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1. 发明专利

GB691042A Copolymers of vinyl phenols with drying oils 未知
公开(公告)号：GB691042A
公开(公告)日：1953-05-06
申请号：GB119049
申请日：1949-01-15
申请人： BRITISH RESIN PROD LTD , EDWARD MICHAEL EVANS , STANLEY ERWIN BRADSHAW , JOHN EDWARD SEAGER WHITNEY
IPC分类号： C08F16/02
摘要： Vinyl phenols, e.g. ortho-, meta- and paravinyl phenols and their methyl, ethyl, and propyl nuclear derivatives, are copolymerized with drying oils, e.g. chinawood, dehydrated castor, oiticica, tung, and linseed oils, which may be partially polymerized prior to copolymerization. Also present may be other polymerizable compounds containing the CH2=C

2. 发明专利

GB691041A Copolymerisation of vinyl phenols with polyhydric alcohol esters of alpha unsaturated alpha beta polycarboxylic acids 未知
公开(公告)号：GB691041A
公开(公告)日：1953-05-06
申请号：GB92449
申请日：1949-01-13
申请人： BRITISH RESIN PROD LTD , EDWARD MICHAEL EVANS , JOHN EDWARD SEAGER WHITNEY
IPC分类号： C08F16/02 , C08F283/01
摘要： Vinyl phenols, e.g. ortho, meta, and paravinyl phenols, and their methyl, ethyl, and propyl nuclear derivatives, are copolymerized with unsaturated alkyd resins derived from alpha, beta unsaturated polycarboxylic acids, the vinyl phenol constituting from 0.1 to 99.9 per cent of the monomer mixture. The unsaturated alkyd resins, which may be used in either the monomeric or partially polymerized state, are derived from polyhydric alcohols such as glycol, diethylene glycol, propylene glycol, butylene glycol, hexamethylene glycol, glycerol, pentaerythritol and their mixtures, and acids such as maleic, fumaric, itaconic, mesaconic, citraconic acids, or their anhydrides, or mixtures thereof. The alkyd resins may be prepared in the presence of zinc chloride and modifying agents such as butanol, decyl and octadecyl alcohols, phthalic, succinic, sebacic, butyric, stearic and abietic acids or anhydrides, castor oil, dehydrated castor oil and tung oil. Copolymerization may be carried out in bulk or aqueous dispersion, when the pH is preferably maintained below 7, with the aid of heat, actinic light, and catalysts such as lauryl, acetyl, crotonyl, benzoyl, tert.-butyl, and isopropyl benzene peroxides, tert.-butyl and isopropyl benzene hydroperoxides, hydrogen peroxide, alkali metal and ammonium persulphates and perborates, Friedel-Crafts catalysts, stannic chloride, hydrochloric and sulphuric acids, and acid-activated clays. The reaction may be terminated at a point short of gelation, and the copolymers stabilized by the addition of hydroquinone or metol. Hardening may be effected subsequently after the removal of the inhibitor, addition of more catalyst, or further heating. The copolymers may be used as a basis for moulding compositions, as rubbery sheets, and in the production of laminates and lacquers. Specification 691,037 is referred to.

3. 发明专利

GB691040A Copolymers of vinyl phenols with butadiene compounds 未知
公开(公告)号：GB691040A
公开(公告)日：1953-05-06
申请号：GB92249
申请日：1949-01-13
申请人： BRITISH RESIN PROD LTD , EDWARD MICHAEL EVANS , JOHN EDWARD SEAGER WHITNEY
IPC分类号： C08F16/02 , C08F36/04 , C08F212/14 , C08F236/04 , C08F240/00
摘要： Vinyl phenols, e.g. ortho-, meta-, and paravinyl phenols, and their methyl, ethyl and propyl nuclear derivatives, are copolymerized with butadiene type compounds, e.g. butadiene, isoprene, 2 : 3-dimethyl butadiene, and chloroprene. Polymerization may be carried out in bulk or aqueous dispersion with the aid of heat and light in the presence of catalysts such as benzoyl, acetyl, crotonyl, tert.-butyl, and isopropyl benzene peroxides, tert.-butyl, and isopropyl benzene hydroperoxides, tert.-butyl perbenzoate, hydrogen peroxide, alkali metal and ammonium perborates and persulphates, Friedel-Crafts catalysts, such as boron tri-fluoride, stannic chloride, hydrochloric and sulphuric acids, activated clays, and a combination of an oxidizing agent with a reducing agent such as sodium sulphite. When the reaction is performed in aqueous dispersion ethylene oxide polymer and sulphonated castor oil may be present, and the pH is preferably maintained below 7. The copolymers may be rendered infusible by vulcanization or by condensation with an aldehyde, and may be etherified. The products may be used as a basis for moulding compositions, adhesives and lacquers. Specifications 691,035, 691,036 and 691,037 are referred to.

4. 发明专利

GB680441A Copolymerisation of styrene and drying oils 未知
公开(公告)号：GB680441A
公开(公告)日：1952-10-08
申请号：GB1780149
申请日：1949-07-06
申请人： BRITISH RESIN PROD LTD , STANLEY ERWIN BRADSHAW , EDWARD MICHAEL EVANS
IPC分类号： C08F212/14
摘要： Copolymers of styrene, alpha-methyl styrene, or their methyl- and ethyl-substituted derivatives, with triglycerides of long chain fatty acids, of which one acid, at least, contains conjugated double bonds, or mixtures thereof, e.g. blown linseed oil, dehydrated castor oil and tung oil, and/or with alkyd resins modified with drying oils and, if desired, with alphabeta, unsaturated acids such as maleic acid, are made by effecting the polymerization, preferably in a homogeneous liquid phase, in the presence of a transfer agent selected from halogen-substituted paraffins or olefins of 1-3 carbon atoms, a di- or tri-aryl substituted methane, a dito penta-aryl substituted ethane or an arylene or di-arylene substituted methane or ethane, e.g. carbon tetrachloride, ethylene dichloride, di- and triphenyl methane, tetrabromethylene, fluorene, acenaphthene and pentaphenylethane. The polymerization may be interrupted before gelling occurs. Specified substituted derivatives are para-methyl styrene, p alpha-methyl para-methyl styrene, meta-ethyl styrene, and vinyl meta-xylene. The copolymers admixed with solvents, e.g. xylene, and conventional driers, are used as varnishes.

5. 发明专利

GB619975A Improvements in or relating to the production of oil-modified alkyd resins and to improved coating compositions prepared therefrom 未知
公开(公告)号：GB619975A
公开(公告)日：1949-03-17
申请号：GB2231446
申请日：1946-07-26
申请人： BRITISH RESIN PROD LTD , EDWARD MICHAEL EVANS , ELIZABETH MARGARET RILEY , LEONARD RALPH ANTHONY
IPC分类号： C08G63/48
摘要： Oil-modified alkyd resins are prepared by heating a mixture of castor oil, a polyhydric alcohol and a polybasic acid or anhydride thereof at a temperature between 260 DEG and 270 DEG C. until the initial decrease in viscosity of the reaction mixture has substantially ceased, and, before there is any substantial increase in viscosity adding a sufficient quantity of polyhydric alcohol and/or polybasic acid or anhydride thereof at such a temperature as to reduce the temperature of the reaction mixture to a value not exceeding 230 DEG C., and continuing to react the added polyhydric alcohol and added polybasic acid or anhydride thereof at a temperature between 160 DEG and 230 DEG C. and adding any further polyhydric alcohol and/or polybasic acid or anhydride which may be necessary to produce a reaction product, the oil content of which does not exceed 50 per cent thereof and which contains a small amount of free polyhydric alcohol. Cooling means may be provided to remove the excess heat of the reaction vessel. Preferably, the initial reaction mixture contains 5-75 per cent excess of glycerol over the equivalent amount and contains 40-95 per cent of oil. Any further additions of polyhydric alcohol are preferably made before the addition of further polybasic-acid. Suitable alcohols are glycerol, pentaery, thritol, ethylene glycol, trimethylol propane mannitol, sorbitol and butyne-diol, and suitable acids are phthalic acid and anhydride, tetrahydrophthalic acid, tetrachlorophthalic anhydride, methylene di-salicylic acid, maleic, fumaric and citric acids, and maleic and fumaric acid adducts with terpenes and cyclo-olefines. In examples, castor oil, glycerol and phthalic anhydride are heated at 260-270 DEG C., and when the minimum viscosity is passed sufficient glycerol is added to reduce the temperature to 230 DEG C. Further phthalic anhydride is added, followed by further heating, firstly at 230 DEG C. and then at 180 DEG C.; (2) the procedure of (1) is followed, but a further addition of phthalic anhydride and glycerol is made whilst heating at 180 DEG C.; (3) castor oil, phthalic anhydride and glycerol are heated at 260-270 DEG C. and pentaerythritol added when the minimum viscosity is passed to reduce the temperature to 230 DEG C. Phthalic acid is added and heating continued at 220 DEG C.; (4) sorbitol replaces the pentaerythritol of (3). The products dissolved in xylene are p suitable as varnishes, and cobalt linoleate or naphthenate driers may be added. Specifications 431,495 and 474,620 are referred to. A sample has been furnished under Sect. 2 (5) of a product obtained by heating castor oil glycerol and phthalic anhydride, and when the minimum viscosity is reached adding more glycerol and phthalic anhydride and heating at 220 DEG C., then adding butyne diol and heating at 210 DEG C. The product at 200 DEG C. is dissolved in xylene.

6. 发明专利

GB613648A Manufacture of organic silicon compounds 未知
公开(公告)号：GB613648A
公开(公告)日：1948-12-01
申请号：GB1887646
申请日：1946-06-24
申请人： ANDREW BOWMAN , EDWARD MICHAEL EVANS , JAMES ROBERTSON MYLES , LAURENCE CONRAD PAYMAN , ICI LTD
IPC分类号： C07F7/18
摘要： Aryl substituted silicanes of the general formula RnSi(OR1)4-n, wherein R represents an aryl residue, R1 is a secondary alcohol residue containing more than three carbon atoms and n is a whole number less than 4, are prepared by reacting a silicane of the general formula XnSi(OR1)4-n, wherein R1 and n have the above significance and X represents halogen, with a mono-halogenated aryl hydrocarbon in the presence of an alkali metal, e.g. sodium. The reaction may be carried out in stages by first reacting the mono-halogenated aryl hydrocarbon with the alkali metal, and then reacting the resulting alkali metal aryl with the halogeno-silicane. The reaction may be effected under the usual conditions for a Würtz-Fittig reaction, in the presence or absence of diluents, e.g. ether, petroleum ether or other inert solvents, and in the presence or absence of catalysts, e.g. ethyl alcohol, acetic acid and ethyl acetate. The aryl substituted silicanes may be hydrolysed to yield silicols of the general formula RnSi(OH)4-n, wherein R and n have the above significance, e.g. by heating with aqueous alkalis or aqueous acids in the presence of a water-miscible solvent for the silicanes such as the monethyl ether of ethylene glycol. In examples: (1) to (4) phenyl-tricyclohexoxysilicane is prepared by reacting chlorobenzene, sodium and chloro-tricyclohexoxy silicane; (5) and (6) diphenyl-dicyclohexoxy-silicane and diphenyl - di - secondary - butoxy - silicane are prepared by reacting sodium, chlorobenzene and dichloro-dicyclohexoxysilicane and dichloro - di - secondary - butoxysilicane respectively; (7) phenylsilicanetriol is prepared by hydrolysing phenyl-tricyclohexoxysilicane prepared as in examples (1) to (4). Specifications 574,653 and 583,754 are referred to.

7. 发明专利

GB583754A New and improved synthetic resins 未知
公开(公告)号：GB583754A
公开(公告)日：1946-12-30
申请号：GB2378544
申请日：1944-11-29
申请人： ANDREW BOWMAN , EDWARD MICHAEL EVANS , ICI LTD
IPC分类号： C08G63/91 , C08G77/00
摘要： A synthetic resin is prepared by heating an alkyd resin, which may be oil-modified or not, with the hydrolysis product of a compound of the formula RnSiX4-n, where R represents any substituted or unsubstituted hydrocarbon radical such as alkyl, e.g. methyl, ethyl, propyl, n- or i-butyl; cycloalkyl, e.g. cyclohexyl; aryl, e.g. phenyl, para-chlorphenyl and para-tolyl; or aralkyl, e.g. benzyl; X is a halogen, e.g. chlorine, bromine or iodine, or OR1- (where R1 is a hydrocarbon radical), e.g. methoxy, ethoxy, or phenoxy; and n is a whole number less than 3. Specified compounds of the above formula are methylsilicon trichloride, dimethylsilicon dichloride, diphenylsilicon dibromide, phenylethylsilicon dichloride, phenylsilicon trichloride, dibenzyl silicon dichloride, phenyltriethoxy silicane, diphenyldiethoxy silicane, cyclohexylsilicon trichloride and para-tolylsilicon trichloride. The alkyd resins may be glyceryl phthalates modified or not with linseed oil, castor oil or hydrogenated castor oil. The reaction is preferably carried out in a solvent, e.g. benzene, toluene, xylene or n-butanol. The product, dissolved in a solvent, e.g. butanol, with or without the incorporation of pigments, e.g. titanium dioxide, may be used as a coating composition. In examples: (1) castor-oil-modified glyceryl phthalate resin is reacted in xylene solution with the hydrolysis product of phenylsilicon trichloride and the product is dissolved in butanol; with the addition of titanium dioxide and xylene, an enamel is formed; (3) hydrogenated-castor-oil-modified glyceryl phthalate resin is reacted in xylene solution with the hydrolysis product of phenylsilicon trichloride; the product dissolved in butanol and titanium dioxide added to form a coating composition; (4) linseed-oil-modified glyceryl phthalate resin is reacted with the hydrolysis product of phenylsilicon trichloride in xylene solution, the product dissolved in butanol and xylene and pigmented with titanium dioxide forming a coating composition to which cobalt naphthenate may be added; (5) butanol-modified glyceryl adipate resin is reacted with the hydrolysis product of phenylsilicon trichloride in xylene solution, the product dissolved in butanol and xylene, and pigmented with titanium dioxide to form a coating composition; (6) castor-oil-modified glyceryl phthalate resin is reacted with the hydrolysis product of benzylsilicon trichloride in xylene solution and the product dissolved in butanol; (7) castor-oil-modified glycerylphthalate resin is reacted with the hydrolysis product of cyclohexyl silicon trichloride in xylene solution and the product is dissolved in butanol; (8) castor-oil-modified glycerylphthalate resin is reacted with xylene solution with the hydrolysis product of the reaction production of methyl magnesium chloride with silicon tetrachloride and butanol is added periodically when the mixture gels and the product is finally dissolved in butanol. The compounds formulated above may be obtained by treatment of the appropriate tetrahalogenosilicane or silicic acid ortho-ester with Grignard reagents, and may be hydrolysed by treatment with water, aqueous alkali or aqueous acid. In an example, phenylsilicon trichloride dissolved in ether is added slowly to ice-water with cooling. The ether layer, together with an ether extract of the aqueous layer, is washed with water, dried, and mixed with xylene and the ether evaporated. Specifications 542,655, 548,911, 548,912, 551,649 and 552,640 are referred to.

8. 发明专利

GB691043A New synthetic resins 未知
公开(公告)号：GB691043A
公开(公告)日：1953-05-06
申请号：GB411049
申请日：1949-02-15
申请人： BRITISH RESIN PROD LTD , EDWARD MICHAEL EVANS , JOHN EDWARD SEAGER WHITNEY
IPC分类号： C08F16/02 , C08F36/04 , C08F212/14 , C08F236/04 , C08F240/00
摘要： Vinyl phenols, e.g. ortho-, meta- and paravinyl phenols and their methyl, ethyl, and propyl nuclear derivatives, are copolymerized with cyclopentadiene and indene type compounds, e.g. cyclopentadiene, indene, coumarone and their methyl and ethyl derivatives, and naphtha fractions containing these substances. Copolymerization may be carried out in bulk or solution with the aid of heat, ultra-violet light, and catalysts such as hydrochloric and sulphuric acids, activated clays such as activated Fuller's earth, stannic chloride, boron trifluoride, phosphorus oxychloride, aluminium chloride, and organic peroxy compounds. The copolymers may be rendered infusible by heating with hexamethylene tetramine, cross-linked by condensing with aldehydes, or etherified. The copolymers may be used as a basis for lacquers or moulding powders. Specifications 691,035 and 691,036 are referred to.

9. 发明专利

GB691038A Copolymerisation of vinyl phenol type compounds with styrene type compounds 未知
公开(公告)号：GB691038A
公开(公告)日：1953-05-06
申请号：GB3069348
申请日：1948-11-26
申请人： BRITISH RESIN PROD LTD , EDWARD MICHAEL EVANS , JOHN EDWARD SEAGER WHITNEY
IPC分类号： C08F16/02
摘要： Vinyl phenols or their lower nuclear homologues, e.g. methyl, ethyl or propyl substituted derivatives, are copolymerized with styrene compounds, e.g. styrene, monomethyl, ethyl and a -methyl p-methyl styrene and mono- and dichlorstyrenes; maleic acid esters and half esters of saturated aliphatic alcohols; acrylic compounds, e.g. methacrylic, a -ethyl, a -chlor, a -fluor acrylic acids, methyl and ethyl acrylates, ethyl and butyl methacrylates, methyl a -chlor-acrylate, acrylonitrile, methacrylonitrile, acrylyl chloride, and acryl- and methacrylamide; vinyl organic esters, e.g. formate, acetate, propionate, butyrate and stearate; vinyl ethers, e.g. methyl, ethyl, isopropyl, butyl, phenyl, tolyl, naphthyl, vinyl and propenyl ethers; vinyl ketones, e.g. methyl, ethyl, isopropyl, and butyl ketones; N-vinyl compounds, e.g. N-vinyl carbazole, pyrrole and piperidine; polymerizable allyl compounds, e.g. esters of allyl, methallyl, ethallyl, chlorallyl, crotonyl, cinnamyl, butene-1-ol-3, pentene-1-ol-3 and butadiene-2 : 3-ol-1, and polyhydric allyl alcohols with formic, phenoxy formic, acetic, lactic, butyric, glycollic, salicylic and oleic acids; or allyl ethers and allyl substituted aldehydes and ketones and their acetals and ketals. The reactive group in the latter may be chemically after-treated, and the vinyl ester copolymers may be hydrolysed partially or completely to produce vinyl alcohol units which in turn may be acetalized, e.g. with formaldehyde or hexamethylene tetramine. Copolymerization may be effected by heat or ultra-violet light with catalysts such as acetyl, crotonyl, benzoyl, tertiary-butyl, and isopropyl benzene peroxides, tertiary butyl perbenzoate, tertiary butyl and isopropyl benzene hydroperoxides, hydrogen peroxide, alkali metal or ammonium persulphates, Friedel-Craft catalysts, such as boron tri-fluoride, strong hydrochloric or sulphuric acid and acid-activated clay, or a Redox system with, e.g. sodium sulphite, in a homogeneous phase or in an aqueous dispersion of pH 7 or less. High molecular weight polymers may be separated by dissolving the initial resin in benzene, for example, and fractionally precipitating by an ethanol/petroleum ether mixture. The resins may be after-treated by cross-linking and/or etherification. Examples describe the homogeneous copolymerization of meta-vinyl phenol with styrene, ethyl acrylate, allyl caproate, diamyl maleate, ethyl vinyl ether containing divinyl ether, diallyl phthalate, and N-vinyl carbazole; of orthovinyl phenol with styrene; the copolymerization of meta-vinyl phenol with acrylonitrile, vinyl acetate or styrene in emulsions, in which sulphonated castor oil, polyethylene oxide, sodium sulphite and hydrogen peroxide are used; and the copolymerization of a solution of b -methyl styrene and m-vinyl phenol in toluene. Specifications 691,035, 691,036 and 691,037 are referred to.

10. 发明专利

GB691036A Etherification of vinyl phenol polymers or copolymers 未知
公开(公告)号：GB691036A
公开(公告)日：1953-05-06
申请号：GB3048248
申请日：1948-11-24
申请人： BRITISH RESIN PROD LTD , EDWARD MICHAEL EVANS , JOHN EDWARD SEAGER WHITNEY
IPC分类号： C08F8/00
摘要： Polymers and copolymers of ortho and meta vinyl phenols and their lower nuclear homologues are etherified by reaction with an unsaturated or saturated alkyl inorganic ester, e.g. dimethyl or diethyl sulphate, allyl or b -methallyl chloride, bromide or iodide but not fluoride. Copolymers with compounds such as butadiene hydrocarbons, chloroprene, styrene compounds, vinyl naphthalenes, acenaphthylene, N-vinyl pyridine, cyclopentadiene, vinyl and vinylidene halides, vinyl esters, acrylic esters, acrolein, or allyl compounds may be used. The polymer may be treated in a solution or dispersion in an alkaline polar medium, e.g. water or lower aliphatic alcohol or a non-polar medium, e.g. benzene or benzene-alcohol mixture, and in the latter case a quaternary ammonium hydroxide condensing agent is preferable. Films formed from a solution of the product in benzene containing tert-butyl hydroperoxide may be rendered insoluble on heating. In a modification the polymeric resin is treated with both an aldehyde and an etherifying agent, together or separately in one or two stages to yield a thermosetting resin which may be used as a moulding powder when compounded with fillers, plasticizers and lubricants, or used as a lacquer or adhesive when in a solution or dispersion. In examples poly-m-vinyl phenol, copolymers of m-vinyl phenol with styrene or methyl acrylate, and of o-vinyl phenol with styrene are etherified, the alkaline agents used being sodium hydroxide, methyl pyridinium hydroxide and tetramethyl ammonium hydroxide; and poly-m-vinyl phenol is reacted simultaneously with dimethyl sulphate and formaldehyde. Specifications 691,037, 691,038 and 691,040 are referred to.

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