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    • 6. 发明专利
    • DE2043334B2
    • 1975-06-05
    • DE2043334
    • 1970-09-01
    • MITA INDUSTRIAL CO. LTD., OSAKA (JAPAN)
    • NIHYAKUMEN, KOUZIKOUCHI, TOSHIHIROHIRAKATA, OSAKAYOKOYAMA, TAIZO, OSAKAUEDA, YASUO, KOBEKAMEZAWA, YASUTOKIAIZAWA, TATSUO
    • G03C5/18G03C1/61G03C7/46
    • An improved process for diazo-type multicolor reproduction comprising A. exposing to light an assembly comprising I. AN ORIGINAL COMPRISING OPAQUE IMAGE AREAS AND COMPLEMENTARY NON-IMAGE AREAS WHICH TRANSMIT LIGHT, II. A PHOTOSENSITIVE LAYER CONTAINING AT LEAST ONE PHOTOSENSITIVE DIAZONIUM SALT (C), AN AZO COUPLER (B) AND A SUBSTANTIALLY NON-THERMOVOLATILE ACIDIC SUBSTANCE (D), THE ACIDIC SUBSTANCE (D) BEING PRESENT IN AN AMOUNT OF AT LEAST 5 MOLS PER MOL OF THE DIAZONIUM SALT (C), AND III. A LAYER OF A THERMOVOLATILE OR SUBLIMABLE COUPLER (A) DISPOSED BETWEEN THE ORIGINAL AND THE PHOTOSENSITIVE LAYER IN FACE-TO-FACE CONTACT WITH THE PHOTOSENSITIVE LAYER IN AREAS CORRESPONDING TO ONLY A SELECTED PORTION OF THE TOTAL IMAGE AREAS OF THE ORIGINAL, THE COUPLER (A) HAVING A HIGHER COUPLING RATE UNDER DEVELOPING CONDITIONS THAN THE COUPLER (B), AND A DYESTUFF FORMED FROM THE COUPLER (A) AND THE DIAZONIUM SALT (C), AND A DYESTUFF FORMED FROM THE COUPLER (B) AND THE DIAZONIUM SALT (C) HAVING HUES DIFFERENT FROM ONE ANOTHER, TO FORM LATENT IMAGE AREAS ON THE PHOTOSENSITIVE LAYER CORRESPONDING TO THE IMAGE AREAS OF THE ORIGINAL; B. heating the assembly to thereby transfer the coupler (a) onto the surface of the photosensitive layer, steps (A) and (B) being carried out coincidentally, or in the order of (A) to (B), or (B) to (A); and C. thereafter developing the exposed photosensitive layer whereby a multicolor reproduction is obtained in which image areas of one color correspond with areas where the coupler (a) has coupled with the diazonium salt (c), and in which image areas of another color correspond with the remaining image areas where the coupler (b) has coupled with the diazonium salt (c).