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    • 88. 发明公开
    • Solvent cast acrylic film
    • 溶剂浇铸丙烯酸膜
    • EP0154108A3
    • 1988-03-09
    • EP84870159
    • 1984-11-27
    • VCF Packaging Films Inc.
    • Knoop, Henry E.
    • C08J05/18B29C39/14B29C41/24C08L33/08C08L33/10C08L51/00B29K33/00
    • C08J5/18C08J2333/06Y10S525/902Y10S525/937Y10T428/31855
    • Acrylic films having superior properties are produced by casting a solution comprising an organic solvent and a polymer system of one or more completely polymerized acryllc polymers onto a carrier, removing the solvent thereby forming the film on the carrier, and stripping the film from the carrier. The polymer system comprises at least one polymer prepared by polymerizing monomers of the general formula (i):
      wherein: R, is hydrogen or methyl; and R 2 is striaght or branched alkyl of about 1-20 carbon atoms, preferably about 1-8 carbon atoms, more preferably 1-4 carbon atoms, and most preferably 1-2 carbon atoms. The polymers are homopolymers, mixed copolymers, and graft copolymers. They may be cross-linked. The polymers have the following properties:
      Total Elongation (%) of about 120-250, preferably about 150-210, and more preferably about 170-190; Tear Resistance of about 4.5-12.5 g/mil (which is about 177-492 mg/micron), preferably 6-10 g/mil (which is about 236-394 mg/micron), and more preferably about 8-9 g/mil (which is about 315-354 mg/micron); Tensile Strength of about 4500-5000 Ibs/in 2 (about 317-387 kg/cm 2 ), preferably about 4800-5200 Ibsi/n 2 (about 338-366 kg/cm 2 ), and more preferably about 4900-5100 Ibs/in 2 (about 345-359 kg/cm 2 ). Molecular Weight (amu) of about 250,000-500,000, preferably about 300,000-400,000, and more preferably about 325,000-375,000; Acid Content (%) of about 0.0-5.0, preferably about 0.0-2.0, and more preferably about 0.0-0.9; Tucon hardness (Knoop No.) of about 6-12, preferably of about 7-11, and more preferably of about 8-10; and The polymer is substantially free of reactive groups, such as hydroxy groups. The acrylic film has Total Elongation, Tensile Strength, Tear Resistance, Acid Content and Tucon hardness in the aforesaid ranges, and is substantially free of reactive groups, such as hydroxy groups. The residual solvent in the film is (weight %) about 0-3, preferably about 0-2, and more preferably about 0.1-1.0. The film has dimensional stability (% shrinkage at about 130°C. for films of 0.5-5.0 mils, which is about 13-127 microns) of about 0-3, preferably of about 0-2, and more preferably of about 0.1-1.0. The thickness of the films is generally about 0.5-5.0 mils (which is about 13-127 microns), preferably about 0.75-3.0 mils (about 19-76 microns), and more preferably about 1.0-2.5 mils (which is about 25-63 microns). The films have excellent flexibility and extensibility. They are completely free of pinholes, gels and imperfections. The films have excellent weatherability.
    • 通过将包含有机溶剂和一种或多种完全聚合的丙烯酸聚合物的聚合物体系的溶液流延到载体上,除去溶剂从而在载体上形成膜,并从载体上剥离膜来制备具有优异性能的丙烯酸膜。 聚合物体系包含至少一种通过聚合通式(ⅰ)的单体制备的聚合物:其中:R 1是氢或甲基; R2是约1-20个碳原子,优选约1-8个碳原子,更优选1-4个碳原子,最优选1-2个碳原子的直链或支链烷基。 该聚合物是均聚物,混合共聚物和接枝共聚物。 它们可能是交联的。 该聚合物具有以下性质:总伸长率(%)约为120-250,优选约150-210,更优选约170-190; 约4.5-12.5克/密耳(约177-492毫克/微米),优选6-10克/密耳(约236-394毫克/微米),更优选约8-9克/密耳的抗撕裂性, mil(约315-354mg /微米); 约4500-5000磅/英寸2(约317-387千克/厘米2),优选约4800-5200磅/英寸2(约338-366千克/厘米2)的拉伸强度,更优选约4900-5100磅/英寸2 345-359公斤/厘米2)。 分子量(amu)约250,000-500,000,优选约300,000-400,000,更优选约325,000-375,000; 约0.0-5.0,优选约0.0-2.0,更优选约0.0-0.9的酸含量(%); 约6-12,优选约7-11,更优选约8-10的Tucon硬度(努普号); 并且聚合物基本上不含反应性基团,例如羟基。 该丙烯酸膜在上述范围内具有总伸长率,抗拉强度,耐撕裂性,酸含量和Tucon硬度,并且基本上不含反应性基团,例如羟基。 膜中的残留溶剂为(重量%)约0-3,优选约0-2,更优选约0.1-1.0。 该膜具有约0-3,优选约0-2,更优选约0.1-1.5的尺寸稳定性(在约130℃下的收缩率对于0.5-5.0密耳,约13-127微米的膜) 1.0。 薄膜的厚度通常为约0.5-5.0密耳(约13-127微米),优选约0.75-3.0密耳(约19-76微米),更优选约1.0-2.5密耳(约25- 63微米)。 这些薄膜具有出色的灵活性和可扩展性。 它们完全没有针孔,凝胶和缺陷。 这些薄膜具有优异的耐候性。