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    • 4. 发明授权
    • Dendrimer solid acid and polymer electrolyte membrane including the same
    • 树枝状聚合物固体酸和聚合物电解质膜包括相同的
    • US08119833B2
    • 2012-02-21
    • US13176699
    • 2011-07-05
    • Myung-sup JungJin-gyu LeeSang-kook MahJae-jun Lee
    • Myung-sup JungJin-gyu LeeSang-kook MahJae-jun Lee
    • C07C309/32C07C309/42C07C309/33C07C309/44H01M8/22
    • C08J5/2256C08J5/2275C08J2300/00C08J2300/202C08J2379/08
    • Provided are a dendrimer solid acid and a polymer electrolyte membrane using the same. The polymer electrolyte membrane includes a macromolecule of a dendrimer solid acid having ionically conductive terminal groups at the surface thereof and a minimum amount of ionically conductive terminal groups required for ionic conduction, thus suppressing swelling and allowing a uniform distribution of the dendrimer solid acid, thereby improving ionic conductivity. Since the number of ionically conductive terminal groups in the polymer electrolyte membrane is minimized and the polymer matrix in which swelling is suppressed is used, methanol crossover and difficulties of outflow due to a large volume may be reduced, and a macromolecule of the dendrimer solid acid having the ionically conductive terminal groups on the surface thereof is uniformly distributed. Accordingly, ionic conductivity is high and thus, the polymer electrolyte membrane shows good ionic conductivity even in non-humidified conditions.
    • 提供了树枝状聚合物固体酸和使用其的聚合物电解质膜。 聚合物电解质膜包括其表面具有离子导电性端基的树枝状聚合物固体酸的高分子和离子传导所需的离子导电性端基的最小量,因此抑制了树枝状聚合物固体酸的均匀分布,从而 提高离子电导率。 由于聚合物电解质膜中的离子导电性端基的数量被最小化,并且使用抑制了溶胀的聚合物基体,所以甲基交联和体积大的流出困难可能降低,并且树枝状聚合物固体酸的高分子 其表面上的离子导电性端基均匀分布。 因此,离子电导率高,因此即使在非加湿条件下,高分子电解质膜也具有良好的离子传导性。
    • 5. 发明授权
    • Porous anode active material, method of preparing the same, and anode and lithium battery employing the same
    • 多孔阳极活性材料及其制备方法以及使用其的阳极和锂电池
    • US08048339B2
    • 2011-11-01
    • US11829787
    • 2007-07-27
    • Sang-kook MahHan-su KimDong-min Im
    • Sang-kook MahHan-su KimDong-min Im
    • H01B1/06H01B1/24H01M4/13
    • H01M4/134H01M4/133H01M4/1393H01M4/364H01M4/38H01M4/386H01M4/387H01M4/42H01M4/466H01M4/587H01M4/625H01M10/052H01M2004/021
    • Provided are a porous anode active material, a method of preparing the same, and an anode and a lithium battery employing the same. The porous anode active material includes fine particles of metallic substance capable of forming a lithium alloy; a crystalline carboneous substance; and a porous carboneous material coating and attaching to the fine particles of metallic substance and the crystalline carboneous substance, the porous anode active material having pores exhibiting a bimodal size distribution with two pore diameter peaks as measured by a Barrett-Joyner-Halenda (BJH) pore size distribution from a nitrogen adsorption. The porous anode active material has the pores having a bimodal size distribution, and thus may efficiently remove a stress occurring due to a difference of expansion between a carboneous material and a metallic active material during charging and discharging. Further, the anode electrode and the lithium battery comprising the anode active material have excellent charge/discharge characteristics.
    • 提供一种多孔阳极活性材料,其制备方法,以及使用其的阳极和锂电池。 多孔负极活性物质包括能够形成锂合金的金属物质微粒; 结晶碳物质; 和多孔碳质材料涂覆并附着到金属物质和结晶碳质物质的细颗粒上,多孔负极活性物质具有双孔尺寸分布,具有两孔径峰,由Barrett-Joyner-Halenda(BJH)测量, 孔径分布从氮吸附。 多孔负极活性物质具有双峰尺寸分布的孔,因此可以有效地消除由于填充和排出期间碳质材料和金属活性物质之间的膨胀差而产生的应力。 此外,阳极电极和包含阳极活性材料的锂电池具有优异的充电/放电特性。
    • 6. 发明申请
    • DENDRIMER SOLID ACID AND POLYMER ELECTROLYTE MEMBRANE INCLUDING THE SAME
    • DENDRIMER固体酸和聚合物电解质膜包括它们
    • US20110262833A1
    • 2011-10-27
    • US13176699
    • 2011-07-05
    • Myung-sup JungJin-gyu LeeSang-kook MahJae-jun Lee
    • Myung-sup JungJin-gyu LeeSang-kook MahJae-jun Lee
    • H01M8/10
    • C08J5/2256C08J5/2275C08J2300/00C08J2300/202C08J2379/08
    • Provided are a dendrimer solid acid and a polymer electrolyte membrane using the same. The polymer electrolyte membrane includes a macromolecule of a dendrimer solid acid having ionically conductive terminal groups at the surface thereof and a minimum amount of ionically conductive terminal groups required for ionic conduction, thus suppressing swelling and allowing a uniform distribution of the dendrimer solid acid, thereby improving ionic conductivity. Since the number of ionically conductive terminal groups in the polymer electrolyte membrane is minimized and the polymer matrix in which swelling is suppressed is used, methanol crossover and difficulties of outflow due to a large volume may be reduced, and a macromolecule of the dendrimer solid acid having the ionically conductive terminal groups on the surface thereof is uniformly distributed. Accordingly, ionic conductivity is high and thus, the polymer electrolyte membrane shows good ionic conductivity even in non-humidified conditions.
    • 提供了树枝状聚合物固体酸和使用其的聚合物电解质膜。 聚合物电解质膜包括其表面具有离子导电性端基的树枝状聚合物固体酸的高分子和离子传导所需的离子导电性端基的最小量,因此抑制了树枝状聚合物固体酸的均匀分布,从而 提高离子电导率。 由于聚合物电解质膜中的离子导电性端基的数量被最小化,并且使用抑制了溶胀的聚合物基体,所以甲基交联和体积大的流出困难可能降低,并且树枝状聚合物固体酸的高分子 其表面上的离子导电性端基均匀分布。 因此,离子电导率高,因此即使在非加湿条件下,高分子电解质膜也具有良好的离子传导性。