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    • 1. 发明申请
    • POLYCARBONATE BLEND AND METHOD OF PRODUCING THE SAME
    • 聚碳酸酯混合物及其生产方法
    • WO2013154694A1
    • 2013-10-17
    • PCT/US2013/028966
    • 2013-03-05
    • ROHM & HAAS COMPANYNELLIAPPAN, Veera, G.LUNDQUIST, Eric, G.SAINT-GERARD, Yannick
    • NELLIAPPAN, Veera, G.LUNDQUIST, Eric, G.SAINT-GERARD, Yannick
    • C08L69/00C08L33/12
    • C08L69/00C08L33/12C08F220/14C08F2220/1841
    • A blend comprising from 50 to 95 percent by weight polycarbonate; and from 5 to 50 percent by weight modified methyl methacrylate polymer, wherein the modified methyl methacrylate polymer is selected from the group consisting of modified methyl methacrylate homopolymer, modified methyl methacrylate copolymers, and combinations thereof; wherein the modified methyl methacrylate polymer has one or more end groups provided by reaction with one or more chain transfer agents selected from the group consisting of mercapto esters, cycloalkyl and substituted cycloalkyl thiols, hydroxyl thiols, aryl and substituted aryl thiols, and aminoalkyl thiols, wherein the modified methyl methacrylate polymer has a Mw from 5,000 to 100,000 g/mole; and wherein the blend exhibits a pencil hardness equal to or greater than F measured according to ASTM D3363 - 05 is provided. A method for preparing a polycarbonate/modified methyl methacrylate blend is also provided.
    • 包含50至95重量%的聚碳酸酯的共混物; 和5至50重量%的改性甲基丙烯酸甲酯聚合物,其中所述改性甲基丙烯酸甲酯聚合物选自改性甲基丙烯酸甲酯均聚物,改性甲基丙烯酸甲酯共​​聚物及其组合; 其中所述改性甲基丙烯酸甲酯聚合物具有一个或多个端基,其通过与一种或多种选自巯基酯,环烷基和取代的环烷基硫醇,羟基硫醇,芳基和取代的芳基硫醇以及氨基烷基硫醇的链转移剂反应而提供, 其中所述改性的甲基丙烯酸甲酯聚合物具有5,000至100,000g / mol的Mw; 并且其中所述共混物显示根据ASTM D3363-05测量的等于或大于F的铅笔硬度。 还提供了制备聚碳酸酯/改性甲基丙烯酸甲酯共​​混物的方法。
    • 2. 发明申请
    • METHOD FOR MEASURING POLYMER FOAM EXPANSION AND APPARATUS FOR USE THEREIN
    • 用于测量聚合物泡沫膨胀的方法和用于其的装置
    • WO2013095876A1
    • 2013-06-27
    • PCT/US2012/066735
    • 2012-11-28
    • ROHM & HAAS COMPANYSTEWART, Seth, ThomasVAN RHEENEN, Paul, R.
    • STEWART, Seth, ThomasVAN RHEENEN, Paul, R.
    • B29C44/60G01B5/06B29C47/92
    • B29C44/60B29C44/50B29C47/0009B29C47/92B29C2947/92171B29C2947/92314B29C2947/924B29C2947/92666B29C2947/92809B29C2947/92895G01B5/068
    • A method of measuring polymer foam expansion comprising extruding a free foaming polymer formulation which comprises one or more blowing agents; feeding the extruded formulation through a right angle die (12) to produce a formed foam having a foam front at an exit of the die; measuring a thickness of the formed foam (16) at the die nozzle (14), using a laser thickness measuring device comprising a laser (18), a vertical positioner (20) driven by a motor drive (22) wherein the laser is attached to the vertical positioner permitting adjustment of a vertical position of the laser; adjusting a speed of the motor drive so that the laser moves at a vertical displacement rate equal to the vertical displacement rate of the foam front exiting the die; and recording the foam thickness, wherein the thickness of the formed foam is measured every x seconds where x is from 0.05 to 0.15 and the thickness is recorded as a function of time is provided. Also provided is an apparatus for executing the inventive method.
    • 一种测量聚合物泡沫膨胀的方法,包括挤出包含一种或多种发泡剂的游离发泡聚合物制剂; 通过直角模具(12)将挤出的制剂进料,以在模具的出口处产生具有泡沫前端的成形泡沫; 使用包括激光器(18)的激光厚度测量装置,由电机驱动器(22)驱动的垂直定位器(20)测量所述形成的泡沫体(16)在所述模头喷嘴(14)处的厚度, 到垂直定位器,允许调整激光器的垂直位置; 调整电机驱动器的速度,使得激光器以等于离开模具的泡沫前沿的垂直位移速率的垂直位移速率移动; 并记录泡沫厚度,其中形成的泡沫体的厚度每x秒测量,其中x为0.05至0.15,并且提供厚度作为时间的函数。 还提供了一种用于执行本发明的方法的装置。