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1. 发明授权

US07361938B2 Luminescent ceramic for a light emitting device 有权
标题翻译：用于发光器件的发光陶瓷
公开(公告)号：US07361938B2
公开(公告)日：2008-04-22
申请号：US10861172
申请日：2004-06-03
申请人： Gerd O. Mueller , Regina B. Mueller-Mach , Michael R. Krames , Peter J. Schmidt , Hans-Helmut Bechtel , Joerg Meyer , Jan de Graaf , Theo Arnold Kop
发明人： Gerd O. Mueller , Regina B. Mueller-Mach , Michael R. Krames , Peter J. Schmidt , Hans-Helmut Bechtel , Joerg Meyer , Jan de Graaf , Theo Arnold Kop
IPC分类号： H01L27/15 , H01L29/22
CPC分类号： H01L33/502 , C04B35/44 , C04B35/547 , C04B35/584 , C04B35/597 , C04B35/6268 , C04B35/64 , C04B35/645 , C04B2235/3213 , C04B2235/3217 , C04B2235/3224 , C04B2235/3225 , C04B2235/3229 , C04B2235/3286 , C04B2235/6027 , C04B2235/662 , C09K11/7774 , H01L33/007 , H01L33/0075 , H01L33/0079 , H01L33/06 , H01L33/12 , H01L33/32 , H01L33/50 , H01L33/501 , H01L33/505 , H01L33/508 , H01L33/54 , H01L33/56 , H01L33/58 , H01L33/62 , H01L33/641 , H01L33/644 , H01L2924/0002 , H01L2933/0041 , H01L2933/005 , H01L2933/0066 , H01L2933/0075 , H01L2924/00
摘要： A semiconductor light emitting device comprising a light emitting layer disposed between an n-type region and a p-type region is combined with a ceramic layer which is disposed in a path of light emitted by the light emitting layer. The ceramic layer is composed of or includes a wavelength converting material such as a phosphor. Luminescent ceramic layers according to embodiments of the invention may be more robust and less sensitive to temperature than prior art phosphor layers. In addition, luminescent ceramics may exhibit less scattering and may therefore increase the conversion efficiency over prior art phosphor layers.
摘要翻译：包括设置在n型区域和p型区域之间的发光层的半导体发光器件与设置在由发光层发射的光的路径中的陶瓷层组合。陶瓷层由磷光体等波长转换材料构成或包含波长转换材料。根据本发明的实施例的发光陶瓷层可以比现有技术的荧光体层更坚固并且对温度不太敏感。此外，发光陶瓷可能表现出更少的散射，因此可以提高现有技术荧光体层的转换效率。

2. 发明授权

US07064355B2 Light emitting diodes with improved light extraction efficiency 有权
公开(公告)号：US07064355B2
公开(公告)日：2006-06-20
申请号：US09880204
申请日：2001-06-12
申请人： Michael D. Camras , Michael R. Krames , Wayne L. Snyder , Frank M. Steranka , Robert C. Taber , John J. Uebbing , Douglas W. Pocius , Troy A. Trottier , Christopher H. Lowery , Gerd O. Mueller , Regina B. Mueller-Mach , Gloria E. Hofler
发明人： Michael D. Camras , Michael R. Krames , Wayne L. Snyder , Frank M. Steranka , Robert C. Taber , John J. Uebbing , Douglas W. Pocius , Troy A. Trottier , Christopher H. Lowery , Gerd O. Mueller , Regina B. Mueller-Mach , Gloria E. Hofler
IPC分类号： H01L33/00
CPC分类号： H01L33/58 , H01L33/20 , H01L33/405 , H01L33/505 , H01L33/60
摘要： Light emitting devices with improved light extraction efficiency are provided. The light emitting devices have a stack of layers including semiconductor layers comprising an active region. The stack is bonded to a transparent optical element having a refractive index for light emitted by the active region preferably greater than about 1.5, more preferably greater than about 1.8. A method of bonding a transparent optical element (e.g., a lens or an optical concentrator) to a light emitting device comprising an active region includes elevating a temperature of the optical element and the stack and applying a pressure to press the optical element and the light emitting device together. A block of optical element material may be bonded to the light emitting device and then shaped into an optical element. Bonding a high refractive index optical element to a light emitting device improves the light extraction efficiency of the light emitting device by reducing loss due to total internal reflection. Advantageously, this improvement can be achieved without the use of an encapsulant.

3. 发明授权

US06870311B2 Light-emitting devices utilizing nanoparticles 有权
公开(公告)号：US06870311B2
公开(公告)日：2005-03-22
申请号：US10165571
申请日：2002-06-07
申请人： Gerd O. Mueller , Regina B. Mueller-Mach , Dietrich Bertram , Thomas Juestel , Peter J. Schmidt , Joachim Opitz
发明人： Gerd O. Mueller , Regina B. Mueller-Mach , Dietrich Bertram , Thomas Juestel , Peter J. Schmidt , Joachim Opitz
IPC分类号： H01L33/50 , H01L33/56 , H01J1/62 , H01J63/04
CPC分类号： H01L33/501 , H01L33/56 , H01L2933/0091
摘要： Light-emitting devices are disclosed that comprise a light source emitting first light, a first material substantially transparent to and located to receive at least a portion of the first light, and particles of a second material dispersed in the first material. The second material has an index of refraction greater than an index of refraction of the first material at a wavelength of the first light. The particles of the second material have diameters less than about this wavelength. Particles of a third material may also be dispersed in the first material.

4. 发明授权

US06696703B2 Thin film phosphor-converted light emitting diode device 有权
标题翻译：薄膜磷光体转换发光二极管器件
公开(公告)号：US06696703B2
公开(公告)日：2004-02-24
申请号：US09405938
申请日：1999-09-27
申请人： Regina B. Mueller-Mach , Gerd O. Mueller
发明人： Regina B. Mueller-Mach , Gerd O. Mueller
IPC分类号： H01L3300
CPC分类号： H01L33/50 , H01L33/46 , H01L33/504 , Y10S257/918
摘要： The present invention provides a phosphor-converted LED device comprising one or more phosphor thin films that convert primary light emitted by the LED into one or more other wavelengths of light to produce light of a particular color. Each phosphor thin film comprises dopant ions that are statistically spatially distributed in such a manner that the phosphor conversion of the primary light is predictable and controlled by the concentration of the dopants and by the thickness of the thin film. Therefore, variations in the color of the light produced by phosphor-converted LED devices can be eliminated, thereby enabling uniformity in the quality of the colored light produced to be ensured. In accordance with one embodiment of the present invention, a single phosphor thin film is comprised by the LED device. The thin film converts a portion of the primary emission into yellow light while allowing a portion of the primary blue light to pass through the thin film. The primary light and the yellow light combine to produce white light. Alternatively, a plurality of phosphor thin films, each of which emits a different color of light, may be comprised in the LED device. Each of the thin films converts a portion of primary radiation into a particular color of light, e.g., red or green light. The red light, green light and the unconverted primary light combine to form white light. Alternatively, one of the thin films completely absorbs the primary radiation and converts it into blue light. This converted blue light then functions as the primary light that undergoes phosphor conversion via one or more other phosphor thin films to produce white light. One or more thin films may be used in this manner to perform phosphor conversion to produce light of colors other than white, such as green light.
摘要翻译：本发明提供了一种磷光体转换的LED器件，其包括一个或多个荧光体薄膜，其将由LED发射的原始光转换成一个或多个其它波长的光以产生特定颜色的光。每个荧光体薄膜包括统计学上以空间分布的掺杂剂离子，使得初级光的荧光体转换是可预测的并且由掺杂剂的浓度和薄膜的厚度控制。因此，可以消除由磷光体转换的LED器件产生的光的颜色的变化，从而可以确保产生的着色光的质量的均匀性。根据本发明的一个实施例，由LED器件构成单个荧光体薄膜。薄膜将一次发射的一部分转换成黄色光，同时允许一部分蓝色蓝光通过薄膜。主光和黄光结合产生白光。或者，可以在LED器件中包含多个发射不同颜色的光的荧光体薄膜。每个薄膜将一部分初级辐射转换成特定的光色，例如红色或绿色光。红光，绿光和未转换的主光结合形成白光。或者，一个薄膜完全吸收主辐射并将其转换成蓝光。这种转换的蓝光然后用作经由一个或多个其它荧光体薄膜进行磷光体转换以产生白光的主要光。可以以这种方式使用一个或多个薄膜进行磷光体转换以产生除白色以外的其它颜色的光，例如绿光。

5. 发明授权

US06680569B2 Red-deficiency compensating phosphor light emitting device 有权
标题翻译：红色补偿荧光体发光装置
公开(公告)号：US06680569B2
公开(公告)日：2004-01-20
申请号：US10083314
申请日：2002-02-25
申请人： Regina B. Mueller-Mach , Gerd O. Mueller , Tomas Jüestel , Peter Schmidt
发明人： Regina B. Mueller-Mach , Gerd O. Mueller , Tomas Jüestel , Peter Schmidt
IPC分类号： H01J162
CPC分类号： H01L33/504 , H01L33/502
摘要： A light emitting device includes a light source that emits first light in response to an electrical signal, and a fluorescent layer positioned over the light source. The fluorescent layer includes a first fluorescent material which radiates second light and a second fluorescent material which radiates third light. In one embodiment, the second fluorescent material contains europium activated calcium sulfide. In another embodiment, the second fluorescent material contains europium activated nitrido-silicate. In some embodiments, the device includes a light propagation medium which transmits the first, second, and third light as composite output.
摘要翻译：发光装置包括响应于电信号发射第一光的光源和位于光源上方的荧光层。荧光层包括辐射第二光的第一荧光材料和辐射第三光的第二荧光材料。在一个实施方案中，第二荧光材料含有铕激活的硫化钙。在另一个实施方案中，第二荧光材料含有铕活化的氮化硅酸盐。在一些实施例中，该装置包括传播第一，第二和第三光作为复合输出的光传播介质。

6. 发明授权

US09818916B2 Incandescent-like-dimming light emitting diode 有权
公开(公告)号：US09818916B2
公开(公告)日：2017-11-14
申请号：US15254734
申请日：2016-09-01
申请人： Gerd O. Mueller , Regina B. Mueller-Mach
发明人： Gerd O. Mueller , Regina B. Mueller-Mach
IPC分类号： H01L33/50 , H01L33/32 , C09K11/61 , C09K11/62 , C09K11/77 , H05B33/08
CPC分类号： H01L33/504 , C09K11/617 , C09K11/62 , C09K11/7774 , H01L33/32 , H05B33/0857 , Y02B20/181
摘要： Phosphor-converted light emitting diodes comprising a blue or near-UV emitting semiconductor device, a yellow-green phosphor, and a red phosphor exhibit incandescent-like dimming behavior in that the Correlated Color Temperature of a white light output decreases with reduced brightness.

7. 发明申请

US20100289044A1 WAVELENGTH CONVERSION FOR PRODUCING WHITE LIGHT FROM HIGH POWER BLUE LED 审中-公开
标题翻译：用于从大功率蓝光LED生产白光的波长转换
公开(公告)号：US20100289044A1
公开(公告)日：2010-11-18
申请号：US12464327
申请日：2009-05-12
申请人： Michael R. KRAMES , Gerd O. MUELLER , Regina B. MUELLER-MACH , Hans-Helmut BECHTEL , Peter J. SCHMIDT
发明人： Michael R. KRAMES , Gerd O. MUELLER , Regina B. MUELLER-MACH , Hans-Helmut BECHTEL , Peter J. SCHMIDT
IPC分类号： H01L33/00
CPC分类号： C09K11/08 , H01L33/504 , H05B33/14 , Y02B20/181
摘要： A white light LED is described that uses an LED die that emits visible blue light in a wavelength range of about 450-470 nm. A red phosphor or quantum dot material converts some of the blue light to a visible red light having a peak wavelength between about 605-625 nm with a full-width-half-maximum (FWHM) less than 80 nm. A green phosphor or quantum dot material converts some of the blue light to a green light having a FWHM greater than 40 nm, wherein the combination of the blue light, red light, and green light produces a white light providing a color rendering of Ra,8>90 and a color temperature of between 2500K-5000K. Preferably, the red and green converting material do not saturate with an LED die output of 100 W/cm2 and can reliably operate with an LED die junction temperature over 100 degrees C.
摘要翻译：描述了使用发射在约450-470nm的波长范围内的可见蓝光的LED管芯的白光LED。红色荧光体或量子点材料将一些蓝色光转换成具有在约605-625nm之间的峰值波长和小于80nm的全宽半最大值（FWHM）的可见红光。绿色荧光体或量子点材料将一些蓝色光转换成具有大于40nm的FWHM的绿色光，其中蓝色光，红色光和绿色光的组合产生提供Ra的显色性的白色光， 8> 90，色温在2500K-5000K之间。优选地，红色和绿色转换材料对于100W / cm 2的LED管芯输出不饱和，并且可以在LED管芯结温超过100摄氏度时可靠地工作。

8. 发明申请

US20090173960A1 SEMICONDUCTOR LIGHT EMITTING DEVICE WITH PRE-FABRICATED WAVELENGTH CONVERTING ELEMENT 有权
标题翻译：具有预制波长转换元件的半导体发光器件
公开(公告)号：US20090173960A1
公开(公告)日：2009-07-09
申请号：US12403926
申请日：2009-03-13
申请人： Paul S. MARTIN , Gerd O. MUELLER , Regina B. MUELLER-MACH , Helena TICHA , Ladislav TICHY
发明人： Paul S. MARTIN , Gerd O. MUELLER , Regina B. MUELLER-MACH , Helena TICHA , Ladislav TICHY
IPC分类号： H01L33/00
CPC分类号： H01L33/501 , C03C3/12 , C03C8/10 , C03C14/004 , C03C2214/04 , C03C2214/16 , C09K11/02 , C09K11/7774 , H01L2933/0041
摘要： A semiconductor light emitting device is provided with a separately fabricated wavelength converting element. The wavelength converting element, of e.g., phosphor and glass, is produced in a sheet that is separated into individual wavelength converting elements, which are bonded to light emitting devices. The wavelength converting elements may be grouped and stored according to their wavelength converting properties. The wavelength converting elements may be selectively matched with a semiconductor light emitting device, to produce a desired mixture of primary and secondary light.
摘要翻译：半导体发光器件设置有单独制造的波长转换元件。例如磷光体和玻璃的波长转换元件在分离成各个波长转换元件的片材中产生，其结合到发光器件。波长转换元件可以根据其波长转换特性进行分组和存储。波长转换元件可以选择性地与半导体发光器件匹配，以产生所需的初级和次级光的混合。

9. 发明授权

US07521862B2 Light emitting device including luminescent ceramic and light-scattering material 有权
标题翻译：包括发光陶瓷和光散射材料的发光器件
公开(公告)号：US07521862B2
公开(公告)日：2009-04-21
申请号：US11561859
申请日：2006-11-20
申请人： Gerd O. Mueller , Regina B. Mueller-Mach
发明人： Gerd O. Mueller , Regina B. Mueller-Mach
IPC分类号： H01J1/62
CPC分类号： H01L33/501 , C04B35/584 , C04B2235/3213 , C04B2235/3215 , C04B2235/3224 , C04B2235/3865 , C04B2235/3873 , C09K11/7731 , C09K11/7734 , C09K11/7774 , H01L33/44 , H01L2933/0091 , H05B33/14
摘要： A ceramic body comprising a wavelength converting material is disposed in the path of light emitted by the light emitting region of a semiconductor structure comprising a light emitting region disposed between an n-type region and a p-type region. A layer of transparent material is also disposed in the path of light emitted by the light emitting region. The transparent material may connect the ceramic body to the semiconductor structure. Particles configured to scatter light emitted by the light emitting region are disposed in the layer of adhesive material. In some embodiments the particles are phosphor; in some embodiments the particles are not a wavelength-converting material.
摘要翻译：包括波长转换材料的陶瓷体设置在由包括设置在n型区域和p型区域之间的发光区域的半导体结构的发光区域发射的光的路径中。透明材料层也设置在由发光区域发射的光的路径中。透明材料可以将陶瓷体连接到半导体结构。被配置为将由发光区域发射的光散射的颗粒设置在粘合剂材料层中。在一些实施方案中，颗粒是磷光体; 在一些实施方案中，颗粒不是波长转换材料。

10. 发明授权

US07462086B2 Phosphor for phosphor-converted semiconductor light emitting device 失效
标题翻译：磷光体用于磷光体转换半导体发光器件
公开(公告)号：US07462086B2
公开(公告)日：2008-12-09
申请号：US10829140
申请日：2004-04-21
申请人： Regina B. Mueller-Mach , Gerd O. Mueller
发明人： Regina B. Mueller-Mach , Gerd O. Mueller
IPC分类号： H01J9/00
CPC分类号： C09K11/7774 , C09K11/7731 , C09K11/7734 , H01L33/502
摘要： A semiconductor light emitting device comprising a light emitting layer configured to emit light of a first wavelength disposed between an n-type region and a p-type region is combined with a cerium-doped garnet phosphor having a wider excitation spectrum than conventional cerium-doped garnet phosphors. In some embodiments, the phosphor has a cerium concentration between about 4 mol % and about 8 mol %.
摘要翻译：包括被配置为发射设置在n型区域和p型区域之间的第一波长的光的发光层的半导体发光器件与具有比常规铈掺杂的激发光谱更宽的铈掺杂石榴石荧光体组合石榴石荧光粉。在一些实施方案中，磷光体的铈浓度在约4mol％至约8mol％之间。

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