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1. 发明授权

US4528401A Catalytic process for the manufacture of ketones 失效
标题翻译：用于制造酮的催化方法
公开(公告)号：US4528401A
公开(公告)日：1985-07-09
申请号：US516903
申请日：1983-07-25
申请人： Chuen Y. Yeh , Charles Savini
发明人： Chuen Y. Yeh , Charles Savini
IPC分类号： C07C45/28 , C07C45/42
CPC分类号： C07C45/28
摘要： An improved process is provided for forming ketones from the corresponding olefins in the vapor phase in the presence of water vapor employing a heterogeneous catalyst comprising a molybdenum disulfide catalyst formed by the thermal decomposition of a thiomolybdate compound. It has been surprisingly found that these catalysts effect the formation of ketones in high selectivities with minimal selectivities to the undesirable carbon dioxide and carbon monoxide by-products.
摘要翻译：提供了一种改进的方法，用于在水蒸气存在下，使用包含通过硫钼酸盐化合物的热分解形成的二硫化钼催化剂的多相催化剂在气相中从相应的烯烃形成酮。已经令人惊奇地发现，这些催化剂以高选择性的方式影响酮的形成，对不期望的二氧化碳和一氧化碳副产物的选择性最小。

2. 发明授权

US4219685A Improving odor of isopropanol 失效
标题翻译：改善异丙醇的气味
公开(公告)号：US4219685A
公开(公告)日：1980-08-26
申请号：US31761
申请日：1979-04-20
申请人： Charles Savini
发明人： Charles Savini
IPC分类号： C07C29/76 , C07C29/80 , C07C29/82 , C07C29/84 , C07C29/24
CPC分类号： C07C29/82 , C07C29/76 , C07C29/80 , C07C29/84
摘要： Methods for deodorizing lower alcohols such as ethanol and isopropyl alcohol and their oxy derivatives such as ethers and esters are disclosed, including contacting these compounds with a deodorizing contact mass comprising, on a support, metals and/or metal oxides, preferably of the metals of Group IB, VIB and VIII of the Periodic Table, where the metal oxides are at least partially reduced to metal and the deodorizing contact mass has a minimum particle dimension of greater than about 0.254 mm so as to be in a form suitable for use in a fixed bed contacting process. In a preferred embodiment, isopropyl alcohol is deodorized employing such deodorizing contact masses, preferably comprising Group VIII metals such as nickel, iron, cobalt and the like, on a support, so that the contact mass has a surface area less than about 1,500 m.sup.2 per gram.Overall isopropyl alcohol finishing procedures are also disclosed employing such deodorizing methods in combination with extractive distillation procedures to produce a high grade, e.g., 91%, and/or anhydrous grade isopropyl alcohol from a crude isopropyl alcohol stream containing more than about 0.0005 percent water.
摘要翻译：公开了用于除去低级醇如乙醇和异丙醇及其氧衍生物如醚和酯的除臭方法，包括使这些化合物与除臭接触物质接触，所述除臭接触物质在载体上包含金属和/或金属氧化物，优选金属和/ 元素周期表IB，VIB和VIII族，其中金属氧化物至少部分还原成金属，并且除臭接触物质具有大于约0.254mm的最小颗粒尺寸，以便成为适合用于固定床接触过程。在一个优选的实施方案中，使用这种除臭接触块，优选包含第VIII族金属如镍，铁，钴等在支撑体上除异丙醇，使得接触物质的表面积小于约1500m 2 / 公克。还公开了使用这种除臭方法与萃取蒸馏方法组合以从含有大于约0.0005％水的粗异丙醇流中生产高级，例如91％和/或无水级异丙醇的整体异丙醇精制程序。

3. 发明授权

US4876392A Process for preparation of keystones by oxidation of secondary alcohols using a trimetallic catalyst comprising molybdenum, rhenium and a group VIII noble metal 失效
标题翻译：通过使用包含钼，铼和VIII族贵金属的三金属催化剂氧化仲醇来制备基石的方法
公开(公告)号：US4876392A
公开(公告)日：1989-10-24
申请号：US174126
申请日：1988-03-28
申请人： Chuen Y. Yeh , Charles Savini
发明人： Chuen Y. Yeh , Charles Savini
IPC分类号： B01J23/36 , B01J23/656 , C07C45/28 , C07C45/29 , C07C45/34
CPC分类号： C07C45/34 , B01J23/36 , B01J23/6567 , C07C45/28 , C07C45/29
摘要： An improved process for preparing ketones by contacting a secondary aliphatic alcohol in the vapor phase with a trimetallic catalyst containing molybdenum, rhenium and a Group VIII noble metal.
摘要翻译：通过使气相中的仲脂族醇与含有钼，铼和VIII族贵金属的三金属催化剂接触来制备酮的改进方法。

4. 发明授权

US4406760A Electrolytic process for treating sulfuric acid streams 失效
标题翻译：用于处理硫酸流的电解过程
公开(公告)号：US4406760A
公开(公告)日：1983-09-27
申请号：US325002
申请日：1981-11-25
申请人： George A. Knudsen , Charles Savini
发明人： George A. Knudsen , Charles Savini
IPC分类号： C25B3/02 , C01B17/90 , C07C27/00 , C07C29/06 , C07C31/02 , C07C67/00
CPC分类号： C01B17/90
摘要： An improved process is provided for treating spent sulfuric acid streams formed in the catalytic hydration of olefins to prepare alcohols, wherein the spent acid stream containing organo-sulfonic acid impurities is treated in an electrolysis zone under conditions sufficient to electrolytically oxidize at least a portion of said organo-sulfonic acid impurities to form partially oxidized organic compounds therefrom and thereby provide a treated sulfuric acid stream of increased thermal stability. The improved process permits continuous operation at levels of total organic carbon in the treated acid which would otherwise be unacceptable and minimizes the substantial operating problems associated with formation of heavy carbon deposits in the process equipment.
摘要翻译：提供了一种改进的方法，用于处理在烯烃的催化水合中形成的废硫酸流以制备醇，其中含有机磺酸杂质的废酸流在电解区中在足以电解氧化至少一部分所述有机磺酸杂质从其形成部分氧化的有机化合物，从而提供具有增加的热稳定性的经处理的硫酸流。改进的方法允许在经处理的酸中的总有机碳的水平下连续操作，否则将是不可接受的，并且使与工艺设备中的重碳沉积物形成相关的实质操作问题最小化。

5. 发明授权

US4649223A Catalysts and process for the conversion of olefins to ketones 失效
标题翻译：用于将烯烃转化为酮的催化剂和方法
公开(公告)号：US4649223A
公开(公告)日：1987-03-10
申请号：US776790
申请日：1985-09-16
申请人： Chuen Y. Yeh , Charles Savini
发明人： Chuen Y. Yeh , Charles Savini
IPC分类号： B01J23/36 , B01J23/656 , C07C45/28 , C07C45/29 , C07C45/34 , C07C45/00
CPC分类号： C07C45/34 , B01J23/36 , B01J23/6567 , C07C45/28 , C07C45/29
摘要： An improved process is provided for forming ketones from the corresponding olefins in the vapor phase in the presence of water vapor employing a heterogeneous catalyst comprising rhenium compounds and complexes, optionally containing at least one metal compound or complex selected from the group consisting of Group VIB metals and Group VIII noble metals, and mixtures thereof. It has been surprisingly found that these catalysts effect the formation of ketones in high selectivities with minimal selectivities to the undesirable carbon dioxide and carbon monoxide by-products.
摘要翻译：提供了一种改进的方法，用于在水蒸气存在下，使用包含铼化合物和配合物的非均相催化剂，任选地含有至少一种金属化合物或选自由VIB族金属组成的组的复合物，在蒸气相中形成酮和VIII族贵金属及其混合物。已经令人惊奇地发现，这些催化剂以高选择性的方式影响酮的形成，对不期望的二氧化碳和一氧化碳副产物的选择性最小。

6. 发明授权

US4560805A Catalysts and process for the conversion of olefins to ketones 失效
公开(公告)号：US4560805A
公开(公告)日：1985-12-24
申请号：US516902
申请日：1983-07-25
申请人： Chuen Y. Yeh , Charles Savini
发明人： Chuen Y. Yeh , Charles Savini
IPC分类号： B01J23/36 , B01J23/656 , C07C45/28 , C07C45/29 , C07C45/34 , C07C45/42
CPC分类号： C07C45/34 , B01J23/36 , B01J23/6567 , C07C45/28 , C07C45/29
摘要： An improved process is provided for forming ketones from the corresponding olefins in the vapor phase in the presence of water vapor employing a heterogeneous catalyst comprising rhenium compounds and complexes, optionally containing at least one metal compound or complex selected from the group consisting of Group VIB metals and Group VIII noble metals, and mixtures thereof. It has been surprisingly found that these catalysts effect the formation of ketones in high selectivities with minimal selectivities to the undesirable carbon dioxide and carbon monoxide by-products.

7. 发明授权

US4737482A Catalysts for oxidation of olefins to ketones 失效
标题翻译：用于将烯烃氧化成酮的催化剂
公开(公告)号：US4737482A
公开(公告)日：1988-04-12
申请号：US776228
申请日：1985-09-16
申请人： Chuen Y. Yeh , Charles Savini
发明人： Chuen Y. Yeh , Charles Savini
IPC分类号： B01J23/36 , B01J23/656 , C07C45/28 , C07C45/29 , C07C45/34 , B01J27/051 , B01J27/045 , B01J27/047 , B01J27/049
CPC分类号： C07C45/29 , B01J23/36 , B01J23/6567 , C07C45/28 , C07C45/34
摘要： An improved process is provided for forming ketones from the corresponding olefins by vapor phase oxidiation of the olefin in the presence of molecular oxygen and water vapor employing a heterogeneous catalyst comprising rhenium compounds and complexes, optionally containing at least one metal compound or complex selected from the group consisting of Group VIB metals and Group VIII noble metals, and mixtures thereof. It has been surprisingly found that these catalysts effect the formation of ketones in high selectivities with minimal selectivities to the undesirable carbon dioxide and carbon monoxide by-products.
摘要翻译：提供了一种改进的方法，用于在分子氧和水蒸汽的存在下，使用包含铼化合物和络合物的非均相催化剂，任选地含有至少一种选自以下的金属化合物或络合物的复合物，通过气相氧化烯烃从相应的烯烃形成酮：由VIB族金属和VIII族贵金属组成的组，及其混合物。已经令人惊奇地发现，这些催化剂以高选择性的方式影响酮的形成，对不期望的二氧化碳和一氧化碳副产物的选择性最小。

8. 发明授权

US4560804A Catalytic process for the manufacture of ketones 失效
标题翻译：用于制造酮的催化方法
公开(公告)号：US4560804A
公开(公告)日：1985-12-24
申请号：US516537
申请日：1983-07-25
申请人： Chuen Y. Yeh , Charles Savini
发明人： Chuen Y. Yeh , Charles Savini
IPC分类号： B01J27/04 , C07C45/28 , C07C45/34 , C07C45/42
CPC分类号： B01J27/04 , C07C45/28 , C07C45/34
摘要： An improved process is provided for forming ketones from the corresponding olefins by vapor phase oxidation of the olefin in the presence of water vapor, and optionally in the additional presence of molecular oxygen employing a heterogeneous catalyst comprising at least one member selected from the group consisting of Ce, Nd and La and compounds and complexes thereof, optionally containing at least one metal compound or complex selected from the group consisting of Group VIB metals and Group VIII noble metals, and mixtures thereof. It has been surprisingly found that these catalysts effect the formation of ketones in high selectivities with minimal selectivities to the undesirable carbon dioxide and carbon monoxide by-products.
摘要翻译：提供了一种改进的方法，用于在水蒸气存在下通过气相氧化烯烃从相应的烯烃形成酮，并且任选地在额外存在分子氧的情况下，使用包含至少一种选自以下的组分的多相催化剂： Ce，Nd和La及其化合物和络合物，任选地含有至少一种选自VIB族金属和VIII族贵金属的金属化合物或络合物，及其混合物。已经令人惊奇地发现，这些催化剂以高选择性的方式影响酮的形成，对不期望的二氧化碳和一氧化碳副产物的选择性最小。

9. 发明授权

US4560803A Catalysts and process for oxidation of olefins to ketones 失效
标题翻译：将烯烃氧化成酮的催化剂和方法
公开(公告)号：US4560803A
公开(公告)日：1985-12-24
申请号：US516901
申请日：1983-07-25
申请人： Chuen Y. Yeh , Charles Savini
发明人： Chuen Y. Yeh , Charles Savini
IPC分类号： B01J23/36 , B01J23/656 , C07C45/28 , C07C45/29 , C07C45/34 , C07C45/39
CPC分类号： C07C45/34 , B01J23/36 , B01J23/6567 , C07C45/28 , C07C45/29
摘要： An improved process is provided for forming ketones from the corresponding olefins by vapor phase oxidation of the olefin in the presence of molecular oxygen and water vapor employing a heterogeneous catalyst comprising rhenium compounds and complexes, optionally containing at least one metal compound or complex selected from the group consisting of Group VIB metals and Group VIII noble metals, and mixtures thereof. It has been surprisingly found that these catalysts effect the formation of ketones in high selectivities with minimal selectivities to the undesirable carbon dioxide and carbon monoxide by-products.
摘要翻译：提供了一种改进的方法，用于通过使用包含铼化合物和络合物的非均相催化剂在分子氧和水蒸汽存在下气相氧化烯烃来形成酮，任选地含有至少一种选自以下的金属化合物或络合物：由VIB族金属和VIII族贵金属组成的组，及其混合物。已经令人惊奇地发现，这些催化剂以高选择性的方式影响酮的形成，对不期望的二氧化碳和一氧化碳副产物的选择性最小。

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