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    • 1. 发明授权
    • Off-gas scrubber system
    • 废气洗涤系统
    • US5405590A
    • 1995-04-11
    • US15022
    • 1993-02-05
    • Pedro B. D. MacedoHamid HojajiMarek BrandysRobert K. Mohr
    • Pedro B. D. MacedoHamid HojajiMarek BrandysRobert K. Mohr
    • B01D47/12B01D53/14B01D53/50B01D53/68C01D3/02B01D53/34
    • B01D53/501B01D47/12B01D53/1406B01D53/68C01D3/02
    • An off-gas quencher and solid recovery scrubber unit includes a wet flue gas scrubber which has the dual responsibilities of lowering the temperature of the inlet hot gas entering through the scrubber and trapping contaminants from the gas stream into the liquid stream. The hot exhaust gases are first cooled by evaporating the liquid scrubber solution. The contaminants of the exhaust gas are neutralized by a suitable reagent such as sodium hydroxide and the product is collected in the scrubbing solution. Since the solution is continuously recycled, the concentration of the scrubbing agent will be diminished as the scrubbing proceeds, while the concentration of the scrubbing product in the solution will rise to the solubility limit of the product. The scrubbing products start to precipitate and are collected at the bottom of the scrubber and are withdrawn. The scrubbing reagents are continuously replenished to the scrubber. The secondary scrubber is another wet scrubber which uses reagents/water from spray nozzles to scrub off any contaminants that might have escaped the solid recovery scrubber. In addition, the exhaust gas entering the secondary scrubber is cooled below its dew point which results in condensation of water in the scrubber.
    • 废气猝灭剂和固体回收洗涤器单元包括湿烟道气洗涤器,其具有降低通过洗涤器进入的入口热气体的温度并将污染物从气流捕获到液体流中的双重职责。 首先通过蒸发液体洗涤器溶液来冷却热废气。 废气中的污染物被合适的试剂如氢氧化钠中和,并将产物收集在洗涤溶液中。 由于溶液被连续循环,洗涤剂的浓度随着洗涤进行而减少,而溶液中洗涤产物的浓度将升至产物的溶解度极限。 洗涤产物开始沉淀并收集在洗涤器的底部并被抽出。 洗涤剂不断补充到洗涤器中。 二次洗涤器是另一种湿式洗涤器,其使用来自喷嘴的试剂/水来洗涤可能已经从固体回收洗涤器逸出的任何污染物。 此外,进入二次洗涤器的排气被冷却到其露点以下,这导致洗涤器中的水冷凝。
    • 2. 发明授权
    • Method and apparatus for eliminating volatiles or airborne entrainments
when vitrifying radioactive and/or hazardous waste
    • 当放射性和/或危险废物玻璃化时消除挥发物或空气夹带的方法和装置
    • US5678236A
    • 1997-10-14
    • US589252
    • 1996-01-23
    • Pedro B. MacedoIan L. PeggHamid HojajiRobert K. MohrMarek Brandys
    • Pedro B. MacedoIan L. PeggHamid HojajiRobert K. MohrMarek Brandys
    • G21F9/16B09B3/00B09B5/00C03B5/00G21F9/36G21F9/00C03B5/16
    • B09B3/0066C03B5/005
    • In this invention radioactive or hazardous containing materials are vitrified in a melter having two or more chambers. Glass feed materials are added to the primary chamber of the melter and they are heated to a molten glass which is then transported to one or more secondary chambers where hazardous and/or radioactive containing materials are added and are encapsulated and/or melted. In addition, the non-plutonium part of a glass feed can be melted in a non-radioactive environment which permits contact operations and maintenance; no radioactive shielding; and a conventional off gas system-similar to commercial vitrification plants. The hot molten "clean" glass is directed into a radioactive containment such as a "glove box"; shielded "glove box"; or hot cell, or a combination of these. By delivering hot "clean" glass from a melter including non-radioactive materials, 90% of the off gases will be non-radioactive. Thereby only minimum heating is needed in the radioactive containment resulting in very significant reductions in size of the maintenance requirements for the radioactive portion of the process. In the radioactive portion, the glove box will include means for adding plutonium feed. The glass melt will be homogenized with the plutonium feed, optionally by additional stirring. Once the plutonium glass is sufficiently homogeneous, it can be cooled in the container in the glove box or the container becomes a disposal container for the glass. If the melt chamber is different than the container, the melt is discharged to a separate container, all within the glove box, for subsequent disposal.
    • 在本发明中,在具有两个或更多个室的熔化器中将放射性或有害物质玻璃化。 将玻璃进料添加到熔化器的主室中,并将其加热到熔融玻璃中,然后将其输送到一个或多个二级室,其中添加有危险和/或放射性的材料并被包封和/或熔化。 此外,可以在允许接触操作和维护的非放射性环境中熔化玻璃进料的非钚部分; 无放射性屏蔽; 和常规的废气系统 - 类似于商业玻璃化装置。 热熔融的“干净”玻璃被引导到诸如“手套箱”的放射性容纳物; 屏蔽“手套箱”; 或热电池,或这些的组合。 通过从包括非放射性物质的胶机提供热的“干净”玻璃,90%的废气将是非放射性的。 因此,在放射性容纳物中仅需要最小的加热,导致该方法的放射性部分的维护要求的大小的非常显着的减小。 在放射性部分,手套箱将包括用于添加钚饲料的装置。 玻璃熔体将用钚进料均化,任选地通过另外搅拌。 一旦钚玻璃足够均匀,就可以在手套箱中的容器中冷却,或者容器成为玻璃的处理容器。 如果熔体室与容器不同,则将熔体排放到单独的容器中,全部在手套箱内,以便后续处理。