed labeling cationic macromolecule, a cation demand of suspension system sample is obtained. Thus, the optimum quantity of addition agent for effectively performing cohesion or the like of several suspension systems can be known.
    • 7. 发明专利
    • Thread cutting attachment of machine tool
    • 螺纹切割机床附件
    • JPS58211822A
    • 1983-12-09
    • JP9507482
    • 1982-06-02
    • Masaru HananoKashiwara TadashiTanaka Hiroo
    • HANANO MASARU
    • B23G3/00B23G3/04B23G3/08
    • B23G3/04
    • PURPOSE:To prevent vibration caused by a shock, in which a stopper piece hits a positioing limit part at resetting time of a turning cam, by resetting a movable holder through pull down motion of a handle and the turning cam automatically to a cutting start position. CONSTITUTION:A cam part (a), pressure receiving cam part (b) and recessed parts of a brake cam part (c), cut up positioning part (d), escape turn promoting part (e), escape turn deceleration part (f), etc. are formed to a turning cam 9. And successively to the above parts, a turning cam resetting sloped cam part (g) and an escape resetting part (h), which can automatically turn an auxiliary resetting upper subpawl 16 in parallel to the cam part (g), are provided, while a resetting sloped cam part (i) only use for the subpawl 16 is parallel to the recessed parts (e), (f) is formed in a staircase shape from the resetting part (h) partially successively to the cam part (g). In this way, interlocking to the resetting of a movable holder 2 by a resetting depressive handle 6 fixed to the holder 2, the turning cam is automatically reset to a cutting start position and thread cutting work can be repeatedly performed.
    • 目的:为了防止在通过手柄的下拉运动和转动凸轮自动切换到切割开始位置的情况下通过将可动夹持器复位而使止动片撞击转动凸轮的复位时的止挡件撞击定位极限部分而产生的振动 。 构成:凸轮部分(a),受压凸轮部分(b)和制动器凸轮部分(c)的凹陷部分,切割定位部分(d),逃生转向部分(e),逃生转弯减速部分 )等形成为转动凸轮9.并且依次连接到上述部件,转动凸轮复位倾斜凸轮部分(g)和逃生复位部分(h),其可以并行地自动地转动辅助复位上部副棘爪16 设置在凸轮部分(g)上,而仅用于副爪16的复位倾斜凸轮部分(i)平行于凹部(e),(f)从复位部分形成阶梯形状 h)部分地依次连接到凸轮部分(g)。 以这种方式,通过固定到保持器2的复位抑制手柄6与可移动保持器2的复位联动,转动凸轮自动复位到切割开始位置,并且可以重复执行螺纹切削加工。
    • 8. 发明专利
    • MACROMOLECULAR LECTROLYTE TITRATION METHOD
    • JPH0431761A
    • 1992-02-03
    • JP13808990
    • 1990-05-28
    • TANAKA HIROO
    • TANAKA HIROO
    • G01N31/16G01N21/64G01N31/22
    • PURPOSE:To make it possible to analyze cation starch, flocculant having super- high molecular weight and the like which cannot be determined by conventional methods by using super-dilute standard normal solution for determining the concentration of macromolecular electrolyte solution. CONSTITUTION:A specified % of PDMA is put into a beaker. The beaker is mounted on a magnetic stirrer which is attached to the sample chamber of a fluorescence spectrophotometer. A specified amount of AF is added during stirring, and the intensity of fluorescence is read. A specified quantity of PVSK standard solution whose concentration is lower than the normal value of 1/5,000 is added into the beaker from a microburet, and the intensity of the fluorescence is read. This operation is sequentially repeated, and the titration curve shown in the figure is obtained based on the obtained measured values. The concentra tion of the liquid under test is accurately obtained from the bending point of the titration curve.