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    • 1. 发明申请
    • WATER ABSORBING AGENT, WATER ABSORBING ARTICLE AND METHOD FOR PRODUCTION OF WATER ABSORBING AGENT
    • 吸水剂,吸水剂及其吸水剂的生产方法
    • WO2006088115A1
    • 2006-08-24
    • PCT/JP2006/302782
    • 2006-02-10
    • NIPPON SHOKUBAI CO., LTD.KIMURA, KazukiFUJINO, Shin-ichiWADA, KatsuyukiISHIZAKI, Kunihiko
    • KIMURA, KazukiFUJINO, Shin-ichiWADA, KatsuyukiISHIZAKI, Kunihiko
    • C08J3/12
    • A61L15/60B01J20/26B01J20/264B01J20/267B01J20/28004B01J20/2803B01J20/28047B01J20/30B01J20/3028B01J2220/68C08J3/245C08J2300/14Y10T428/2982Y10T428/2991Y10T428/2998
    • An object of the present invention is to provide a water absorbing agent having a low amount of residual monomer, small variance of the amount of residual monomer among ranges of particle size distribution and favorable absorption properties, and being sanitary; an absorbing article; and a method for the production of a water absorbing agent. The water absorbing agent of the present invention has the amount of residual monomer of not higher than 500 ppm, and a residual monomer index of not greater than 0.30.The method for the production includes a first step of obtaining a hydrogel polymer by polymerizing an aqueous solution of a monomer including an unsaturated carboxylic acid and/or a salt thereof in the presence of a crosslinking agent;a second step of obtaining a water absorbent resin precursor which is in powder form and includes particles having a particle size of 300 to 850 µm and particles having a particle size of smaller than 300 µm as main components by drying said hydrogel polymer followed by pulverization and classification to adjust the particle size distribution,a third step of obtaining a water absorbent resin by heating a mixture of said water absorbent resin precursor and a surface crosslinking agent, which can form an ester bond around the surface of said water absorbent resin precursor,a fourth step of adding by spraying an aqueous solution that includes a sulfur-containing reducing agent to said water absorbent resin, and a fifth step of subjecting the mixture of the water absorbent resin and said aqueous solution to a heat treatment under an airflow of not lower than 40°C but not higher than 120°C.
    • 本发明的目的是提供一种具有少量残留单体的吸水剂,在粒度分布范围和吸收性能良好之间的残留单体量的变化小,并且是卫生的; 吸收物品 和吸水剂的制造方法。 本发明的吸水剂的残留单体的量不高于500ppm,残留单体指数不大于0.30。制备方法包括通过聚合水性聚合物获得水凝胶聚合物的第一步骤 包含不饱和羧酸和/或其盐的单体在交联剂存在下的溶液;第二步,获得粉末形式的吸水性树脂前体,并且包括粒度为300至850μm的颗粒 粒径小于300μm的颗粒作为主要组分,通过干燥所述水凝胶聚合物,然后粉碎和分级以调节粒度分布;第三步骤,通过加热所述吸水性树脂前体的混合物获得吸水性树脂 以及可在所述吸水性树脂前体的表面周围形成酯键的表面交联剂,第四步骤 通过将包含含硫还原剂的水溶液喷雾到所述吸水性树脂中而添加,第五步是在吸水性树脂和所述水溶液的混合物在不低于40°的气流下进行热处理 但不高于120℃。
    • 3. 发明申请
    • FOLDER FOR FILING
    • 文件夹填写
    • WO2008050469A1
    • 2008-05-02
    • PCT/JP2007/001083
    • 2007-10-04
    • Cosmicdyne International Corporation
    • SHIMANAKA, Yoshihiro
    • B42F11/00B42F13/00
    • B42F11/00B42F13/26B42F15/0041
    • A folder (2) for filing is constituted to be accommodated in a file having two bars, and includes a restricting portion (4) for restricting a paper, and a hook portion (6) connected to a rear part of the restricting portion (4). The hook portion (6) is connected to the rear part of the restricting portion (4). The hook portion (6) includes a longitudinal guide (8) extended in a longitudinal direction from an edge (14) of the hook portion (6) and a lateral guide (10) extended forward from the other edge (14) of the hook portion (6). The longitudinal guide (8) is fitted in one of the bars and the hook portion (6) is thus rotated around the bar so that the lateral guide (10) can be fitted in the other bar.
    • 用于填充的文件夹(2)被构造成容纳在具有两个杆的文件中,并且包括用于限制纸张的限制部分(4)和连接到限制部分(4)的后部的钩部分 )。 钩部(6)与限制部(4)的后部连接。 钩部分(6)包括从钩部(6)的边缘(14)沿纵向方向延伸的纵向引导件(8)和从钩子的另一边缘(14)向前延伸的侧向引导件 部分(6)。 纵向引导件(8)装配在一个杆中,并且钩部(6)因此围绕杆旋转,使得侧向引导件(10)可以装配在另一个杆中。