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    • 4. 发明申请
    • METHOD OF PRODUCING SODIUM CARBONATE DECAHYDRATE
    • 生产碳酸钠的方法
    • WO2009068670A1
    • 2009-06-04
    • PCT/EP2008/066470
    • 2008-11-28
    • SOLVAY CHEMICALS, INC.HANSEN, David M.FULLER, John T.
    • HANSEN, David M.FULLER, John T.
    • C01D7/00C01D7/24
    • C01D7/00C01D7/24C01P2006/10C01P2006/60
    • A method of producing crystals of crystallizable mineral salt comprises introducing an effluent comprising a dissolved crystallizable mineral salt at a temperature higher than the mineral salt crystallization temperature to a crystallization pond area to provide a pond solution; cooling the pond solution to provide cooling crystallization promoting conditions effective to form a crystalline mineral salt deposit; stopping the flow of the effluent; draining remaining spent liquor to a liquor pond area; and recovering the deposit. Cooling the pond solution may comprise exposure to cool ambient temperatures which are lower than the crystallization temperature. Preferably, the mineral salt includes or is sodium carbonate decahydrate; the pond solution comprises less than 10 % NaCl; and/or the decahydrate deposit is sent or recycled to a soda ash plant. The deposit thus formed by cooling crystallization has a higher purity, lower hardness, and/or lower density than a deposit formed by evaporative crystallization.
    • 一种生产可结晶矿物盐晶体的方法包括在高于矿物盐结晶温度的温度下将包含溶解的可结晶矿物盐的流出物引入结晶池区域以提供池溶液; 冷却池塘溶液以提供有效形成结晶矿物盐沉积物的冷却结晶促进条件; 停止流出物的流动; 将剩余的废液排入酒池区域; 并收回存款。 冷却池塘溶液可能包括暴露于低于结晶温度的冷环境温度。 优选地,矿物盐包括或是碳酸钠十水合物; 池塘溶液含有少于10%的NaCl; 和/或十水合物沉积物被送回或再循环到苏打灰厂。 通过冷却结晶形成的沉积物具有比通过蒸发结晶形成的沉积物更高的纯度,更低的硬度和/或更低的密度。