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    • 2. 发明申请
    • POLYPROPYLENE FIBER
    • 聚丙烯纤维
    • WO2014005816A1
    • 2014-01-09
    • PCT/EP2013/062245
    • 2013-06-13
    • BASELL POLIOLEFINE ITALIA S.R.L.
    • GALVAN, MonicaNEUMANN, AndreasPANTALEONI, RobertoMAZZUCCO, AntonioFUSCO, OfeliaGADDI, BenedettaCOLLINA, Gianni
    • D01F6/06C08F4/651C08F10/06
    • D01F6/06B29C47/0004B29K2023/12B29L2031/731D04H3/007D04H3/016D04H3/16D10B2321/022Y10T442/681C08F10/00C08F4/651C08F4/6545C08F4/6492C08F110/06C08F2500/12
    • Fibers comprising a polypropylene obtainable by a process comprising the steps of: (i) polymerizing propylene in the presence of a catalyst system comprising the product obtained by contacting the following components: (a) a solid catalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being present in an amount from 40 to 90% by mol with respect to the total amount of donors and selected from succinates and the other being selected from 1,3 diethers, (b) an aluminum hydrocarbyl compound, and (c) optionally an external electron donor compound, to obtain a polypropylene precursor having a melt flow rate MFRl; (ii) subjecting the thus-obtained polypropylene precursor to visbreaking to obtain a visbroken polypropylene having a melt flow rate MFR2; (iii) spinning the visbroken polypropylene obtained in the previous step; wherein MFR2 is comprised between from 15 to 40 g/10min, the ratio MFR2/MFR1 is comprised between 8 and 18, both MFRl and MFR2 being measured according to ISO method 1133 (230° C, 2.16 kg).
    • 包含聚丙烯的纤维包括以下步骤:(i)在催化剂体系存在下聚合丙烯,所述催化剂体系包含通过使以下组分接触获得的产物:(a)固体催化剂组分,其包含卤化镁,钛化合物 具有至少一个Ti-卤素键和至少两个电子给体化合物,其中一种以相对于供体总量为40-90%摩尔量存在,选自琥珀酸盐,另一种选自1, 3二醚,(b)铝烃基化合物和(c)任选的外电子给体化合物,以获得熔体流动速率MFR1的聚丙烯前体; (ii)将由此获得的聚丙烯前体进行减粘裂化以得到熔体流动速率MFR 2的减粘裂化聚丙烯; (iii)纺丝上一步获得的耐磨破坏聚丙烯; 其中MFR 2为15至40g / 10min,MFR 2 / MFR 1的比率为8至18,根据ISO方法1133(230℃,2.16kg)测量MFR1和MFR2。
    • 5. 发明申请
    • SOFT POLYOLEFIN COMPOSITIONS AND HIGHLY FILLED COMPOUNDS THEREOF
    • 软的聚烯烃组合物及其高填充化合物
    • WO2012152802A1
    • 2012-11-15
    • PCT/EP2012/058476
    • 2012-05-09
    • BASELL POLIOLEFINE ITALIA S.R.L.GOBERTI, PaoloPELLEGATTI, GiampaoloLUNGHI, Luca
    • GOBERTI, PaoloPELLEGATTI, GiampaoloLUNGHI, Luca
    • C08L23/10C08L23/16C08K3/00
    • C08L23/14C08K3/00C08L23/10C08L23/16Y10T428/2933
    • Flexible polyolefin compositions with improved balance of properties particularly for applications where softness and ductility at low temperature is requested comprising: A) from 20 to 40% by weight of a crystalline polymer fraction consisting of a propylene homopolymer, or a copolymer of propylene, or mixtures thereof, said crystalline fraction having a xylene insoluble fraction at 25°C of at least 90% by weight,. B) from 60 to 80 % by weight of an elastomeric fraction consisting of a copolymeror blend of copolymers of propylene with one or more alpha-olefins, and optionally with minor quantities of a diene; said copolymer or blend containing ethylene in a quantity lower than 40% by weight. the fraction soluble in xylene at 25°C of said polyolefin composition having IVgpc lower than 2.5 dl/g, Mw/Mn (GPC) equal to or higher than 4, Mz/Mw (GPC) equal to or higher than 2.5. Said polyolefin composition optionally further comprising an inorganic filler (II) selected from flame-retardant inorganic fillers and inorganic oxides or salts.
    • 具有改善的性能平衡的柔性聚烯烃组合物,特别适用于要求低温柔软度和延展性的应用,包括:A)20-40重量%的由丙烯均聚物或丙烯共聚物或其混合物组成的结晶聚合物部分 所述结晶部分在25℃下的二甲苯不溶部分至少为90重量%。 B)60至80重量%的由丙烯与一种或多种α-烯烃的共聚物和任选地少量二烯的共聚物共混物组成的弹性体级分; 所述共聚物或共混物含有低于40重量%的乙烯。 所述聚烯烃组合物在25℃下可溶于二氯甲烷的馏分具有低于2.5dl / g,Mw / Mn(GPC)等于或高于4,Mz / Mw(GPC)等于或高于2.5的聚烯烃组合物。 所述聚烯烃组合物任选地还包含选自阻燃无机填料和无机氧化物或盐的无机填料(II)。