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1. 发明授权

US5453336A Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode 失效
标题翻译：具有碱性电解液的可充电锌电池抑制锌电极的形状变化
公开(公告)号：US5453336A
公开(公告)日：1995-09-26
申请号：US188039
申请日：1994-01-26
申请人： Thomas C. Adler , Frank R. McLarnon , Elton J. Cairns
发明人： Thomas C. Adler , Frank R. McLarnon , Elton J. Cairns
IPC分类号： H01M10/26 , H01M10/34
CPC分类号： H01M10/26
摘要： An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing one or more hydroxides having the formula M(OH), one or more fluorides having the formula MF, and one or more carbonates having the formula M.sub.2 CO.sub.3, where M is a metal selected from the group consisting of alkali metals. The electrolyte inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics.
摘要翻译：描述了一种改进的可充电锌电池，其包括锌电极和另一电极，例如含镍电极，并且具有含有一种或多种具有式M（OH）的氢氧化物的电解质，一种或多种具有式 MF和一种或多种具有式M2CO3的碳酸酯，其中M是选自碱金属的金属。电解液抑制锌电极的形状变化，即，锌电极的形状变化较小，导致电池在多次充放电循环中的容量保持率提高，同时仍保持高放电特性。

2. 发明授权

US5827580A Low temperature formation of electrode having electrically conductive metal oxide surface 失效
标题翻译：具有导电金属氧化物表面的电极的低温形成
公开(公告)号：US5827580A
公开(公告)日：1998-10-27
申请号：US625270
申请日：1996-03-27
申请人： Simone Anders , Andre Anders , Ian G. Brown , Frank R. McLarnon , Fanping Kong
发明人： Simone Anders , Andre Anders , Ian G. Brown , Frank R. McLarnon , Fanping Kong
IPC分类号： C23C14/00 , C23C14/08 , H01M4/26 , H01M4/32 , H01T14/00
CPC分类号： H01M4/32 , C23C14/0042 , C23C14/083 , H01M4/26
摘要： A low temperature process is disclosed for forming metal suboxides on substrates by cathodic arc deposition by either controlling the pressure of the oxygen present in the deposition chamber, or by controlling the density of the metal flux, or by a combination of such adjustments, to thereby control the ratio of oxide to metal in the deposited metal suboxide coating. The density of the metal flux may, in turn, be adjusted by controlling the discharge current of the arc, by adjusting the pulse length (duration of on cycle) of the arc, and by adjusting the frequency of the arc, or any combination of these parameters. In a preferred embodiment, a low temperature process is disclosed for forming an electrically conductive metal suboxide, such as, for example, an electrically conductive suboxide of titanium, on an electrode surface, such as the surface of a nickel oxide electrode, by such cathodic arc deposition and control of the deposition parameters. In the preferred embodiment, the process results in a titanium suboxide-coated nickel oxide electrode exhibiting reduced parasitic evolution of oxygen during charging of a cell made using such an electrode as the positive electrode, as well as exhibiting high oxygen overpotential, resulting in suppression of oxygen evolution at the electrode at full charge of the cell.
摘要翻译：公开了一种低温工艺，用于通过阴极电弧沉积在基板上形成金属低氧化物，方法是控制存在于沉积室中的氧气的压力，或通过控制金属熔剂的密度，或通过这些调节的组合，从而控制沉积的金属低氧化物涂层中氧化物与金属的比例。通过调整电弧的脉冲长度（周期的持续时间），并通过调整电弧的频率，或通过调整电弧的频率，可以通过控制电弧的放电电流来调整金属焊剂的密度这些参数。在优选实施例中，公开了一种低温工艺，用于在电极表面（例如氧化镍电极的表面）上形成导电金属低氧化物，例如钛的导电低氧化物，通过这种阴极电弧沉积和沉积参数的控制。在优选的实施方案中，该方法产生了一种低氧化钛涂层的氧化镍电极，其在使用如正极这样的电极制成的电池充电期间表现出减少的氧的寄生放电，并且表现出高的氧超电势，导致抑制在电池完全充电时电极的氧气释放。

3. 发明授权

US6118572A Photochromic, electrochromic, photoelectrochromic and photovoltaic devices 有权
标题翻译：光致变色，电致变色，光电色和光伏器件
公开(公告)号：US6118572A
公开(公告)日：2000-09-12
申请号：US346121
申请日：1999-07-01
申请人： Robert Kostecki , Frank R. McLarnon
发明人： Robert Kostecki , Frank R. McLarnon
IPC分类号： G02F1/163 , G02F1/15
CPC分类号： G02F1/163
摘要： A light activated photoelectrochromic device is formed of a two-component system formed of a photoactive charge carrier generating material and electrochromic material (plus an elecrolyte). Light interacts with a semiconductive material to generate hole-electron charge carriers which cause a redox reaction in the electrochromic material. One device is formed of hydrated nickel oxide as the electrochromic layer and polycrystalline titanium dioxide as the charge generating material. The materials may be formed as discrete layers or mixed together. Because of the direct charge transfer between the layers, a circuit to apply a voltage to drive the electrochromic reaction is not required, although one can be used to enhance the reaction. The hydrated nickel oxide-titanium dioxide materials can also be used to form a photovoltaic device for generating electricity.
摘要翻译：光活化光电装置由光活性电荷载体产生材料和电致变色材料（加上电解质）形成的双组分体系形成。光与半导体材料相互作用以产生在电致变色材料中引起氧化还原反应的空穴 - 电子电荷载体。一个装置由作为电致变色层的水合氧化镍和作为电荷产生材料的多晶二氧化钛形成。材料可以形成为离散层或混合在一起。由于层之间的直接电荷转移，不需要施加电压来驱动电致变色反应的电路，尽管可以使用它来增强反应。水合氧化镍 - 二氧化钛材料也可用于形成用于发电的光伏器件。

4. 发明授权

US5302475A Rechargeable zinc cell with alkaline electrolyte which inhibits shape change in zinc electrode 失效
标题翻译：具有碱性电解液的可充电锌电池抑制锌电极的形状变化
公开(公告)号：US5302475A
公开(公告)日：1994-04-12
申请号：US791583
申请日：1991-11-12
申请人： Thomas C. Adler , Frank R. McLarnon , Elton J. Cairns
发明人： Thomas C. Adler , Frank R. McLarnon , Elton J. Cairns
IPC分类号： H01M10/26 , H01M10/34
CPC分类号： H01M10/26
摘要： An improved rechargeable zinc cell is described comprising a zinc electrode and another electrode such as, for example, a nickel-containing electrode, and having an electrolyte containing KOH and a combination of KF and K.sub.2 CO.sub.3 salts which inhibits shape change in the zinc electrode, i.e., the zinc electrode exhibits low shape change, resulting in an improved capacity retention of the cell over an number of charge-discharge cycles, while still maintaining high discharge rate characteristics.
摘要翻译：描述了一种改进的可充电锌电池，其包括锌电极和另一电极，例如含镍电极，并且具有包含KOH的电解质和KF和K 2 CO 3盐的组合，其抑制锌电极中的形状变化，即锌电极表现出低的形状变化，导致电池在多次充放电循环中的容量保持率提高，同时仍然保持高放电特性。

5. 发明授权

US5169732A Sealed battery with integral reserve cell and switch 失效
标题翻译：密封电池与集成的储备电池和开关
公开(公告)号：US5169732A
公开(公告)日：1992-12-08
申请号：US649907
申请日：1991-02-04
申请人： Donald T. Beldock , Paul P. Craig , Frank R. McLarnon
发明人： Donald T. Beldock , Paul P. Craig , Frank R. McLarnon
IPC分类号： H01M2/10 , H01M2/20 , H01M2/30 , H01M6/30 , H01M6/42
CPC分类号： H01M2/30 , H01M2/105 , H01M2/20 , H01M6/30 , H01M6/425
摘要： A sealed battery is provided with a cathode, first and second anodes which are isolated by insulation, first and second current collectors which are separated by the insulation, and an integral switch. The cathode is coupled to a positive terminal of the battery, while the first current collector is coupled to the first anode and to the negative terminal. The second current collector is also coupled to the second terminal via the switch which is easily activated by hand manipulation or by use of a common object such as a ball point pen point. The cathode, first anode, and first current collector provide a large cell. When the large cell is exhausted, as indicated by the failure of the equipment which it is powering to function properly, the reserve cell comprised of the cathode, second anode, and second current collector is readily activated by manipulating the switch. The reserve cell may be smaller than the large cell but provides enough power to properly power the equipment until the batteries can be replaced.
摘要翻译：密封电池设有阴极，通过绝缘隔离的第一和第二阳极，由绝缘体隔开的第一和第二集电器以及集成开关。阴极耦合到电池的正极端子，而第一集电器耦合到第一阳极和负极端子。第二集电器还经由开关耦合到第二端子，该开关可以通过手动操作或通过使用诸如圆珠笔点的公共对象容易地启动。阴极，第一阳极和第一集电器提供大电池。当大电池耗尽时，正如供电正常工作的设备的故障所示，由阴极，第二阳极和第二集电器构成的储备电池通过操纵开关而容易地起动。备用电池可能小于大电池，但提供足够的电力以正确为电源供电，直到电池可以更换。

6. 发明授权

US3663300A Foam electrolyte, fuel cell, and method for increasing effectiveness of fuel cells 失效
标题翻译：泡沫电解质，燃料电池和用于提高燃料电池效率的方法
公开(公告)号：US3663300A
公开(公告)日：1972-05-16
申请号：US3663300D
申请日：1969-06-12
申请人： LEONARD NANIS , FRANK R MCLARNON
发明人： NANIS LEONARD , MCLARNON FRANK R
IPC分类号： H01M8/08 , H01M27/00
CPC分类号： H01M8/08
摘要： The introduction of one or more ingredients of a chemical reaction into a foam atmosphere for the purpose of promoting such reaction. With respect to the application of the present invention to fuel cells, the electrolyte in one or both the anode and cathode cabinets of a fuel cell is modified with the addition of a foaming agent so that the electrodes of the cell are in contact with foamed electrolyte.
摘要翻译：将一种或多种化学反应成分引入泡沫气氛中以促进这种反应。关于本发明在燃料电池中的应用，通过添加发泡剂来改变燃料电池的阳极室和阴极室中的一个或两个中的电解质，使得电池的电极与泡沫电解质接触。

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