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    • 88. 发明专利
    • Improvements in glycidyl ester copolymers
    • GB901941A
    • 1962-07-25
    • GB3954160
    • 1960-11-17
    • DEVOE & RAYNOLDS CO
    • C08F220/32C08F222/20C08G59/14C08G59/32C08G59/36C09D125/14C09D133/12F26B5/00
    • Glycidyl ester copolymer solutions are prepared by polymerizing an unsaturated glycidyl ester and a monoethylenically unsaturated monomer in solution in a monohydric or polyhydric alcohol having a viscosity not exceeding 130 centipoises at the polymerization temperature and which reacts with the copolymer and/or a cross-linking agent for the copolymer under curing conditions. Glycidyl esters specified are the acrylate, methacrylate and crotonate, diglycidyl maleate, fumarate and itaconic acids and glycidyl alkyl esters of the aforementioned dicarboxylic acids. Copolymerizable monomers specified are styrene, vinyl toluene, alpha-alkylstyrenes, alpha- and ar-halostyrenes, esters of vinyl, allyl, methallyl, ethallyl and higher alkenyl alcohols, esters of acrylic, methacrylic, fluoroacrylic, chloroacrylic, bromoacrylic, iodoacrylic, cyanoacrylic, maleic, fumaric and glutaconic acids and amides and nitriles of such acids. Polymerization solvents specified are hexyl, capryl, 2-ethylhexyl, nonyl, lauryl, stearyl, oleyl, linoleyl and linolenyl alcohols, ethylene, propylene, dipropylene, tripropylene, triethylene, tetraethylene, polyoxyethylene and polyoxypropylene glycols, 1,5-pentanediol, glycerin, sorbitol and trimethylol propane. Also present in the solvent may be a mono- or polyepoxide, e.g. styrene oxide, glycidol, phenyl and butyl glycidyl ethers, glycidyl acetate and benzoate and the polyepoxides made by reacting alcohols or phenols with a halohydrin. Polymerization is accelerated by the use of heat and catalysts, e.g. benzoyl, phthalic, acetyl, lauroyl and di-tertbutyl peroxides, cumene and tertbutyl hydroperoxides, aluminium and stannic chlorides and boron trifluoride. The resulting copolymer solutions may be formed into shaped articles without the necessity of removing solvents. This result is achieved by the use of curing agents for epoxide resins, e.g. acids, anhydrides such as phthalic anhydride and methylene endo-cis-bicyclo(2,2,1)-5-heptene-2,3-dicarboxylic anhydride, amines, quaternary ammonium salts, amino-amides, a polyisocyanate and boron trifluoride complexes. Specification 679,536 is referred to.