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81. 发明专利

DE1301102B 未知
公开(公告)号：DE1301102B
公开(公告)日：1969-08-14
申请号：DEF0046473
申请日：1965-06-30
申请人： HOECHST AG
发明人： HAEFNER , KARL-HEINZ DR , MESSWARB , GUENTHER DR , FISCHER , EDGAR DR
IPC分类号： C07D303/22 , C08G2/00 , C08G2/18 , C08G2/26 , C08G1/14

82. 发明专利

DE1259568B 未知
公开(公告)号：DE1259568B
公开(公告)日：1968-01-25
申请号：DEA0048215
申请日：1965-01-22
申请人： ASAHI CHEMICAL IND
发明人： ISHIDA SHINICHI , SAITO SHIZUKO
IPC分类号： C08G2/00 , C08G2/26 , C08G1/18

83. 发明专利

GB1002664A Unsaturated esters and polymers thereof 未知
公开(公告)号：GB1002664A
公开(公告)日：1965-08-25
申请号：GB2912863
申请日：1963-07-23
申请人： ICI LTD
发明人： GIBB ALEXANDER RAMSEY MAUND
IPC分类号： C08G2/00 , C08G2/26 , C08G2/38 , C08G4/00
摘要： Polymers and copolymers of unsaturated esters of formula where R1 is a monovalent radical with at least one carbon-carbon double bond, R2 is as R1, or may additionally be a monovalent aliphatic, cycloaliphatic, arylaliphatic or aromatic hydrocarbon radical, or monovalent heterocyclic radical or a substituted derivative thereof, R3 may be as R2 or additionally R2-O-, hydrogen or a divalent chain forming a cyclic hydrocarbon or heterocyclic ring with the carbon atom, T is an organic radical containing two or more carbon atoms and having a valency of 2Z, the two oxygen atoms being attached to different carbon atoms of T, Z is a positive integer and X is either one or two, and n is an integer greater than 1, specifically polyoxymethylene acetate methacrylate, polydioxolane diacrylate, diacrylate of a dioxolane/trioxane copolymer, pentaerythritol dicrotonate di-(oxymethyl crotonate), and poly-(4-methyldioxolane) dicrotonate are prepared using free radical catalysts such as benzoyl peroxide and azodiisobutyronitrile or U.V. radiation. Copolymers with styrene, methyl methacrylate or vinyl acetate. The esters are prepared (see Division C2) by reacting an unsaturated carboxylic acid anhydride of formula with a cyclic acetal, ketal or cyclic orthoester in presence of acidic or Friedel-Crafts catalyst. Examples describe the preparation of the specific esters above and their polymerization and copolymerization with styrene and vinyl acetate.ALSO:Unsaturated polymerizable esters of formula where R1 is a monovalent radical with at least one carbon-carbon double bond, R2 is as R1 or may additionally be a monovalent aliphatic, cyclo-aliphatic, aryl aliphatic or aromatic hydrocarbon radical, or monovalent, heterocyclic radical or a substituted derivative thereof, R3 may be as R2 or additionally R2-O-, hydrogen or a divalent chain forming a cyclic hydrocarbon or heterocyclic ring with the carbon atom, T is an organic radical containing two or more carbon atoms and having a valency 2Z, the two oxygen atoms being attached to different carbon atoms of T, z is a positive integer and x is either one or two, and n is an integer greater than 1, specifically polyoxymethylene acetate methacrylate, polydioxolane diacylate, diacylate of a dioxolane/trioxane copolymer, pentaerythritol dicrotonate di-(oxymethylcrotonate) and poly-(4-methyl dioxolane) dicrotonate, are prepared by reacting an unsaturated carboxylic acid anhydride with a cyclic acetal, a cyclic ketal, or a cyclic orthoester of formula in the presence of an acidic or Friedel-Crafts catalyst. Anhydrides of acrylic, methacrylic, crotonic and mixed linseed oil fatty acids, and acetyl methacrylate are specified and the cyclic acetal, ketal or ortho-ester may be trioxane, 1,3-dioxolane, 4-methyl-1,3-dioxolane, 4-chloromethyl - 1,3 - dioxolane, 2 - methyl - 1,3 - dioxolane, 2 - ethoxy - 1,3 - dioxolane, 2 - ethyl - 1,3-dioxolane, ethylene glycol cyclohexanone ketal, neopentyl glycol cyclic formal, trimethylolethane monoacetate monoformal, pentaerythritol dichloride monoformal, 1,3,5-trioxepane, 1.3.6,trioxocane, pentaerythritol diformal, trimethylol propane sesquiformal, sorbitol triformal, polyvinyl formal, polyvinyl butyral or mixtures thereof. Catalysts mentioned are perchloric, sulphuric acids, boron trifluoride, boron trifluoride etherate, triethyl oxonium fluoroborate, ferric, stannic or aluminium chloride, a stannic bromide, and a base such as triethylamine or sodium acetate may be used to neutralize them after completion of the reaction. The products may be polymerized with free radical catalysts or by treatment with ultra-violet radiation and copolymerized for example with styrene, methyl methacrylate or vinyl acetate. Examples describe the reaction of acetyl methacrylate with trioxane to yield polyoxymethylene acetate methacrylate; acrylic anhydride and dioxolane to yield a polydioxolane diacrylate; acrylic anhydride and dioxolane/trioxolane; crotonic anhydride and pentaerythritol diformal to yield pentaerythritol dicrotonate di-(oxymethylcrotonate) (CH3CH= CHCO2CH2)2C(CH2OCH2O2C.CH = CH CH3)2; crotonic anhydride and pentaerythritol bis-(acrolein acetal); and crotonic anhydride and 4-methyldioxalane to yield a poly-(4-methyl-dioxolane) dicrotonate.

84. 发明专利

BE650906A 未知
公开(公告)号：BE650906A
公开(公告)日：1965-01-25
申请号：BE650906
申请日：1964-07-23
IPC分类号： C08G2/00 , C08G2/26 , C08G2/38 , C08G4/00
摘要： Polymers and copolymers of unsaturated esters of formula where R1 is a monovalent radical with at least one carbon-carbon double bond, R2 is as R1, or may additionally be a monovalent aliphatic, cycloaliphatic, arylaliphatic or aromatic hydrocarbon radical, or monovalent heterocyclic radical or a substituted derivative thereof, R3 may be as R2 or additionally R2-O-, hydrogen or a divalent chain forming a cyclic hydrocarbon or heterocyclic ring with the carbon atom, T is an organic radical containing two or more carbon atoms and having a valency of 2Z, the two oxygen atoms being attached to different carbon atoms of T, Z is a positive integer and X is either one or two, and n is an integer greater than 1, specifically polyoxymethylene acetate methacrylate, polydioxolane diacrylate, diacrylate of a dioxolane/trioxane copolymer, pentaerythritol dicrotonate di-(oxymethyl crotonate), and poly-(4-methyldioxolane) dicrotonate are prepared using free radical catalysts such as benzoyl peroxide and azodiisobutyronitrile or U.V. radiation. Copolymers with styrene, methyl methacrylate or vinyl acetate. The esters are prepared (see Division C2) by reacting an unsaturated carboxylic acid anhydride of formula with a cyclic acetal, ketal or cyclic orthoester in presence of acidic or Friedel-Crafts catalyst. Examples describe the preparation of the specific esters above and their polymerization and copolymerization with styrene and vinyl acetate.ALSO:Unsaturated polymerizable esters of formula where R1 is a monovalent radical with at least one carbon-carbon double bond, R2 is as R1 or may additionally be a monovalent aliphatic, cyclo-aliphatic, aryl aliphatic or aromatic hydrocarbon radical, or monovalent, heterocyclic radical or a substituted derivative thereof, R3 may be as R2 or additionally R2-O-, hydrogen or a divalent chain forming a cyclic hydrocarbon or heterocyclic ring with the carbon atom, T is an organic radical containing two or more carbon atoms and having a valency 2Z, the two oxygen atoms being attached to different carbon atoms of T, z is a positive integer and x is either one or two, and n is an integer greater than 1, specifically polyoxymethylene acetate methacrylate, polydioxolane diacylate, diacylate of a dioxolane/trioxane copolymer, pentaerythritol dicrotonate di-(oxymethylcrotonate) and poly-(4-methyl dioxolane) dicrotonate, are prepared by reacting an unsaturated carboxylic acid anhydride with a cyclic acetal, a cyclic ketal, or a cyclic orthoester of formula in the presence of an acidic or Friedel-Crafts catalyst. Anhydrides of acrylic, methacrylic, crotonic and mixed linseed oil fatty acids, and acetyl methacrylate are specified and the cyclic acetal, ketal or ortho-ester may be trioxane, 1,3-dioxolane, 4-methyl-1,3-dioxolane, 4-chloromethyl - 1,3 - dioxolane, 2 - methyl - 1,3 - dioxolane, 2 - ethoxy - 1,3 - dioxolane, 2 - ethyl - 1,3-dioxolane, ethylene glycol cyclohexanone ketal, neopentyl glycol cyclic formal, trimethylolethane monoacetate monoformal, pentaerythritol dichloride monoformal, 1,3,5-trioxepane, 1.3.6,trioxocane, pentaerythritol diformal, trimethylol propane sesquiformal, sorbitol triformal, polyvinyl formal, polyvinyl butyral or mixtures thereof. Catalysts mentioned are perchloric, sulphuric acids, boron trifluoride, boron trifluoride etherate, triethyl oxonium fluoroborate, ferric, stannic or aluminium chloride, a stannic bromide, and a base such as triethylamine or sodium acetate may be used to neutralize them after completion of the reaction. The products may be polymerized with free radical catalysts or by treatment with ultra-violet radiation and copolymerized for example with styrene, methyl methacrylate or vinyl acetate. Examples describe the reaction of acetyl methacrylate with trioxane to yield polyoxymethylene acetate methacrylate; acrylic anhydride and dioxolane to yield a polydioxolane diacrylate; acrylic anhydride and dioxolane/trioxolane; crotonic anhydride and pentaerythritol diformal to yield pentaerythritol dicrotonate di-(oxymethylcrotonate) (CH3CH= CHCO2CH2)2C(CH2OCH2O2C.CH = CH CH3)2; crotonic anhydride and pentaerythritol bis-(acrolein acetal); and crotonic anhydride and 4-methyldioxalane to yield a poly-(4-methyl-dioxolane) dicrotonate.

85. 发明专利

DE602007005031D1 未知
公开(公告)号：DE602007005031D1
公开(公告)日：2010-04-15
申请号：DE602007005031
申请日：2007-01-19
申请人： ROHM & HAAS
发明人： BRINKMAN FRANK LARRY , KAUFFMAN THOMAS FREDERICK
IPC分类号： C08F222/10 , C07C69/72 , C08F265/04 , C08G2/26 , C08G16/06 , C08K9/10 , C08L61/00 , C09D135/00 , C09D201/06
摘要： Encapsulated base catalysts in the presence of Michael donors and acceptors result in compositions useful as adhesives, sealants, coatings, elastomers, films, and foams by providing unprecedented control over pot-life and cure rate in a two-part or multi-component system and allowing for use as a one-part composition. Encapsulated catalysts prevent premature reaction of the various reactants during storage and processing and yet, upon the rupture of the capsules by a pre-determined event such as the application of heat, pressure, or solvation, produce rapid cure. Use of encapsulated catalysts gives unprecedented control over pot-life and cure rate over compositions previously contemplated. As such the use of encapsulated catalysts also results in the potential for one-part Michael addition compositions previously not known. The use of encapsulated catalysts also allows for faster green strength development by providing for a very rapid cure upon rupture of the capsules.

86. 发明专利

MX2007000747A CATALIZADOR ENCAPSULADO DE ADICION DE MICHAEL. 未知
公开(公告)号：MX2007000747A
公开(公告)日：2008-10-29
申请号：MX2007000747
申请日：2007-01-19
申请人： ROHM & HAAS
发明人： BRINKMAN LARRY FRANK , KAUFFMAN THOMAS FREDERICK
IPC分类号： C08F222/10 , B32B27/00 , C08F265/04 , C07C69/72 , C08G2/26 , C08G16/06 , C08K9/10 , C08L61/00 , C09D135/00 , C09D201/06
摘要： Catalizadores básicos encapsulados en la presencia de donadores y aceptadores de Michael, producen composiciones útiles como adhesivos, selladores, recubrimientos, elastómeros, películas y espumas, por la provisión de un control sin precedentes de la vida en pote y la velocidad de curación en un sistema de dos partes o multicomponente, y permitiendo el uso como una composición de una parte. Los catalizadores encapsulados previenen la reacción prematura de los varios reactivos durante el almacenamiento y el proceso y aún en la ruptura de las cápsulas por un evento predeterminado, tal como la aplicación de calor, presión o solvación, producen una curación rápida. El uso de los catalizadores encapsulados suministra un control sin precedentes sobre la vida en pote y la velocidad de curación en las composiciones previamente consideradas. Como tal, el uso de los catalizadores encapsulados también resulta en el potencial de as composiciones de adición de Michael previamente no conocido. El uso de, 'estos catalizadores encapsulados también permite el desarrollo más rápido de la resistencia en estado sin tratar, por la provisión de una curación muy rápida en la ruptura de las cápsulas.

87. 发明专利

AT122070T 未知
公开(公告)号：AT122070T
公开(公告)日：1995-05-15
申请号：AT90200120
申请日：1990-01-16
申请人： SHELL INT RESEARCH
发明人： VAN LEEUWEN PETRUS WILHELMUS N , ROOBEEK CORNELIS FRANCISCUS
IPC分类号： C08G2/26 , B01J31/18 , B01J31/24 , C08F4/80 , C08G67/02
摘要： Catalyst compositions which are based upon a) a Group VIII metal, b) a diphosphine R R P-R-PR R , and c) 0.25 to 2 mol per mol of Group VIII metal of a monophosphine R R R P or of a monophosphine oxide of the general formula R R HPO, wherein R , R , R , R , R and R are identical or different optionally polar-substituted hydrocarbon groups, R is hydrogen or an optionally polar-substituted hydrocarbyl group, and R is a bridging group having at least two carbon atoms in the bridge, are suitable for the copolymerization of carbon monoxide with one or more olefinically unsaturated compounds.

88. 发明专利

HU210265B PROCESS FOR PRODUCING OF VINIL CHLORIDE POLYMERS MODIFIED WITH LACTONE POLYMERS 未知
公开(公告)号：HU210265B
公开(公告)日：1995-03-28
申请号：HU140990
申请日：1990-03-12
申请人： SOLVAY
发明人： MALFROID PIERRE , NGUYEN QUI LONG , BLONDIN JEAN-MARIE , DEWAELE NICOLE , BURNAY JEAN-PAUL
IPC分类号： C08F14/06 , C08F2/44 , C08F14/00 , C08F283/00 , C08F283/02 , C08G63/08 , C08G63/68 , C08G63/682 , C08G63/82 , C08G63/91 , C08G2/26 , C08G2/30 , C08G8/28 , C08G81/02 , C08F216/36
摘要： In a first stage, a lactone is polymerized by an ionic route in vinyl chloride with the aid of a catalyst consisting of the product, optionally complexed with tetrahydrofuran, of the reaction of an alkylmetal with ethylenically unsaturated alcohol, optionally in the presence of water and, in a second stage, the said vinyl chloride is polymerized by a radical route in an aqueous suspension and in the presence of the polymerization medium originating from the first stage, to which other unsaturated monomers are optionally added. The invention also relates to new modified vinyl chloride polymers consisting of lactone polymers whose number-average molecular weight is less than 5,000, grafted with vinyl chloride polymers.

89. 发明专利

CA2143745A1 BLOCK COPOLYACETALS, PROCESS FOR PRODUCING THE SAME AND THEIR USE IN WASHING AND CLEANING AGENTS 未知
公开(公告)号：CA2143745A1
公开(公告)日：1994-05-11
申请号：CA2143745
申请日：1993-10-29
申请人： BASF AG
发明人： KRONER MATTHIAS , SCHORNICK GUNNAR , BAUR RICHARD , SCHWENDEMANN VOLKER , HARTMANN HEINRICH
IPC分类号： C08G65/34 , C08G81/00 , C08G81/02 , C08J3/24 , C09K23/52 , C11D3/37 , C08G2/26
摘要： There are described block copolyacetals obtainable by cationically initiated polyaddition of (A) polyacetals containing acetaldehyde acetal units and having at least 2 OH groups in the molecule and (B) polyacetals containing acetaldehyde acetal units and having at least 2 vinyl ether groups in the molecule. in a molar ratio of (A):(B) of from 2:1 to 1:2, processes for preparing the block copolyacetals by cationically initiated polyaddition of (A) and (B), and the use of the block polyacetals as additament to reduced-phosphate and phosphate-free detergents and cleaners and as low-foam surfactants in dishwashing compositions.

90. 发明专利

BR9002216A 未知
公开(公告)号：BR9002216A
公开(公告)日：1991-08-13
申请号：BR9002216
申请日：1990-05-11
申请人： HOECHST CELANESE CORP
发明人： BROUSSARD JERRY A , AUERBACH ANDREW B , PAUL JAMES L
IPC分类号： C08G65/16 , C08G2/00 , C08G2/24 , C08G2/26 , C08F297/00
摘要： Cationic copolymerization of trioxane and 1,2,6-hexanetriol formal (HTF) or its ester derivatives yields acetal copolymers having pendant functional groups. The HTF formal or ester derivatives of HTF may therefore include functional groups selected from hydroxyl or ester moieties which are protected, and thus survive, the copolymerization with trioxane. These groups may then be present as functional reactive sites for the subsequent synthesis of block copolymers and/or to chemically bind modifiers to the acetal copolymer backbone, for example.

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