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1. 发明授权

US08114258B2 Electrolysis device for the production of alkali metal 失效
标题翻译：用于生产碱金属的电解装置
公开(公告)号：US08114258B2
公开(公告)日：2012-02-14
申请号：US11575187
申请日：2005-09-13
申请人： Guenther Huber , Michael Lutz , Michael Wille , Holger Friedrich , Josef Guth , Uwe Behling , Axel Franke , Elisabeth Gunkel
发明人： Guenther Huber , Michael Lutz , Michael Wille , Holger Friedrich , Josef Guth , Uwe Behling , Axel Franke , Elisabeth Gunkel
IPC分类号： C25D17/00 , C25B9/14
CPC分类号： C25C7/005 , C25C3/02 , C25C7/007
摘要： An electrolysis device producing alkali metals from a liquid alkali metal heavy metal alloy, including at least two connected tubes forming an electrolysis unit. Two solid electrolyte tubes are arranged concentrically in each tube and oriented with openings towards one end of each tube such that a first annular gap for guiding a liquid alkali metal forming an anode is located between the inside of the tube and the outside of the solid electrolyte tubes. An alloy inlet and outlet for the liquid alkali metal in each of the tubes leads into the first annular gap of a tube. An inner chamber sealed off from the alloy inlet, first annular gap, and alloy outlet in each solid electrolyte tube receives liquid alkali metal that can be used as a cathode connected to the alkali metal outlet. Two respective closure devices are arranged at the two ends of each tube.
摘要翻译：一种从液态碱金属重金属合金制造碱金属的电解装置，包括形成电解单元的至少两个连接管。两个固体电解质管同心地布置在每个管中并且朝向每个管的一端定向开口，使得用于引导形成阳极的液态碱金属的第一环形间隙位于管的内部和固体电解质的外部之间管。每个管中的液态碱金属的合金入口和出口通向管的第一环形间隙。在每个固体电解质管中的合金入口，第一环形间隙和合金出口密封的内室容纳可用作连接到碱金属出口的阴极的液态碱金属。两个相应的闭合装置布置在每个管的两端。

2. 发明申请

US20080053837A1 Electrolysis Device For The Production Of Alkali Metal 失效
标题翻译：用于生产碱金属的电解装置
公开(公告)号：US20080053837A1
公开(公告)日：2008-03-06
申请号：US11575187
申请日：2005-09-13
申请人： Gunther Huber , Michael Lutz , Michael Wille , Holger Friedrich , Josef Guth , Uwe Behling , Axel Franke , Elisabeth Gunkel
发明人： Gunther Huber , Michael Lutz , Michael Wille , Holger Friedrich , Josef Guth , Uwe Behling , Axel Franke , Elisabeth Gunkel
IPC分类号： C25C1/22 , C25D17/00
CPC分类号： C25C7/005 , C25C3/02 , C25C7/007
摘要： An electrolysis device producing alkali metals from a liquid alkali metal heavy metal alloy, including at least two connected tubes forming an electrolysis unit. Two solid electrolyte tubes are arranged concentrically in each tube and oriented with openings towards one end of each tube such that a first annular gap for guiding a liquid alkali metal forming an anode is located between the inside of the tube and the outside of the solid electrolyte tubes. An alloy inlet and outlet for the liquid alkali metal in each of the tubes leads into the first annular gap of a tube. An inner chamber sealed off from the alloy inlet, first annular gap, and alloy outlet in each solid electrolyte tube receives liquid alkali metal that can be used as a cathode connected to the alkali metal outlet. Two respective closure devices are arranged at the two ends of each tube.
摘要翻译：一种从液态碱金属重金属合金制造碱金属的电解装置，包括形成电解单元的至少两个连接管。两个固体电解质管同心地布置在每个管中并且朝向每个管的一端定向开口，使得用于引导形成阳极的液态碱金属的第一环形间隙位于管的内部和固体电解质的外部之间管。每个管中的液态碱金属的合金入口和出口通向管的第一环形间隙。在每个固体电解质管中的合金入口，第一环形间隙和合金出口密封的内室容纳可用作连接到碱金属出口的阴极的液态碱金属。两个相应的闭合装置布置在每个管的两端。

3. 发明授权

US09011790B2 Reactor for performing a three-phase reaction of a fluid and a gaseous phase on a packed bed catalyst 有权
标题翻译：用于在填充床催化剂上进行流体和气相的三相反应的反应器
公开(公告)号：US09011790B2
公开(公告)日：2015-04-21
申请号：US12665533
申请日：2008-06-20
申请人： Stefan Iselborn , Andreas Daiss , Reiner Geier , Marcus Bechtel , Michael Wille , Benjamin Hepfer , John Sauter
发明人： Stefan Iselborn , Andreas Daiss , Reiner Geier , Marcus Bechtel , Michael Wille , Benjamin Hepfer , John Sauter
IPC分类号： B01J8/02 , B01J8/04 , C07C7/167 , B01J8/00 , B01J19/00 , B01J19/24 , B01J19/30 , B01J35/00 , B01J35/02
CPC分类号： B01J8/008 , B01J8/025 , B01J8/0278 , B01J8/0453 , B01J8/0492 , B01J2208/00548 , C07C7/167 , C10G2400/20 , C07C11/08
摘要： A reactor for carrying out a three-phase reaction of a liquid phase, a gaseous phase, and a catalyst over a fixed catalyst bed is disclosed. The liquid and gaseous phases are passed through the reactor via a mixing and distribution device positioned over the fixed catalyst bed. The mixing and distribution device includes a trough distributor for the liquid phase, having trough-shaped channels, outlet tubes in the trough-shaped channels for the liquid phase, a distributor plate below the trough distributor, and vertical nozzles, having one or more openings for the gaseous phase and one or more openings, arranged below the openings for the gaseous phase. For entry of the liquid phase, the nozzles are installed so that, at a predetermined liquid feed rate, the surface of the liquid on the distributor plate is below the openings for the gaseous phase and above the openings for the liquid phase.
摘要翻译：公开了一种用于在固定催化剂床上进行液相，气相和催化剂的三相反应的反应器。液相和气相通过位于固定催化剂床上的混合和分配装置通过反应器。混合和分配装置包括用于液相的槽分配器，具有槽形通道，用于液相的槽形通道中的出口管，槽分配器下方的分配板，以及具有一个或多个开口用于气相和一个或多个开口，布置在用于气相的开口下方。为了进入液相，喷嘴被安装成使得以预定的液体进料速率，分配器板上的液体表面低于气相的开口和用于液相的开口的上方。

4. 发明申请

US20100185032A1 REACTOR FOR PERFORMING A THREE-PHASE REACTION OF A FLUID AND A GASEOUS PHASE ON A PACKED BED CATALYST 有权
标题翻译：用于在包装床催化剂上进行流体和气相的三相反应的反应器
公开(公告)号：US20100185032A1
公开(公告)日：2010-07-22
申请号：US12665533
申请日：2008-06-20
申请人： Stefan Iselborn , Andreas Daiss , Reiner Geier , Marcus Bechtel , Michael Wille , Benjamin Hepfer
发明人： Stefan Iselborn , Andreas Daiss , Reiner Geier , Marcus Bechtel , Michael Wille , Benjamin Hepfer
IPC分类号： C07C5/03 , B01F3/04 , B01J8/02
CPC分类号： B01J8/008 , B01J8/025 , B01J8/0278 , B01J8/0453 , B01J8/0492 , B01J2208/00548 , C07C7/167 , C10G2400/20 , C07C11/08
摘要： A reactor (R) for carrying out a three-phase reaction of a liquid phase (1) and a gaseous phase (2) over a fixed catalyst bed (F), with the fixed catalyst bed (F) being arranged horizontally in the reactor (R) and the liquid phase (1) and the gaseous phase (2) being passed through the reactor (R) in cocurrent from the top downward via a mixing and distribution device (MD) over the fixed catalyst bed (F), wherein the mixing and distribution device (MD) comprises a trough distributor (TD) for the liquid phase (1) having trough-shaped channels (C) and outlet tubes (O) in the trough-shaped channels (C) for the liquid phase (1) and a distributor plate (P) which is arranged with a spacing below the trough distributor (TD) and in which vertical nozzles (N) having one or more openings (P1) for entry of the gaseous phase (2) and one or more openings (P2), which are arranged below the openings (P1) for entry of the gaseous phase, for entry of the liquid phase (1) into the nozzles (N) are installed, with the number and size of the openings (P2) for entry of the liquid phase (1) being designed so that, at a predetermined liquid feed rate, the surface of the liquid on the distributor plate (P) is established below the openings (P1) for entry of the gaseous phase (2) and above the openings (P2) for entry of the liquid phase (1), is proposed.
摘要翻译：用于在固定的催化剂床（F）上进行液相（1）和气相（2）的三相反应的反应器（R），其中固定的催化剂床（F）在反应器中水平布置（R）和液相（1）和气相（2）通过混合和分配装置（MD）从顶部向下并流通过反应器（R），其中固定催化剂床（F），其中混合和分配装置（MD）包括用于液相（1）的槽分配器（TD），其具有用于液相的槽形通道（C）中的槽形通道（C）和出口管（O） 1）和分配器板（P），其布置在槽分配器（TD）下方的间隔处，并且其中具有用于进入气相（2）的一个或多个开口（P1）的垂直喷嘴（N）和一个或布置在用于进入气相的开口（P1）下方的用于将液相（1）进入喷嘴（N）的更多的开口（P2）被安装其中液相（1）进入的开口（P2）的数量和尺寸被设计成使得以预定的液体进给速率将分配器板（P）上的液体的表面建立在提出了用于进入液相（2）的气相（2）和用于进入液相（1）的开口（P2）上方的开口（P1）。

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