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    • 87. 发明授权
    • Multi-branched mannich base corrosion inhibitor and preparation method thereof
    • 多分支甘露糖基腐蚀抑制剂及其制备方法
    • US09493399B2
    • 2016-11-15
    • US14234854
    • 2012-04-27
    • Ling MaLei LiXiangjun KongMalike DilibaiXinping ZhenChunge NiuShengjun Bai
    • Ling MaLei LiXiangjun KongMalike DilibaiXinping ZhenChunge NiuShengjun Bai
    • C07C225/06C10G75/02C23F11/14C07C221/00C07C225/10C07C225/12C07C225/16
    • C07C225/06C07C221/00C07C225/10C07C225/12C07C225/16C10G75/02C23F11/141
    • The present invention relates to a multi-branched Mannich base corrosion inhibitor and the method for preparing thereof. The method comprises (1) adding 3˜7 moles ketone and 3˜7 moles aldehyde to reaction kettle, adjusting pH to 2˜6 with acid, controlling temperature to 20˜50° C. and stirring for 20˜30 mins; (2) adding 1 mole organic polyamine to the reaction kettle under stirring, or adding the pH-adjusted ketone, aldehyde and organic solvent to organic polyamine, controlling temperature to 60˜90° C. and reacting for 1˜3 hrs, and after completion of the reaction, heating the system to 110° C. under nitrogen to remove water; the organic polyamine is organic compound comprising three or more primary amine groups and/or secondary amine groups. The Mannich base corrosion inhibitor of the present invention shows characters of strong adsorption force, high film strength, high film compactness, increase in corrosion inhibition efficiency by at least 2%, and overcomes the disadvantages in prior art of few adsorption centers, single adsorption group and weak adsorption force to metal surfaces.
    • 本发明涉及多支化曼尼希碱缓蚀剂及其制备方法。 该方法包括:(1)向反应釜中加入3〜7摩尔酮和3〜7摩尔醛,用酸调节pH至2〜6,控制温度为20〜50℃,搅拌20〜30分钟; (2)在搅拌下向反应釜中加入1摩尔有机多胺,或将pH调节的酮,醛和有机溶剂加入到有机多胺中,控制温度为60〜90℃,反应1〜3小时后 反应完成,在氮气下将体系加热至110℃以除去水; 有机多胺是包含三个或更多个伯胺基和/或仲胺基团的有机化合物。 本发明的曼尼希碱防腐蚀剂具有吸附力强,膜强度高,膜致密性高,腐蚀抑制效率提高至少2%的特征,克服了少量吸附中心现有技术的缺点,单吸附组 对金属表面的吸附力弱。
    • 90. 发明申请
    • A MULTI-BRANCHED MANNICH BASE CORROSION INHIBITOR AND PREPARATION METHOD THEREOF
    • 多分支曼氏碱腐蚀抑制剂及其制备方法
    • US20140296575A1
    • 2014-10-02
    • US14234854
    • 2012-04-27
    • Ling MaLei LiXiangjun KongMalike DilibaiXinping ZhenChunge NiuShengjun Bai
    • Ling MaLei LiXiangjun KongMalike DilibaiXinping ZhenChunge NiuShengjun Bai
    • C07C225/06C07C225/10C07C221/00C07C225/12C07C225/16
    • C07C225/06C07C221/00C07C225/10C07C225/12C07C225/16C10G75/02C23F11/141
    • The present invention relates to a multi-branched Mannich base corrosion inhibitor and the method for preparing thereof. The method comprises (1) adding 3˜7 moles ketone and 3˜7 moles aldehyde to reaction kettle, adjusting pH to 2˜6 with acid, controlling temperature to 20˜50° C. and stirring for 20˜30 mins; (2) adding 1 mole organic polyamine to the reaction kettle under stirring, or adding the pH-adjusted ketone, aldehyde and organic solvent to organic polyamine, controlling temperature to 60˜90° C. and reacting for 1˜3 hrs, and after completion of the reaction, heating the system to 110° C. under nitrogen to remove water; the organic polyamine is organic compound comprising three or more primary amine groups and/or secondary amine groups. The Mannich base corrosion inhibitor of the present invention shows characters of strong adsorption force, high film strength, high film compactness, increase in corrosion inhibition efficiency by at least 2%, and overcomes the disadvantages in prior art of few adsorption centers, single adsorption group and weak adsorption force to metal surfaces.
    • 本发明涉及多支化曼尼希碱缓蚀剂及其制备方法。 该方法包括:(1)向反应釜中加入3〜7摩尔酮和3〜7摩尔醛,用酸调节pH至2〜6,控制温度为20〜50℃,搅拌20〜30分钟; (2)在搅拌下向反应釜中加入1摩尔有机多胺,或将pH调节的酮,醛和有机溶剂加入到有机多胺中,控制温度为60〜90℃,反应1〜3小时后 反应完成,在氮气下将体系加热至110℃以除去水; 有机多胺是包含三个或更多个伯胺基和/或仲胺基团的有机化合物。 本发明的曼尼希碱防腐蚀剂具有吸附力强,膜强度高,膜致密性高,腐蚀抑制效率提高至少2%的特征,克服了少量吸附中心现有技术的缺点,单吸附组 对金属表面的吸附力弱。