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    • 3. 发明授权
    • Reinforced lead anode for the electrolytic production of zinc from
sulphate solution and process for the preparation thereof
    • 用于从硫酸盐溶液中电解生产锌的强化铅阳极及其制备方法
    • US4437965A
    • 1984-03-20
    • US357195
    • 1982-03-11
    • Noel DreulleAlain Van CeulenClaude Eusebe
    • Noel DreulleAlain Van CeulenClaude Eusebe
    • C25C1/16C25C3/20C25C7/02C25B11/00
    • C25C7/02Y10T156/10
    • The anodes for the electrolytic production of zinc from acid aqueous solutions of sulphate comprise a skin portion formed by conventional anode metal, lead containing from 0.25 to 1.0% silver, and a stiffening reinforcing member of titanium or zirconium. The reduction in thickness of the anodes, which is made possible by the provision of the reinforcing member, results in a substantial saving in the amount of silver-bearing lead which is immobilized, and a substantial reduction in the unit weight of the anodes. The resistance of the lead to anodic corrosion in a sulphuric acid medium is maintained and the resistance to corrosion by passivation of the reinforcing member permits the reinforcing member to be accidentally exposed, without disadvantage. To produce the anodes, the reinforcing members are clad with lead at a temperature of more than 100.degree. by rolling sheets of lead, by casting in a mould or by spraying on molten lead.
    • 用于从酸性硫酸水溶液中电解生产锌的阳极包括由常规阳极金属形成的皮肤部分,含有0.25至1.0%的银的铅和钛或锆的加强增强构件。 通过设置加强构件可使减少阳极的厚度导致固定的含银铅的量显着节省,阳极的单位重量显着降低。 导致在硫酸介质中的阳极腐蚀的电阻被保持,并且通过加强构件的钝化的耐腐蚀性允许增强构件被意外地暴露,而没有缺点。 为了生产阳极,通过在模具中铸造或通过喷涂在熔融铅上,通过轧制铅片,使加强构件在大于100℃的温度下用铅包覆。
    • 4. 发明授权
    • Electrolytic cell for electrolytically preparing a metal in pulverulent
form
    • 用于电解制备粉末状金属的电解槽
    • US4064033A
    • 1977-12-20
    • US566111
    • 1975-04-08
    • Roger DekeisterGilbert LemaireDaniel Marzys
    • Roger DekeisterGilbert LemaireDaniel Marzys
    • C25C1/00C25C5/00C25C5/02C25C7/00C25C7/08
    • C25C5/02C25C7/002
    • A method and apparatus for electrolytically preparing in an electrolytic cell metal, preferably zinc, in pulverulent form from a compound of the metal, for example, zinc oxide, in an aqueous ionized solution, for example potassium hydroxide of a concentration of 100 to 800 g/l, the solution preferably containing 10 to 350 of zinc per liter. The cathode at the bottom of the electrolytic cell comprises a layer of the same pulverulent metal, for example zinc, into which a grid cathode current input is introduced, the cathode current applied being sufficient to prevent the formation of metal in continuous form, preferably between 8 and 18 A/dm.sup.2. The anode is disposed in the cell above the cathode. New solution is injected about the lower periphery of the cell so as to set the solution and pulverulent metal is turbulent suspension. The suspension is drawn off by a pump and allowed to settle in a settling tank the pulverulent metal being removed by a conveyor screw, the solution spilling over into a storage tank and then being pumped back to the cell and reintroduced by the injectors. A plurality of cells may be arranged in a stack or columns, operating sequentially, and utilizing the same settling tank, associated pumps, and other auxiliary equipment.
    • 一种浓度为100〜800g的电解池中的金属离子溶液例如氢氧化钾中的金属化合物例如氧化锌的粉末状电解槽金属,优选为锌电解制备的方法和装置, / l,溶液优选每升含有10至350个锌。 电解池底部的阴极包括一个相同的粉状金属(例如锌)的层,其中引入栅极阴极电流,施加的阴极电流足以防止形成连续形式的金属,优选在 8和18A / dm2。 阳极设置在阴极上方的电池中。 围绕电池的下边缘注入新的溶液,以便设定溶液和粉状金属是湍流悬浮液。 悬浮液由泵抽出并使其沉降在沉淀槽中,粉状金属通过输送螺杆除去,溶液溢出到储存罐中,然后被泵送回单元并由喷射器重新引入。 多个电池可以以堆叠或列布置,顺序地操作,并且利用相同的沉淀池,相关联的泵和其它辅助设备。
    • 6. 发明授权
    • Process of sulfuric acid leaching silicated zinc ores
    • 硫酸浸出硅酸锌矿石的工艺
    • US4070260A
    • 1978-01-24
    • US656966
    • 1976-02-10
    • Noel Dreulle
    • Noel Dreulle
    • C22B19/20C01B33/12C01G9/06C22B20060101C22B3/00C22B3/04C22B19/00C22C3/00C25C1/16C25C1/20
    • C22B19/22Y02P10/234
    • A process of leaching silicated zinc ores with sulfuric acid in which the ore is reacted at elevated temperature with at least a stoichiometric amount of sulfuric acid, treating products of the reaction with a predetermined quantity of hot water, filtering the zinc sulfate solution from precipitated silica, washing with a further predetermined quantity of hot water (the total amount of hot water used being determined so as to obtain the desired concentration of zinc in solution). The zinc is later recovered electrolytically. A 1 to 6N sulfuric acid solution may be used in which case a gelatinous mass is formed upon reaction and then it is evaporated at 100.degree. C of at least 60% of its water content. Alternatively the ore can be malaxated with about 20% stoichiometric excess concentrated sulfuric acid, and filtered at out at elevated temperature.
    • 用硫酸浸提硅酸锌矿石的过程,其中矿石在升高的温度下与至少化学计量的硫酸反应,用预定量的热水处理反应产物,从沉淀二氧化硅中过滤硫酸锌溶液 用进一步预定量的热水洗涤(确定所用热水的总量,以获得溶液中所需的锌浓度)。 锌后来电解回收。 可以使用1至6N的硫酸溶液,在这种情况下,反应时形成凝胶状物质,然后在100℃下蒸发至少60%的水含量。 或者,矿石可以用约20%化学计量过量的浓硫酸进行二次混合,并在高温下过滤。
    • 7. 发明授权
    • Method of electrolytically preparing a metal in pulverulent form
    • 电解制备粉末状金属的方法
    • US4115210A
    • 1978-09-19
    • US804152
    • 1977-06-06
    • Roger DekeisterGilbert LemaireDaniel Marzys
    • Roger DekeisterGilbert LemaireDaniel Marzys
    • C25C5/02C25C7/00C25C5/00
    • C25C5/02C25C7/00
    • A method and apparatus for electrolytically preparing in an electrolytic cell metal, preferably zinc, in pulverulent form from a compound of the metal, for example, zinc oxide, in an aqueous ionized solution, for example potassium hydroxide of a concentration of 100 to 800 g/l, the solution preferably containing 10 to 350 of zinc per liter. The cathode at the bottom of the electrolytic cell comprises a layer of the same pulverulent metal, for example zinc, into which a grid cathode current input is introduced, the cathode current applied being sufficient to prevent the formation of metal in continuous form, preferably between 8 and 18 A/dm.sup.2. The anode is disposed in the cell above the cathode. New solution is injected about the lower periphery of the cell so as to set the solution and pulverulent metal is turbulent suspension. The suspension is drawn off by a pump and allowed to settle in a settling tank the pulverulent metal being removed by a conveyor screw, the solution spilling over into a storage tank and then pump back to the cell and reintroduced by the injectors. A plurality of cells may be arranged in a stack or columns, operating sequentially, and utilizing the same settling tank, associated pumps, and other auxiliary equipment.
    • 一种浓度为100〜800g的电解池中的金属离子溶液例如氢氧化钾中的金属化合物例如氧化锌的粉末状电解槽金属,优选为锌电解制备的方法和装置, / l,溶液优选每升含有10至350个锌。 电解池底部的阴极包括一个相同的粉状金属(例如锌)的层,其中引入栅极阴极电流,施加的阴极电流足以防止形成连续形式的金属,优选在 8和18A / dm2。 阳极设置在阴极上方的电池中。 围绕电池的下边缘注入新的溶液,以便设定溶液和粉状金属是湍流悬浮液。 悬浮液由泵抽出并允许沉淀槽中的粉状金属被输送螺杆除去,溶液溢出到储存罐中,然后泵送回细胞并由喷射器重新引入。 多个电池可以以堆叠或列布置,顺序地操作,并且利用相同的沉淀池,相关联的泵和其它辅助设备。
    • 8. 发明授权
    • Process for reutilization of iron chlorides in aqueous solution
    • 在水溶液中再利用氯化铁的方法
    • US4092401A
    • 1978-05-30
    • US758136
    • 1977-01-10
    • Noel Dreulle
    • Noel Dreulle
    • C01B7/01C01B7/03C01B17/69C01F11/46C01G49/06C01B7/08C01F11/48C01G49/02
    • C01B7/03C01B17/69C01F11/46C01G49/06Y10S423/01
    • Process for the recovery of pigment-grade iron oxide and technical hydrochloric acid of predetermined molarity, from iron chloride solutions such as pickling solutions containing hydrochloric acid. The iron chloride solution is concentrated until the molarity of the chloride ion therein is the same as the molarity of the hydrochloric acid which it is desired to produce. Concentrated sulfuric acid in slight stoichiometric excess relative to the iron, is then added to the iron chloride solution, which solution is thereafter evaporated to dryness. The distillation from this evaporation is hydrochloric acid of the predetermined molarity, and the dry residue is iron sulfate. The iron sulfate is calcined to drive off sulfur dioxide and sulfur trioxide and to leave iron oxide which may contain sulfates; and to remove these latter, the iron oxide is leached with dilute hydrochloric acid and is thereafter washed with water. The washed iron oxide is dried and micropulverized to produce a red iron oxide pigment. The sulfur oxides driven off during calcination may be washed with concentrated sulfuric acid and recycled to the sulfating step, the concentrated sulfuric acid absorbing the sulfur trioxide and letting pass the sulfur dioxide which can if desired be used in the catalytic production of further sulfuric acid. Alternatively, the sulfur oxides can be washed with lime milk to produce calcium sulfite and calcium sulfate, which upon filtration and air drying becomes hydrated calcium sulfate usable as gypsum.
    • 用于回收颜料级氧化铁和工业盐酸的预定摩尔浓度的方法,来自氯化铁溶液,例如含有盐酸的酸洗溶液。 将氯化铁溶液浓缩直到其中的氯离子的摩尔浓度与所希望产生的盐酸的摩尔浓度相同。 然后将相对于铁稍微化学计量过量的浓硫酸加入到氯化铁溶液中,然后将该溶液蒸发至干。 来自该蒸发的蒸馏是预定摩尔浓度的盐酸,干燥残余物是硫酸铁。 硫酸铁被煅烧以除去二氧化硫和三氧化硫,并留下可能含有硫酸盐的氧化铁; 为了除去这些后者,用稀盐酸浸出氧化铁,然后用水洗涤。 将经洗涤的氧化铁干燥并微粉化以产生红色氧化铁颜料。 在煅烧过程中驱除的硫氧化物可以用浓硫酸洗涤并再循环到硫酸化步骤,浓硫酸吸收三氧化硫,并使二氧化硫通过,如果需要,可以将其用于催化生产另外的硫酸。 或者,硫氧化物可以用石灰乳洗涤以产生亚硫酸钙和硫酸钙,其在过滤和空气干燥时变成可用作石膏的水合硫酸钙。
    • 10. 发明专利
    • DE2515714C3
    • 1980-09-04
    • DE2515714
    • 1975-04-10
    • COMPAGNIE ROYALE ASTURIENNE DES MINES, PARIS
    • DEKEISTER, ROGERLEMAIRE, GILBERTMARZYS, DANIEL
    • C25C1/00C25C5/00C25C5/02C25C7/00
    • A method and apparatus for electrolytically preparing in an electrolytic cell metal, preferably zinc, in pulverulent form from a compound of the metal, for example, zinc oxide, in an aqueous ionized solution, for example potassium hydroxide of a concentration of 100 to 800 g/l, the solution preferably containing 10 to 350 of zinc per liter. The cathode at the bottom of the electrolytic cell comprises a layer of the same pulverulent metal, for example zinc, into which a grid cathode current input is introduced, the cathode current applied being sufficient to prevent the formation of metal in continuous form, preferably between 8 and 18 A/dm2. The anode is disposed in the cell above the cathode. New solution is injected about the lower periphery of the cell so as to set the solution and pulverulent metal is turbulent suspension. The suspension is drawn off by a pump and allowed to settle in a settling tank the pulverulent metal being removed by a conveyor screw, the solution spilling over into a storage tank and then being pumped back to the cell and reintroduced by the injectors. A plurality of cells may be arranged in a stack or columns, operating sequentially, and utilizing the same settling tank, associated pumps, and other auxiliary equipment.