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    • 86. 发明授权
    • Process for the preparation of violet dyestuffs of the triphenylmethane
series
    • 制备三苯甲烷系列紫色染料的方法
    • US4062877A
    • 1977-12-13
    • US730207
    • 1976-10-06
    • Manfred HahnkeTheodor Papenfuhs
    • Manfred HahnkeTheodor Papenfuhs
    • C09B11/00C09B11/20C09B11/10
    • C09B11/20
    • A novel process had been found for preparing novel violet dyestuffs of the triphenylmethane series which is characterized by that an aluminum chloride or borotrifluoride or iron-III-chloride-complex compound of a 4,4',4"-trihalogenotriphenylmethylhalide is reacted with phenyl- or naphthylamine which are substituted in the m- or p-position in a molar ratio of 1 to 1.5 at 110.degree. to 135.degree. C and in an inert organic solvent, and the mono-phenyl or -naphthylamino- substituted halide formed is reacted with 5 - 20 mols of an ortho-substituted phenyl- or naphthylamine at 150.degree. to 190.degree. C. The dyestuffs so prepared are well suitable for printing paper and plastics and dyeing polyacrylonitrile fibers.
    • 已经发现了一种制备三苯甲烷系列的新型紫色染料的新方法,其特征在于使4,4',4“ - 三卤代三苯甲基卤化物的氯化铝或三氟化硼或三氯化铁络合物与苯基 - 或萘胺在110〜135℃的摩尔比为1〜1.5,在惰性有机溶剂中在m-或p-位上取代,形成的单苯基或 - 萘基氨基取代的卤化物反应 在150至190℃下加入5-20摩尔邻位取代的苯基或萘胺。如此制备的染料非常适合印刷纸张和塑料以及染色聚丙烯腈纤维。
    • 87. 发明授权
    • Process for the preparation of symmetric
4-halogen-4',4
    • 对称4-卤素-4 {40,4 {41-二芳基氨基 - 三苯基甲烷化合物的制备方法
    • US4041054A
    • 1977-08-09
    • US587413
    • 1975-06-17
    • Manfred HahnkeTheodor Papenfuhs
    • Manfred HahnkeTheodor Papenfuhs
    • C09B11/00C09B11/20C09B11/10
    • C09B11/20
    • An improved process for the preparation of symmetric 4-halogeno-4',4"-diarylamino-triphenyl-methane compounds by reacting a complex compound of a 4,4',4"-trihalogeno-triphenyl-methyl-halide and aliminiumchloride, iron(III)chloride or bortrifluoride with an aromatic amine, which is substituted in m- or p-position to the amino group, at an elevated temperature had been found wherein 1 mol of the complex compound is reacted with more than 4 mol of the aromatic amine and the so obtained complex compound from 4-halogen-4',4"-diarylamino-triphenyl-methyl-halide and aluminiumchloride, iron(III)chloride or bortrifluoride is subsequently converted into the anhydro- or carbinol base of the dyestuff with the aid of an aqueous alkali metal hydroxide solution whereupon the salt of the dyestuff is precipitated by addition of an acid in excess.This novel process obviates the formation of red mono- and blue tri-reaction products, the use of solvents and leads to very clean products which are very well suitable for spin-dyeing solutions.
    • 通过使4,4',4“ - 三卤代 - 三苯甲基 - 卤化物和氯化铝的配合物反应制备对称4-卤代-4',4” - 二芳基氨基 - 三苯基 - 甲烷化合物的改进方法 已经发现,在升高的温度下,已经发现在升高的温度下,与氨基取代m或对位的芳族胺的氯化铁(III)或三氟化硼,其中1摩尔的络合物与大于4摩尔 芳香胺和由此得到的4-卤素-4',4“ - 二芳基氨基 - 三苯甲基卤化物和氯化铝,氯化铁(III)或三氟化硼的络合物随后转化为 借助于碱金属氢氧化物水溶液的染料,然后通过加入过量的酸沉淀染料的盐。