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1. 发明申请

WO2011076357A1 PREPARATION OF METAL OXIDE NANOTUBES 审中-公开
标题翻译：金属氧化物纳米管的制备
公开(公告)号：WO2011076357A1
公开(公告)日：2011-06-30
申请号：PCT/EP2010/007669
申请日：2010-12-16
申请人： BASELL POLYOLEFINE GMBH , MÜLLER, Georg , MÜLHAUPT, Rolf , KRISTEN, Marc, Oliver
发明人： MÜLLER, Georg , MÜLHAUPT, Rolf , KRISTEN, Marc, Oliver
IPC分类号： D01F9/10 , B82Y40/00
CPC分类号： D01F9/10 , B01J21/08 , B01J35/06 , B01J37/0018 , B82Y30/00 , B82Y40/00 , C01B33/18 , C04B35/62807 , C04B35/63416 , C04B2235/3418 , C04B2235/444 , C04B2235/5264 , C04B2235/5284 , C04B2235/5409 , C04B2235/6028 , D01D5/24
摘要： The present invention relates to a preparation process for metal oxide nanotubes, the SiO 2 nanotubes prepared by this process and the use of these nanotubes as catalyst supports. The invention especially concerns a supported catalyst system for polymerization of olefins, comprising a support made of fibers or a fleece of fibers.
摘要翻译：本发明涉及金属氧化物纳米管的制备方法，通过该方法制备的SiO 2纳米管和这些纳米管作为催化剂载体的用途。本发明特别涉及用于烯烃聚合的负载催化剂体系，其包括由纤维制成的载体或纤维的绒毛。

2. 发明申请

WO2010072367A1 METHOD FOR TRANSITIONING BETWEEN INCOMPATIBLE OLEFIN POLYMERIZATION CATALYST SYSTEMS 审中-公开
标题翻译：不可溶性烯烃聚合催化剂体系的转移方法
公开(公告)号：WO2010072367A1
公开(公告)日：2010-07-01
申请号：PCT/EP2009/009066
申请日：2009-12-17
申请人： BASELL POLYOLEFINE GMBH , MEIER, Gerhardus , MIHAN, Shahram
发明人： MEIER, Gerhardus , MIHAN, Shahram
IPC分类号： C08F10/00 , C08F2/34 , C08F2/42
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F2410/05 , C08F4/69 , C08F4/642 , C08F2/34 , C08F2/42 , C08F210/08 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/07 , C08F4/7042 , C08F4/61904
摘要： A method for transitioning from a Ziegler-Natta to a Phillips catalyst system for the olefin polymerization reaction in one reactor, preferably a gas phase reactor, is described. The method comprises the steps of a) discontinuing a first olefin polymerization reaction performed in the presence of the Ziegler-Natta catalyst system; b) performing a second olefin polymerization reaction in the presence of a further catalyst system comprising catalyst components (A) and (B) producing, respectively, a first and a second polyolefin fraction, wherein the M w of the first polyolefin fraction is less than the M w of the second polyolefin fraction and the initial activity of catalyst component (A) exceeds the initial activity of catalyst component (B); and c) performing a third olefin polymerization reaction the presence of the Phillips catalyst system. Thanks to this method, there is no need to empty the reactor after each olefin polymerization reaction, and the transitioning time needed to attain the desired quality of the polyolefin obtained in each olefin polymerization reaction subsequent to the first one is sufficiently short to permit a quick and reliable change of production.
摘要翻译：描述了在一个反应器，优选气相反应器中从齐格勒 - 纳塔过渡到用于烯烃聚合反应的菲利普斯催化剂体系的方法。该方法包括以下步骤：a）停止在齐格勒 - 纳塔催化剂体系存在下进行的第一种烯烃聚合反应; b）在另外的催化剂体系存在下进行第二烯烃聚合反应，所述催化剂体系包含分别产生第一和第二聚烯烃部分的催化剂组分（A）和（B），其中第一聚烯烃部分的Mw小于第二聚烯烃级分的Mw和催化剂组分（A）的初始活性超过催化剂组分（B）的初始活性; 和c）进行第三烯烃聚合反应的存在的菲利浦催化剂体系。由于这种方法，在每个烯烃聚合反应之后不需要清空反应器，并且在第一个烯烃聚合反应之后获得的每个烯烃聚合反应中获得的聚烯烃所需的质量所需的转化时间足够短，以使快速可靠的生产变更。

3. 发明申请

WO2006092378A1 POLYETHYLENE MOLDING COMPOSITION FOR PRODUCING BLOWN FILMS HAVING IMPROVED PROCESSABILITY 审中-公开
标题翻译：用于生产具有改进的可加工性的薄膜的聚乙烯模塑组合物
公开(公告)号：WO2006092378A1
公开(公告)日：2006-09-08
申请号：PCT/EP2006/060223
申请日：2006-02-23
申请人： BASELL POLYOLEFINE GMBH , BERTHOLD, Joachim , HEINICKE, Lutz-Gerd , MEIER, Gerhardus
发明人： BERTHOLD, Joachim , HEINICKE, Lutz-Gerd , MEIER, Gerhardus
IPC分类号： C08J5/18 , C08L23/04
CPC分类号： C08L23/06 , C08J5/18 , C08J2323/04 , C08J2323/06 , C08J2423/08 , C08L23/04 , C08L23/08 , C08L23/0807 , C08L23/0815 , C08L2203/16 , C08L2205/025 , C08L2205/03 , C08L2666/06
摘要： The invention relates to a polyethylene molding composition having a multimodal molar mass distribution particularly suitable for blow molding films having a thickness in the range from 8 to 200 μm. The molding composition has a density at a temperature of 23 °C in the range from 0.953 to 0.960 g/cm3 and an MFR190/5 of the final product after extrusion in the range from 0.10 to 0.50 dg/min. The composition comprises from 30 to 60% by weight of a first ethylene polymer fraction made of a homopolymer A having a first molecular weight, from 22 to 40% by weight of a second ethylene polymer fraction made of a further homopolymer or first copolymer B of ethylene and at least one first comonomer from the group of olefins having from 4 to 8 carbon atoms, the first copolymer B having a second molecular weight higher than the first molecular weight, and from 10 to 30% by weight of a third ethylene polymer fraction made of a second copolymer C having a third molecular weight higher than the second molecular weight. The molding composition of the invention allows to produce thin films having improved processability without impairing the mechanical properties.
摘要翻译：本发明涉及具有特别适用于厚度在8至200μm范围内的吹塑薄膜的多峰摩尔质量分布的聚乙烯模塑组合物。模塑组合物的密度在23℃的温度范围为0.953至0.960g / cm3，挤出后的最终产品的MFR 190/5为0.10至0.50dg / min。该组合物包含30至60重量％的由具有第一分子量的均聚物A制成的第一乙烯聚合物部分，22至40重量％的由其它均聚物或第一共聚物B制成的第二乙烯聚合物部分乙烯和来自具有4至8个碳原子的烯烃基团的至少一种第一共聚单体，第一共聚物B具有高于第一分子量的第二分子量和10至30重量％的第三乙烯聚合物部分由具有高于第二分子量的第三分子量的第二共聚物C制成。本发明的模塑组合物允许制造具有改进加工性能的薄膜而不损害机械性能。

4. 发明申请

WO2006053740A1 POLYETHYLENE MOLDING COMPOSITION FOR EXTERNAL SHEATHING OF ELECTRIC CABLES 审中-公开
标题翻译：聚乙烯模塑组合物电外部外露
公开(公告)号：WO2006053740A1
公开(公告)日：2006-05-26
申请号：PCT/EP2005/012305
申请日：2005-11-17
申请人： BASELL POLYOLEFINE GMBH , VOGT, Heinz , BERTHOLD, Joachim
发明人： VOGT, Heinz , BERTHOLD, Joachim
IPC分类号： C08L23/06
CPC分类号： C08L53/00 , C08F210/16 , C08F297/08 , C08F297/083 , C08L23/06 , C08L23/08 , C08L23/0807 , C08L23/0815 , C08L2203/202 , C08L2205/02 , C08L2205/03 , C08L2314/02 , H01B3/441 , Y10T428/1352 , Y10T428/139 , Y10T428/294 , C08F2/001 , C08L2666/06 , C08L2666/02 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08F2500/17 , C08F2500/05 , C08F2500/01 , C08F2500/02
摘要： The invention relates to a polyethylene molding composition which has a multimodal molar mass distribution and is particularly suitable for producing external sheathing of electric or information transmission cables. The molding composition has a density at a temperature of 23°C in the range from 0.94 to 0.95 g/cm3 and an MFI19015 in the range from 1.2 to 2.1 dg/min. It comprises from 45 to 55% by weight of a low molecular weight ethylene homopolymer A, from 30 to 40% by weight of a high molecular weight copolymer B of ethylene and another olefin having from 4 to 8 carbon atoms and from 10 to 20% by weight of an ultra high molecular weight ethylene copolymer C. The invention also relates to an electric or information transmission cable having an external sheath of the polyethylene molding composition which has'a thickness in the range from-0.2 to 3 cm.
摘要翻译：本发明涉及一种具有多峰摩尔质量分布的聚乙烯模塑组合物，特别适用于生产电或信息传输电缆的外护套。模塑组合物的温度为23℃，密度为0.94〜0.95g / cm3，MFI19015为1.2〜2.1dg / min。它包含45至55重量％的低分子量乙烯均聚物A，30至40重量％的乙烯和另外具有4至8个碳原子的烯烃和10至20重量％的高分子量共聚物B，重量的超高分子量乙烯共聚物C.本发明还涉及具有聚乙烯模塑组合物的外护套的电信息传输电缆或信息传输电缆，其厚度在-0.2至3厘米的范围内。

5. 发明申请

WO2006048278A1 PRESSURE TRANSDUCER 审中-公开
标题翻译：压力传感器
公开(公告)号：WO2006048278A1
公开(公告)日：2006-05-11
申请号：PCT/EP2005/011754
申请日：2005-11-03
申请人： BASELL POLYOLEFINE GMBH , GROOS, Georg , HAMMER, Klaus , SCHMITT, Martin , ROUWEN, Stefan
发明人： GROOS, Georg , HAMMER, Klaus , SCHMITT, Martin , ROUWEN, Stefan
IPC分类号： G01L9/04
CPC分类号： G01L9/0002
摘要： The invention relates to a pressure transducer for chemical reactors comprising an elastically deformable essentially cylindrical deforming body having an outer surface being at least partially in direct contact with the process medium and an inner surface on which at least one sensor element so as to transmit the deformation of the deforming body to the sensor element. It is particularly advantageous that the pressure transducer can determine the pressure directly in or at the chemical reactor, whereby the measuring accuracy and the response can be increased considerably. Furthermore, the pressure transducer can be brought into various positions of the chemical reactor, so that a pressure profile within the reactor can be produced.
摘要翻译：本发明涉及一种用于化学反应器的压力传感器，其包括具有至少部分与处理介质直接接触的外表面的可弹性变形的基本上为圆柱形的变形体，以及内表面，至少一个传感器元件在其上传递变形的变形体传递到传感器元件。特别有利的是，压力传感器可以直接在化学反应器中或在化学反应器中确定压力，从而可以显着提高测量精度和响应。此外，压力传感器可以进入化学反应器的各个位置，从而可以产生反应器内的压力分布。

6. 发明申请

WO2005028097A1 LOOP REACTOR WITH VARYING DIAMETER FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：用于烯烃聚合的循环反应器具有变化的直径
公开(公告)号：WO2005028097A1
公开(公告)日：2005-03-31
申请号：PCT/EP2004/010375
申请日：2004-09-16
申请人： BASELL POLYOLEFINE GMBH , MIHAN, Shahram , GSELLA, Wolfgang , KÖLLE, Peter , WULFF-DÖRING, Joachim
发明人： MIHAN, Shahram , GSELLA, Wolfgang , KÖLLE, Peter , WULFF-DÖRING, Joachim
IPC分类号： B01J19/18
CPC分类号： B01J19/1837 , B01J8/007 , B01J2208/00212 , B01J2208/00584 , B01J2219/00094 , B01J2219/00173 , C08F10/02 , C08F210/16 , Y02P20/544 , C08F2/14 , C08F2/01 , C08F210/14
摘要： Process for polymerizing at least one olefinic monomer in a loop reactor at from 20 to 150°C, but below the melting point of the polymer to be formed, and a pressure of from 5 to 100 bar, where the polymer formed is present in a suspension in a liquid or supercritical suspension medium and this suspension is circulated by means of an axial pump, wherein the loop reactor comprises a cyclic reactor tube whose diameter varies by at least 10%, based on the predominant reactor tube diameter, and in which there is at least one widening and narrowing in a region other than that of the axial pump.
摘要翻译：在环管反应器中在20-150℃下聚合至少一种烯属单体，但低于待形成的聚合物的熔点，压力为5-100巴的方法，其中所形成的聚合物存在于悬浮在液体或超临界悬浮介质中，并且该悬浮液通过轴向泵循环，其中环流反应器包括基于主要的反应器管直径，其直径变化至少10％的循环反应器管，其中在那里在轴向泵以外的区域中至少有一个变宽和变窄。

7. 发明申请

WO2004056481A1 MONOCYCLOPENTADIENYL COMPLEXES 审中-公开
标题翻译：单环戊二烯复合物
公开(公告)号：WO2004056481A1
公开(公告)日：2004-07-08
申请号：PCT/EP2003/013748
申请日：2003-12-05
申请人： BASELL POLYOLEFINE GMBH , MIHAN, Shahram , ENDERS, Markus , NIFANT'EV, Ilya , NICOARA, Cristiana
发明人： MIHAN, Shahram , ENDERS, Markus , NIFANT'EV, Ilya , NICOARA, Cristiana
IPC分类号： B01J31/22
CPC分类号： B01J31/1805 , B01J31/181 , B01J31/2295 , B01J2231/122 , B01J2531/46 , B01J2531/56 , B01J2531/62 , B01J2531/64 , B01J2531/66 , C07F17/00 , C08F4/63912 , C08F10/00 , C08F210/16 , C08F2420/01 , C08F210/14 , C08F2500/08 , C08F4/6392
摘要： Monocyclopentadienyl complexes in which the cyclopentadienyl system bears at least one unsubstituted, substituted or fused, 5-membered heteroaromatic ring system bound via a specific bridge, a catalyst system comprising at least one of the monocyclopentadienyl complexes, the use of the catalyst system for the polymerization or copolymerization of olefins and a process for preparing polyolefins by polymerization or copolymerization of olefins in the presence of the catalyst system and polymers obtainable in this way.
摘要翻译：单环戊二烯基络合物，其中环戊二烯基体系具有至少一个通过特定桥结合的未取代的，取代或稠合的5元杂芳族环系统，包含至少一种单环戊二烯基络合物的催化剂体系，使用催化剂体系进行聚合或烯烃的共聚和通过在催化剂体系存在下烯烃的聚合或共聚制备聚烯烃的方法和以这种方式可获得的聚合物。

8. 发明申请

WO2003106523A1 FLEXIBLE PROPYLENE COPOLYMER COMPOSITIONS HAVING A HIGH TRANSPARENCY 审中-公开
标题翻译：具有高透明度的柔性丙烯共聚物组合物
公开(公告)号：WO2003106523A1
公开(公告)日：2003-12-24
申请号：PCT/EP2003/006042
申请日：2003-06-10
申请人： BASELL POLYOLEFINE GMBH , FUCHS, Alexander , MORHARD, Friederike
发明人： FUCHS, Alexander , MORHARD, Friederike
IPC分类号： C08F297/08
CPC分类号： C08F297/083 , C08F4/65912 , C08F4/65916 , C08F10/06 , C08F110/06 , C08F210/06 , C08F297/08 , C08L23/14 , C08L23/142 , C08L23/16 , C08L2205/02 , C08L2205/025 , C08L2308/00 , C08L2314/06 , C08F2/001 , C08F4/65927 , C08L2666/06 , C08F2500/12 , C08F2500/03 , C08F2500/19 , C08F2500/26 , C08F210/16
摘要： The present invention relates to a propylene copolymer composition comprising A) a propylene copolymer containing from 1 to 20% by weight of olefins other than propylene and B) at least one propylene copolymer containing from 5 to 98% by weight of olefins other than propylene, where the propylene copolymer composition is obtainable by means of a two-stage or multistage polymerization using a catalyst system based on metallocene compounds which is used in both stages.
摘要翻译：丙烯共聚物组合物本发明涉及一种丙烯共聚物组合物，其包含A）含有1至20重量％的除丙烯以外的烯烃的丙烯共聚物和B）至少一种含有5-98重量％的除丙烯以外的烯烃的丙烯共聚物，其中丙烯共聚物组合物可通过使用在两个阶段中使用的基于茂金属化合物的催化剂体系的两阶段或多阶段聚合获得。

9. 发明申请

WO2003076367A3 VERFAHREN ZUR OLIGOMERISIERUNG VON OLEFINEN UNTER VERWENDUNG EINES CYCLOALKYLALKYL-SUBSTITUIERTEN TRIAZACYCLOHEXANS 审中-公开
公开(公告)号：WO2003076367A3
公开(公告)日：2003-09-18
申请号：PCT/EP2003/002425
申请日：2003-03-10
申请人： BASELL POLYOLEFINE GMBH , MIHAN, Shahram , MOLNAR, Ferenc , MAAS, Heiko , PRINZ, Martina
发明人： MIHAN, Shahram , MOLNAR, Ferenc , MAAS, Heiko , PRINZ, Martina
IPC分类号： B01J31/18
摘要： Beschrieben wird ein Verfahren zur Oligomerisierung von Olefinen, bei dem man ein Olefin mit einem Katalysatorsystem in Kontakt bringt, das erhältlich ist aus einer Chromquelle, einem Cycloalkylalkyl-substituierten Triazacyclohexan, insbesondere einem 1,3,5-Tris-(cycloalkylalkyl)-1,3,5-triazacyclohexan und einem Aktivator, wie einer Alkylaluminiumverbindung oder einem Alkylalumoxan.

10. 发明申请

WO2011089000A1 PROCESS FOR THE PREPARATION OF ETHYLENE COPOLYMER COMPOSITIONS IN THE PRESENCE OF AN OLIGOMERIZATION CATALYST 审中-公开
标题翻译：在低级催化剂存在下制备乙烯共聚物组合物的方法
公开(公告)号：WO2011089000A1
公开(公告)日：2011-07-28
申请号：PCT/EP2011/000212
申请日：2011-01-20
申请人： BASELL POLYOLEFINE GMBH , SCHUHEN, Katrin , LUKESOVA, Lenka , MIHAN, Shahram
发明人： SCHUHEN, Katrin , LUKESOVA, Lenka , MIHAN, Shahram
IPC分类号： C08F110/02 , C08F210/16
CPC分类号： C08F110/02 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F210/16 , Y02P20/52 , C08F2/02 , C08F2/34 , C08F2500/07 , C08F2500/17 , C08F210/14 , C08F2500/05 , C08F2500/12 , C08F4/61904 , C08F4/7042
摘要： Process for the preparation of an ethylene copolymer composition having a polydispersity index M w /M n of from 3 to 100, comprising a) feeding ethylene to at least one polymerization reactor; b) performing in the at least one polymerization reactor an oligomerization of ethylene in the presence of an oligomerization catalyst component (C) to produce comonomer; c) performing simultaneously in the at least one polymerization reactor polymerization reactions in the presence of catalyst components (A) and (B) producing, respectively, a first and a second polyethylene fraction, wherein the weight average molecular weight M w of the first polyethylene fraction produced by catalyst component (A) is less than the M w of the second polyethylene fraction produced by catalyst component (B) and the comonomer incorporation ability of catalyst component (B) is higher than the comonomer incorporation ability of catalyst component (A); and d) withdrawing the ethylene copolymer composition from the polymerization reactor.
摘要翻译：制备多分散指数Mw / Mn为3至100的乙烯共聚物组合物的方法，包括：a）将乙烯进料至至少一个聚合反应器; b）在所述至少一个聚合反应器中在低聚催化剂组分（C）的存在下进行乙烯的低聚以产生共聚单体; c）在催化剂组分（A）和（B）的存在下在所述至少一个聚合反应器聚合反应中同时进行第一和第二聚乙烯级分的制备，其中第一聚乙烯级分的重均分子量Mw 由催化剂成分（A）制造的催化剂成分（B）的共聚单体引入能力低于催化剂成分（B）生成的第二聚乙烯馏分的Mw，催化剂成分（B）的共聚单体引入能力高于催化剂成分（A）的共聚单体引入能力。和d）从聚合反应器中取出乙烯共聚物组合物。

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