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    • 4. 发明公开
    • SOLVENT RESISTANT, TRANSPARENT AROMATIC POLYAMIDE FILMS WITH HIGH REFRACTIVE INDICES
    • 具有高折射率的耐溶剂,透明芳香族聚酰胺薄膜
    • EP3186301A1
    • 2017-07-05
    • EP15836204.6
    • 2015-08-31
    • Akron Polymer Systems, Inc.Sun, LiminZhang, DongJing, JiaokaiHarris, Frank W.
    • SUN, LiminZHANG, DongJING, JiaokaiHARRIS, Frank, W.
    • C08J5/18C08G69/12C08L77/06
    • C08J5/18C08G69/265C08G69/32C08J2377/10C09D177/10
    • A solvent resistant, transparent aromatic polyamide film with a high refractive index may be made by reacting at least one aromatic diacid chloride, a first aromatic diamine, and at least one crosslinking agent or a second aromatic diamine in an organic solvent to form an aromatic polyamide polymer in solution. In one embodiment, the at least one aromatic diacid chloride is selected from the group consisting of isophthaloyl dichloride, terephthaloyl dichloride, 2,6-naphthalene-dicarboxylic chloride, or combinations thereof and the first aromatic diamine is selected from the group consisting of 9,9-Bis(4-hydroxyphenyl)fluorine, 2,2′,5,5′-Tetrachlorobenzidine, or combinations thereof. The organic solvent is then evaporated from the aromatic polyamide polymer in solution to form a transparent aromatic polyamide precursor film. The precursor film is then heated at a temperature close to the glass transition temperature of the transparent aromatic polyamide precursor film to form the solvent resistant, transparent aromatic polyamide film.
    • 具有高折射率的耐溶剂透明芳族聚酰胺膜可通过使至少一种芳族二酰氯,第一芳族二胺和至少一种交联剂或第二芳族二胺在有机溶剂中反应以形成芳族聚酰胺 溶液中的聚合物。 在一个实施方案中,所述至少一种芳族二酰氯选自间苯二酰氯,对苯二酰氯,2,6-萘二羧酰氯或其组合,并且第一芳族二胺选自9, 9-双(4-羟基苯基)氟,2,2',5,5'-四氯联苯胺或其组合。 然后将有机溶剂从溶液中的芳族聚酰胺聚合物中蒸发以形成透明的芳族聚酰胺前体膜。 然后在接近透明芳族聚酰胺前体膜的玻璃化转变温度的温度下加热前体膜以形成耐溶剂,透明的芳族聚酰胺膜。