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    • 85. 发明授权
    • Potassium monopersulfate triple salt with increased active oxygen content and substantially no K2S2O8
    • 单过硫酸钾三盐与活性氧含量增加,基本上没有K2S2O8
    • US07090820B2
    • 2006-08-15
    • US10878169
    • 2004-06-28
    • Perry L. Martin
    • Perry L. Martin
    • C01B15/08C01B15/06
    • C01B15/08
    • A method of preparing a potassium monopersulfate composition is presented, wherein the potassium monopersulfate composition has the formula (KHSO5)x(KHSO4)y(K2SO4)z, where x+y+z=1 and x=0.46–0.64, y=0.15–0.37, and z=0.15–0.37, said potassium monopersulfate composition having an active oxygen content greater than or equal to 4.9 wt. % and K2S2O8 at a concentration of
    • 提出了制备单过硫酸钾组合物的方法,其中单过硫酸钾组合物具有式(KHSO 5)x(KHSO 4) 其中x + y + z = 1,x = 0.46-0.64(K 2)其中x + y + z = 1和x = 0.46-0.64 ,y = 0.15-0.37,z = 0.15-0.37,所述单过硫酸钾组合物具有大于或等于4.9重量%的活性氧含量。 %和K 2 S 2 O 8,其浓度<0.5wt。 %的单过硫酸钾组成。 该方法包括使含有至少70重量%的H 2 O 2 O 2 %H 2 O 2 O 2与H 2 SO 4·S溶液以H 2 O 2的亚化学计量比 从而产生弱的Caro酸溶液,然后将弱的Caro酸溶液与发烟硫酸结合 以产生丰富的Caro酸溶液。 丰富的Caro酸溶液可与碱钾化合物组合以产生单过硫酸钾组合物。 在此过程中,温度保持在30°C以下
    • 86. 发明授权
    • Peroxoacid manufacture
    • 过氧酸制造
    • US5304360A
    • 1994-04-19
    • US769803
    • 1991-10-02
    • John R. G. LaneColin F. McDonoghStephen E. Woods
    • John R. G. LaneColin F. McDonoghStephen E. Woods
    • B01J14/00B01J19/24C01B15/06C01B17/98C01B17/48
    • B01J19/2415C01B15/06B01J2219/00094B01J2219/00164
    • Conventional plant to produce peroxomonosulphuric acid (Caro's acid) is large and emphasises extensive cooling, so that it is awkward to transport, can be cumbersome to install beside existing plant and can suffer from relatively expensive capital and/or running costs.In the present invention, Caro's acid is generated continuously in relatively small plant adiabatically, by introducing concentrated hydrogen peroxide into a stream of concentrated sulphuric acid in a reaction chamber dimensioned so that the throughput is very fast. In particularly suitable embodiments, the reaction chamber is annular at the points of introduction of the reagents, its width being greater in the vicinity of the hydrogen peroxide inlet than in the vicinity of the sulphuric acid inlet. The hydrogen peroxide inlet is preferably angled backwardly so that its encounter angle with the sulphuric acid stream is over 90.degree. to about 165.degree..
    • 生产过氧硫酸(Caro's acid)的传统工厂很大,并且强调大量的冷却,因此运输是尴尬的,安装在现有工厂旁边可能很麻烦,并且可能遭受相对昂贵的资金和/或运行成本。 在本发明中,通过将浓缩的过氧化氢引入反应室中的浓硫酸流中,绝热地在相对较小的植物中连续生成Caro酸,其尺寸使得生产量非常快。 在特别合适的实施方案中,反应室在试剂引入点处是环形的,其宽度在过氧化氢入口附近比在硫酸入口附近更大。 过氧化氢入口优选地向后倾斜,使得其与硫酸流的碰撞角超过90度至约165度。
    • 90. 发明授权
    • Potassium monopersulfate compositions and process for preparing them
    • 单过硫酸钾组合物及其制备方法
    • US4579725A
    • 1986-04-01
    • US771490
    • 1985-09-04
    • Madhusudan D. Jayawant
    • Madhusudan D. Jayawant
    • C01B15/08C01B15/06
    • C01B15/08
    • A storage stable salt melting at 80.degree. to 150.degree. C. having the formula (KHSO.sub.5).sub.x (KHSO.sub.4).sub.y (K.sub.2 SO.sub.4).sub.z where x+y+z=1, and x=0.4-0.97, preferably 0.60-0.85; y=0.03-0.60, preferably 0.15-0.40; z=0-0.10, preferably 0-0.3; and y is .gtoreq.z, which is treated with 1.0-9.0% of a basic magnesium compound which is MgCO.sub.3, Mg(OH).sub.2, MgO or mixtures thereof is disclosed. The salt is prepared by neutralizing Caro's acid with a basic potassium compound to form a reaction mixture. Water is evaporated from the reaction mixture at 15.degree. to 35.degree. C. using a vacuum of 2-15 mm Hg absolute pressure to form up to 40 wt. % crystals. The crystals are separated, treated with a basic magnesium compound, dried, and further treated with a basic magnesium compound.
    • 具有式(KHSO 5)x(KHSO 4)y(K 2 SO 4)z,其中x + y + z = 1,x = 0.4-0.97,优选0.60-0.85的在80-150℃下的储存稳定的盐。 y = 0.03-0.60,优选为0.15-0.40; z = 0-0.10,优选0-0.3; 并且y是> = = z,其用1.0-9.0%的MgCO3,Mg(OH)2,MgO或其混合物的碱性镁化合物处理。 盐通过用碱性钾化合物中和Caro酸形成反应混合物来制备。 使用2-15mmHg绝对压力的真空将反应混合物中的水在15至35℃下蒸发,形成至多40wt。 %晶体。 分离晶体,用碱性镁化合物处理,干燥,并用碱性镁化合物进一步处理。