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    • 10. 发明授权
    • Ceramic body of zirconium dioxide (ZrO.sub.2) and method for its
preparation
    • 二氧化锆陶瓷体(ZrO2)及其制备方法
    • US4525464A
    • 1985-06-25
    • US619939
    • 1984-06-12
    • Nils ClaussenManfred RuhleGunter Petzow
    • Nils ClaussenManfred RuhleGunter Petzow
    • C04B35/486C04B35/488C04B35/48C04B35/50
    • C04B35/486C04B35/4885
    • A ceramic body of zirconium dioxide containing, if desired, aluminum oxide, and partially stabilized with yttrium oxide and/or one or more rare earth oxides (e.g., cerium dioxide) and/or magnesium oxide and/or calcium oxide is partially stabilized with 0.5 to 5 mole-% of yttrium oxide and/or 5 to 12 mole-% of magnesium oxide and/or calcium oxide and/or cerium dioxide or one or more rare earth oxides, is 30 to 100% in the tetragonal lattice modification and has in the surface region a content of yttrium oxide, cerium dioxide, magnesium oxide, calcium oxide or rare earth oxide that is 1 to 20 mole-% higher than the average content, such that the body is coated with a thin, PSZ-like layer in a more highly stabilized tetragonal or with a layer that is predominantly in the cubic lattice form. For preparation, the surface of an already sintered or only presolidified compact of partially stabilized zirconium oxide is brought into intimate contact with yttrium oxide, cerium dioxide, magnesium oxide, calcium oxide and/or another rare earth powder or a zirconium dioxide powder containing at least 12 mole-% of yttrium oxide and/or other stabilizer oxides, and then annealed at 1000.degree. to 1600.degree. C. until a more highly stabilized tetragonal or predominantly cubic surface layer of 0.1 to 200 micrometers thickness and 2 to 20 mole-% higher content of yttrium oxide, cerium dioxide, magnesium oxide, calcium oxide or rare earth oxide has formed.
    • 如果需要,包含氧化铝并用氧化钇和/或一种或多种稀土氧化物(例如二氧化铈)和/或氧化镁和/或氧化钙部分稳定的二氧化锆陶瓷体部分地用0.5 至5摩尔%的氧化钇和/或5至12摩尔%的氧化镁和/或氧化钙和/或二氧化铈或一种或多种稀土氧化物在正方晶格修饰中为30至100%,并且具有 在表面区域中,氧化钇,二氧化铈,氧化镁,氧化钙或稀土氧化物的含量比平均含量高1〜20摩尔%,使得体被薄的PSZ状层 在更高度稳定的四方晶体或主要以立方晶格形式的层。 为了制备,已经烧结或仅部分稳定化的氧化锆的预固化压块的表面与氧化钇,二氧化铈,氧化镁,氧化钙和/或其它稀土粉末或至少含有二氧化锆的二氧化锆粉末紧密接触 12摩尔%的氧化钇和/或其他稳定剂氧化物,然后在1000℃至1600℃下退火,直到厚度为0.1至200微米,高2至20摩尔%的更高稳定的四方晶或主要为立方的表面层 已经形成了氧化钇,二氧化铈,氧化镁,氧化钙或稀土氧化物的含量。