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    • 2. 发明授权
    • Regenerative process for removing mercaptans contained in a gas
    • 用于除去气体中所含的硫醇的再生方法
    • US4774067A
    • 1988-09-27
    • US13976
    • 1987-01-02
    • Robert VoirinJean Elgue
    • Robert VoirinJean Elgue
    • B01D53/14B01D53/48C07C7/148C10K1/34B01J8/00C10B17/00
    • C10K1/34B01D53/485C07C7/1485
    • A regenerative process is provided for removing mercaptans contained in a gas by means of an absorbing agent based on at least one metal oxide capable of chemically fixing the mercaptans. The process comprises an absorption step to fix the mercaptans on the absorbing agent and a regeneration step for regenerating the absorbing agent laden with sulphur-containing products resulting from said fixation. The regeneration is carried out by sweeping the absorbing agent with a hot inert gas to bring the absorbing agent to a temperature between 250.degree. and 500.degree. C. and desorb the sulfur-containing products, and by contacting the absorbing agent thus treated with a gas containing free oxygen to reoxidize the absorbing agent and by cooling the reoxidized absorbing agent by sweeping with a cold inert gas.
    • PCT No.PCT / FR86 / 00157 Sec。 371日期1987年1月2日 102(e)日期1987年1月2日PCT提交1986年5月6日PCT公布。 出版物WO86 / 06649 日本公报1986年11月20日。提供一种再生方法,用于通过基于能够化学固定硫醇的至少一种金属氧化物的吸收剂除去气体中所含的硫醇。 该方法包括将硫醇固定在吸收剂上的吸收步骤和用于使由所述固定产生的含硫产物负载的吸收剂再生的再生步骤。 再生通过用热惰性气体吹扫吸收剂进行,以使吸收剂达到250-500℃的温度并解吸含硫产物,并通过将这样处理的吸收剂与气体接触 含有游离氧气以再吸收吸收剂,并通过用冷惰性气体吹扫冷却再氧化吸收剂。
    • 3. 发明授权
    • Process and device for selective extraction of H.sub.2 S from an H.sub.2
S-containing gas
    • 从含H2S的气体中选择性提取H 2 S的方法和装置
    • US4889700A
    • 1989-12-26
    • US67259
    • 1987-06-03
    • Jean ElgueOlivier OliveauJean-Louis Peytavy
    • Jean ElgueOlivier OliveauJean-Louis Peytavy
    • B01D53/14B01D53/52B01D53/77C01B17/16
    • C01B17/167B01D53/1468
    • Method and devices for the selective removal of H.sub.2 S from an H.sub.2 S-containing gas by contacting the gas in an absorption column with an H.sub.2 S-selective absorbent liquid and transferring the H.sub.2 S-charged absorbent liquid to the upper part of a second column. The charged absorbent liquid then travels to a regeneration zone at the bottom of the column, where it is heated to a temperature at which the absorbent liquid is vaporized and the H.sub.2 S is released.The regeneration zone temperature causes the absorbent liquid vapor to strip the H.sub.2 S back to the upper part of the column where it forms an equilibrium with the H.sub.2 S-charged absorbent liquid at a temperature not more than 30.degree. C. higher than the injection temperature of the absorbent liquid in the absorption column, which equilibrium temperature is maintained by the temperature in the regeneration zone. The H.sub.2 S-enriched vapor formed at the equilibrium point is then tapped.
    • PCT No.PCT / FR86 / 00343 Sec。 371日期:1987年6月3日 102(e)日期1987年6月3日PCT申请日1986年10月3日PCT公布。 Wo87 / 01962 PCT出版物 日期1987年4月9日。用于通过使吸收塔中的气体与H 2 S选择性吸收剂液体接触并将带H2S的吸收剂液体接触到上部的H 2 S的气体的选择性去除H 2 S的方法和装置 第二列。 带电的吸收剂液体然后行进到塔底部的再生区,在那里将其加热到吸收液体蒸发并释放H 2 S的温度。 再生区温度导致吸收液体蒸气将H 2 S分离回塔的上部,在该上部与H2S充电的吸收液形成平衡,温度不高于30℃的温度 在吸收塔中的吸收液体,该平衡温度由再生区域中的温度维持。 然后在平衡点形成的富H2S蒸气被轻敲。
    • 4. 发明授权
    • Process and device for the removal of H.sub.2 S
    • 用于去除H 2 S的方法和装置
    • US5133949A
    • 1992-07-28
    • US465067
    • 1990-01-19
    • Jean ElgueJacques Tournier-Lasserve
    • Jean ElgueJacques Tournier-Lasserve
    • B01D53/52B01D53/14B01D53/77C01B17/04C01B17/16C10K1/10
    • B01D53/1468C01B17/167
    • Process for removing hydrogen sulfide at low concentration in a gas containing water vapor. The gas is cooled to a temperature below the dew point of water, which condenses and separates the water. The dry gas is scrubbed free of hydrogen sulfide by an H.sub.2 S-absorbent solvent forming a purified gas. The purified gas is contacted and rehydrated with heated water so that the water content as water vapor corresponds to a mass flow rate of water substantially equal to the mass flow rate of the water present in the H.sub.2 S-containing gas before cooling. The condensed water circulates in a closed circuit to contact and rehydrate the purified gas, and then is cooled to the appropriate temperature for cooling the H.sub.2 S-containing gas. An apparatus, appropriate for carrying out the process is disclosed.
    • PCT No.PCT / FR89 / 00240第 371 1990年1月19日第 102(e)日期1990年1月19日PCT提交1989年5月18日PCT公布。 出版物WO89 / 11326 日期为1989年11月30日。在含有水蒸气的气体中,低浓度除去硫化氢的方法。 将气体冷却至低于水的露点的温度,其冷凝并分离水。 通过形成纯化气体的H 2 S吸收剂溶剂将干燥气体除去硫化氢。 纯化的气体与加热水接触并再水化,使得作为水蒸气的水含量对应于基本上等于冷却前存在于含H2S的气体中的水的质量流量的质量流量。 冷凝水在闭合回路中循环以接触并再净化净化气体,然后冷却至合适的温度以冷却含H2S的气体。 公开了一种适于实施该方法的装置。
    • 7. 发明授权
    • Process and device for selective extraction of H.sub.2 S from an H.sub.2
S-containing gas
    • 从含H2S的气体中选择性提取H 2 S的方法和装置
    • US4773921A
    • 1988-09-27
    • US67258
    • 1987-06-03
    • Jean ElgueOlivier OliveauJean-Louis Peytavy
    • Jean ElgueOlivier OliveauJean-Louis Peytavy
    • B01D53/14B01D53/52B01D53/77C01B17/16
    • B01D53/1468C01B17/167
    • The disclosed method for the selective removal of H.sub.2 S from a H.sub.2 S-containing gas comprises contacting the gas in an absorption area (1) with a selective regeneratable absorbing liquid which absorbs the H.sub.2 S and regenerating by heating the absorbing liquid laden with H.sub.2 S in a regeneration area (3). The absorbing liquid coming out of the area (1) is sent to an enrichment area (2) through a conduit (25), a portion of the gases at the head of the area (3) is tapped through a valve (27) to form an acid gas flow enriched with H.sub.2 S and the remainder is introduced in the area (2) through a conduit (29), the absorbing liquid is tapped at the bottom of the area (2) and introduced through a conduit (25) in the area (3) and a gas stream is collected at the head of the area (2) and is injected through a conduit (22) in the area (1). Application to the simultaneous production of a gas flow highly enriched with H.sub.2 S and a gas having a fixed minimum content of H.sub.2 S.
    • PCT No.PCT / FR86 / 00342 Sec。 371日期:1987年6月3日 102(e)日期1987年6月3日PCT申请日1986年10月3日PCT公布。 出版物WO87 / 01961 日本1987年4月9日公开的用于从含H 2 S气体中选择性除去H 2 S的方法包括使吸收区域(1)中的气体与吸收H 2 S的选择性可再生吸收液体接触并通过加热吸收液体再生 在再生区域(3)装载有H2S。 从区域(1)出来的吸收液体通过导管(25)送至浓缩区域(2),区域(3)的头部的气体的一部分通过阀门(27)进行分接, 形成富含H 2 S的酸性气体流,其余部分通过管道(29)引入区域(2)中,吸收液体在区域(2)的底部被攻丝,并通过管道(25)引入 区域(3),并且在区域(2)的头部处收集气流,并且通过区域(1)中的导管(22)注入。 应用于同时生产高浓度H 2 S的气流和具有固定的最小含量的H 2 S的气体。