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    • 3. 发明申请
    • HIGH DISCHARGE CAPACITY LITHIUM BATTERY
    • 高放电容量锂离子电池
    • WO2005053067A2
    • 2005-06-09
    • PCT/US2004/038612
    • 2004-11-19
    • EVEREADY BATTERY COMPANY, INC.MARPLE, Jack, W.
    • MARPLE, Jack, W.
    • H01M6/16
    • H01M4/381H01M2/0217H01M2/022H01M2/0225H01M2/14H01M2/1653H01M2/18H01M4/02H01M4/40H01M4/581H01M4/5815H01M6/10H01M6/14H01M6/16H01M2004/028H01M2006/5094
    • A lithium/iron disulfide electrochemical battery cell with a high discharge capacity. The cell has a lithium negative electrode, an iron disulfide positive electrode and a nonaqueous electrolyte. The positive electrode mixture containing the iron disulfide contains highly packed solid materials, with little space around the solid particles, to provide a high concentration of iron disulfide within the mixture. The separator is thin, to allow more space within the cell for active materials, yet strong enough to prevent short circuits between the positive and negative electrodes under abusive conditions, even when swelling of the cathode during cell discharge places additional stressed on the separator. As a result, the ratio of the interfacial capacity of the positive electrode to the electrode interfacial volume is high, as is the actual capacity on low rate/ low power and high rate/high power discharge.
    • 具有高放电容量的锂/二硫化铁电池电池。 电池具有锂负极,二硫化铁正极和非水电解质。 含有二硫化铁的正极混合物含有高密度的固体物质,在固体颗粒周围几乎没有空间,从而在混合物内提供高浓度的二硫化铁。 分离器薄,以允许活性材料中的电池内的更多空间,但是足够强大以防止在恶劣条件下正电极和负电极之间的短路,即使在电池放电期间阴极膨胀时,分离器附加应力也会增加。 结果,正极的界面容量与电极界面体积的比率高,低速率/低功率和高速率/高功率放电的实际容量也是如此。
    • 6. 发明申请
    • NONAQUEOUS ELECTROCHEMICAL CELL WITH IMPROVED ENERGY DENSITY
    • 具有改善能量密度的非电解电化学电池
    • WO2003105255A2
    • 2003-12-18
    • PCT/US2003/017728
    • 2003-06-05
    • EVEREADY BATTERY COMPANY, INC.MARPLE, Jack, W.
    • MARPLE, Jack, W.
    • H01M4/00
    • H01M4/625H01M4/06H01M4/382H01M4/5815H01M4/661H01M6/16
    • This invention relates to a nonaqueous cell comprising a lithium metallic foil anode and a cathode coating comprising iron disulfide as the active material wherein the coating is applied to at least one surface of a metallic substrate that functions as the cathode current collector. In particular, the cell of the invention has improved performance on high rate discharge and is achieved, surprisingly, with an anode underbalance. The cell of the invention has an anode to cathode input that is less than or equal to 1.0. We have discovered, unexpectedly, that the energy density for the cell both volumetrically and gravimetrically can be improved by approximately 20 to 25% while only increasing the volume of the cathode coating solids by approximately 10% through a unique and novel cathode coating formulation used in conjunction with an alloyed lithium foil.
    • 本发明涉及包含锂金属箔阳极和包含二硫化铁作为活性材料的阴极涂层的非水电池,其中将涂层施加到用作阴极集电器的金属基板的至少一个表面。 特别地,本发明的电池在高倍率放电时具有改进的性能,令人惊讶的是,阳极不平衡地实现。 本发明的电池具有小于或等于1.0的阳极至阴极输入。 我们意外地发现,体积和重量分辨率的电池的能量密度可以提高约20至25%,而仅通过独特且新颖的阴极涂层配方将阴极涂层固体的体积增加约10% 与合金的锂箔结合。