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81. 发明申请

US20150333371A1 LITHIUM TITANATE OXIDE AS NEGATIVE ELECTRODE IN LI-ION CELLS 审中-公开
标题翻译：钛酸锂作为阴离子电极中的阴极电极
公开(公告)号：US20150333371A1
公开(公告)日：2015-11-19
申请号：US14710753
申请日：2015-05-13
申请人： SAFT GROUPE SA
发明人： Yee Yvonne CHEN , Thomas GRESZLER , Bridget DEVENEY
IPC分类号： H01M10/0567 , H01M10/058 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M4/131
CPC分类号： H01M4/485 , H01M4/0447 , H01M4/131 , H01M4/1391 , H01M4/366 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0567 , H01M10/058 , H01M2004/027 , H01M2004/028 , H01M2300/0025 , Y10T29/4911
摘要： A lithium-ion battery including a negative electrode (anode) containing lithium titanate oxide (Li4Ti5O12) (LTO) as an active material and a stable interface layer disposed on a surface of the electrode; a positive electrode (cathode); an electrolyte containing a solvent and an impedance growth reducing additive; and a separator disposed between the electrodes. The LTO-based cell with the stable interface layer on the negative electrode is formed by holding the potential of the negative electrode below the reduction potential of the impedance growth reducing additive for a sufficient length of time during a first formation cycle. The stable interface layer on the negative electrode mitigates impedance growth on the positive electrode over cycle life. When the impedance growth reducing additive is fluoroethylene carbonate (C3H3FO3), the stable interface layer includes a LiF deposit.
摘要翻译：一种锂离子电池，包括含有钛酸锂（Li4Ti5O12）（LTO）作为活性物质的负极（阳极）和设置在电极表面上的稳定的界面层; 正极（阴极）; 含有溶剂和阻抗增长减少添加剂的电解质; 以及设置在电极之间的隔膜。通过在第一次形成循环期间将负极的电位保持在阻抗增长还原添加剂的还原电位足够长的时间内，形成具有稳定的界面层的基于LTO的电池。负极上的稳定界面层减缓了循环寿命期间正极上的阻抗增长。当阻抗增长减少添加剂是氟代亚乙基碳酸酯（C 3 H 3 FO 3）时，稳定界面层包括LiF沉积物。

82. 发明授权

US09183994B2 Lithium ion capacitors and methods of production 有权
标题翻译：锂离子电容器及其生产方法
公开(公告)号：US09183994B2
公开(公告)日：2015-11-10
申请号：US13687161
申请日：2012-11-28
申请人： Kishor Purushottam Gadkaree , Xiaorong Liu
发明人： Kishor Purushottam Gadkaree , Xiaorong Liu
IPC分类号： H01G11/62 , H01G11/32 , H01G11/06 , H01G11/50 , H01M4/38 , H01M10/0566 , H01M10/0568 , H01M12/00 , H01M4/04 , H01M4/1395 , H01M4/36 , H01M10/052
CPC分类号： H01G11/06 , H01G11/32 , H01G11/34 , H01G11/50 , H01G11/62 , H01G11/84 , H01M4/0447 , H01M4/1395 , H01M4/366 , H01M4/382 , H01M10/052 , H01M10/0566 , H01M10/0568 , H01M12/005 , Y02E60/13 , Y10T29/417
摘要： A lithium-ion capacitor may include a cathode, an anode, a separator disposed between the cathode and the anode, a lithium composite material, and an electrolyte solution. The cathode and anode may be non-porous. The lithium composite material comprises a core of lithium metal and a coating of a complex lithium salt that encapsulates the core. In use, the complex lithium salt may dissolve into and constitute a portion of the electrolyte solution.
摘要翻译：锂离子电容器可以包括阴极，阳极，设置在阴极和阳极之间的隔膜，锂复合材料和电解质溶液。阴极和阳极可以是无孔的。锂复合材料包括锂金属的芯和封装芯的复合锂盐的涂层。在使用中，复合锂盐可以溶解并构成电解质溶液的一部分。

83. 发明申请

US20150263387A1 SECONDARY BATTERY AND METHOD FOR CHARGING AND DISCHARGING SECONDARY BATTERY 有权
标题翻译：用于充电和放电二次电池的二次电池和方法
公开(公告)号：US20150263387A1
公开(公告)日：2015-09-17
申请号：US14707384
申请日：2015-05-08
申请人： Murata Manufacturing Co., Ltd. , Carlit Holdings Co., Ltd.
发明人： Tomoaki Onoue , Masaharu Sato , Eiji Kokubu , Kazumi Chiba , Kazato Yanada , Toshiyuki Kiryu , Teruhisa Takada , Hidehisa Mokudai , Toru Sukigara
IPC分类号： H01M10/0569 , H01M10/44 , H01M10/0525
CPC分类号： H01M10/0569 , H01M4/0447 , H01M4/137 , H01M4/1399 , H01M4/602 , H01M10/052 , H01M10/0525 , H01M10/44 , H01M2220/30 , H01M2300/0028
摘要： A secondary battery that has an electrode active material mainly composed of a low-molecular-weight multi-electron organic compound that has two or more electrons to be involved in a battery electrode reaction, and a solvent for an electrolyte solution that contains a sulfone compound. Apart of the electrode active material is dissolved in and reacted with the electrolyte solution at the first charge and discharge, thereby oligomerizing a part of the electrode active material.
摘要翻译：具有主要由具有两个以上电子参与电池电极反应的低分子量多电子有机化合物构成的电极活性物质的二次电池和含有砜化合物的电解液溶剂。电极活性物质除了在第一次充放电之前溶解并与电解液反应，从而使一部分电极活性物质低聚。

84. 发明授权

US09005311B2 Electrode active surface pretreatment 有权
标题翻译：电极主动表面预处理
公开(公告)号：US09005311B2
公开(公告)日：2015-04-14
申请号：US14069698
申请日：2013-11-01
申请人： Sion Power Corporation
发明人： Marina Safont-Sempere , Chariclea Scordilis-Kelley
IPC分类号： H01M4/13 , H01M4/139 , H01M6/50 , H01M4/04 , H01M4/1395 , H01M10/44
CPC分类号： H01M4/139 , H01M4/0447 , H01M4/1395 , H01M6/5088 , H01M10/44 , Y02E60/122 , Y10T29/49108 , Y10T29/49115
摘要： Electrode structures and methods of formation are provided. The formation process may include an initial high rate discharge to precondition the electrode active surface. The resulting electroactive surface may have reduced pitting and defects resulting in more uniform utilization of the electrode during subsequent cycling.
摘要翻译：提供了电极结构和形成方法。形成过程可以包括初始高速率放电以预处理电极活性表面。所得的电活性表面可能具有减少的点蚀和缺陷，导致在随后的循环期间电极的更均匀的利用。

85. 发明申请

US20140146440A1 LITHIUM ION CAPACITORS AND METHODS OF PRODUCTION 有权
标题翻译：锂离子电容器和生产方法
公开(公告)号：US20140146440A1
公开(公告)日：2014-05-29
申请号：US13687161
申请日：2012-11-28
申请人： Kishor Purushottam Gadkaree , Xiaorong Liu
发明人： Kishor Purushottam Gadkaree , Xiaorong Liu
IPC分类号： H01G11/62 , H01G11/32
CPC分类号： H01G11/06 , H01G11/32 , H01G11/34 , H01G11/50 , H01G11/62 , H01G11/84 , H01M4/0447 , H01M4/1395 , H01M4/366 , H01M4/382 , H01M10/052 , H01M10/0566 , H01M10/0568 , H01M12/005 , Y02E60/13 , Y10T29/417
摘要： A lithium-ion capacitor may include a cathode, an anode, a separator disposed between the cathode and the anode, a lithium composite material, and an electrolyte solution. The cathode and anode may be non-porous. The lithium composite material comprises a core of lithium metal and a coating of a complex lithium salt that encapsulates the core. In use, the complex lithium salt may dissolve into and constitute a portion of the electrolyte solution.
摘要翻译：锂离子电容器可以包括阴极，阳极，设置在阴极和阳极之间的隔膜，锂复合材料和电解质溶液。阴极和阳极可以是无孔的。锂复合材料包括锂金属的芯和封装芯的复合锂盐的涂层。在使用中，复合锂盐可以溶解并构成电解质溶液的一部分。

86. 发明申请

US20140123477A1 ELECTRODE ACTIVE SURFACE PRETREATMENT 有权
标题翻译：电极活性表面预处理
公开(公告)号：US20140123477A1
公开(公告)日：2014-05-08
申请号：US14069698
申请日：2013-11-01
申请人： Sion Power Corporation
发明人： Marina M. Safont Sempere , Chariclea Scordilis-Kelley
IPC分类号： H01M4/139
CPC分类号： H01M4/139 , H01M4/0447 , H01M4/1395 , H01M6/5088 , H01M10/44 , Y02E60/122 , Y10T29/49108 , Y10T29/49115
摘要： Electrode structures and methods of formation are provided. The formation process may include an initial high rate discharge to precondition the electrode active surface. The resulting electroactive surface may have reduced pitting and defects resulting in more uniform utilization of the electrode during subsequent cycling.
摘要翻译：提供了电极结构和形成方法。形成过程可以包括初始高速率放电以预处理电极活性表面。所得的电活性表面可能具有减少的点蚀和缺陷，导致在随后的循环期间电极的更均匀的利用。

87. 发明授权

US06270535B1 Method of forming CoOOH and NiOOH in a NiMH electrochemical cell and an electrochemical cell formed thereby 失效
标题翻译：在NiMH电化学电池中形成CoOOH和NiOOH的方法以及由此形成的电化学电池
公开(公告)号：US06270535B1
公开(公告)日：2001-08-07
申请号：US09148176
申请日：1998-09-04
申请人： Deepika B. Singh
发明人： Deepika B. Singh
IPC分类号： H01M452
CPC分类号： H01M4/0447 , H01M4/52 , H01M10/288 , H01M10/345 , H01M10/44 , H01M10/446 , H02J7/0075 , Y10T29/49108
摘要： A formation procedure for a NiMH electrochemical cell is disclosed that significantly shortens the time required to fully form such a cell. The formation procedure includes a first step during which the cell is charged at a constant voltage of preferably 1.0 volt for approximately three hours. A second charging step is performed by applying either a constant charge current at a predetermined rate of C/3 for five hours or applying a constant voltage of 1.45 to 1.5 volts for five to nine hours. A third step may optionally be used whereby the cell is charged at a constant current of C/10 for about two hours. NiMH cells subjected to this formation procedure have a much greater percentage of the starting cobalt material in the positive electrode converted to CoOOH thereby improving the conductive matrix formed about the Ni(OH)2/NiOOH particles, which constitute the active material of the positive electrode. The disclosed inventive formation procedures result in higher utilization, higher cell capacities following long-term storage, or storage at high temperatures as well as improved capacity recovery following deep discharge.
摘要翻译：公开了一种NiMH电化学电池的形成方法，其显着缩短了完全形成这种电池所需的时间。形成步骤包括第一步骤，在该步骤中，电池以优选1.0伏的恒定电压充电大约三个小时。通过以C / 3的预定速率施加恒定充电电流5小时或施加1.45至1.5伏的恒定电压进行5至9小时来执行第二充电步骤。可以任选地使用第三步骤，由此电池以C / 10的恒定电流充电约2小时。经过这种形成过程的NiMH电池具有比正转化成CoOOH的起始钴材料的百分比大得多，从而改善了构成正极活性材料的Ni（OH）2 / NiOOH颗粒周围形成的导电基体。所公开的本发明形成方法导致更高的利用率，长期储存后的更高的电池容量或在高温下的储存以及在深度放电之后改进的容量恢复。

88. 发明授权

US6048645A Method of preparing lithium ion electrochemical cells 失效
标题翻译：制备锂离子电化学电池的方法
公开(公告)号：US6048645A
公开(公告)日：2000-04-11
申请号：US915990
申请日：1997-08-21
申请人： Mohamed-Yazid Saidi , Jeffrey L. Swoyer
发明人： Mohamed-Yazid Saidi , Jeffrey L. Swoyer
IPC分类号： C01G45/00 , C01G45/12 , H01M4/04 , H01M4/131 , H01M4/50 , H01M4/505 , H01M10/0525 , H01M10/36 , H01M10/44 , H01M4/02
CPC分类号： H01M4/505 , C01G45/1228 , C01G45/1235 , H01M10/0525 , H01M10/44 , H01M4/0447 , H01M4/0459 , C01P2002/72 , C01P2002/77 , C01P2006/40 , H01M10/446 , H01M4/131
摘要： In one embodiment, the invention provides a novel active material which is a lithium-rich, manganese oxide active material in the form of a single phase tetragonal crystal structured Li.sub.2 Mn.sub.2 O.sub.4 compound having lattice parameters a=b=5.665 .ANG..+-.0.003 .ANG., and c=9.265 .ANG..+-.0.003 .ANG.. A unique characteristic of the compound is that when lithium ions are deintercalated (extracted) from the Li.sub.2 Mn.sub.2 O.sub.4 at first and second voltage plateaus, the crystal structure is transformed to a cubic structure characterized by lattice parameters a=b=c=8.235 .ANG..+-.0.004 .ANG.. On subsequent charge and discharge of the battery, corresponding to subsequent extraction and reinsertion of lithium into the electrode material at the second voltage plateau, the cubic structure is maintained.
摘要翻译：在一个实施方案中，本发明提供了一种新颖的活性材料，其为具有晶格参数a = b = 5.665 ANGSTROM +/- 0.003 ANGSTROM的单相四方晶体结构Li2Mn2O4化合物形式的富锂锰氧化物活性材料，以及 c = 9.265 ANGSTROM +/- 0.003 ANGSTROM。化合物的独特特征是当锂离子在第一和第二电压平台从Li2Mn2O4脱嵌（提取）时，晶体结构转变为以晶格参数为特征的立方结构a = b = c = 8.235 ANGSTROM +/- 0.004 ANGSTROM。在随后的电池的充电和放电中，对应于随后在第二电压平台处将锂提取并重新插入电极材料中，保持立方结构。

89. 发明授权

US5948569A Lithium ion electrochemical cell 失效
标题翻译：锂离子电化学电池
公开(公告)号：US5948569A
公开(公告)日：1999-09-07
申请号：US897775
申请日：1997-07-21
申请人： Peter R. Moses , Shuming Zeng , Enoch Wang , Guang Wei
发明人： Peter R. Moses , Shuming Zeng , Enoch Wang , Guang Wei
IPC分类号： H01M2/16 , H01M4/04 , H01M10/0525 , H01M10/40 , H01M10/42 , H01M10/44
CPC分类号： H01M10/0525 , H01M10/4235 , H01M2/16 , H01M4/0447 , H01M10/446 , H01M2010/4292 , Y02P70/54 , Y10T29/49108 , Y10T29/49115
摘要： A lithium ion cell having an amount of a Group 1 element between the positive electrode and the negative electrode is described. The Group 1 element can be on an surface of an electrode separator as a deposit. The Group 1 element can increase the charging capacity of the cell, eliminate the irreversible capacity of the cell, improve the rechargeable cell cyclability, or increase the charging reversibility of the cell.
摘要翻译：对在正极和负极之间具有1族元素量的锂离子电池进行说明。第1族元素可以作为沉积物在电极分离器的表面上。第1族元素可以增加电池的充电能力，消除电池的不可逆容量，提高可充电电池的循环性，或提高电池的充电可逆性。

90. 发明授权

US5612152A Rechargeable lithium battery for use in applications requiring a low to high power output 失效
标题翻译：可充电锂电池，用于需要低至高功率输出的应用
公开(公告)号：US5612152A
公开(公告)日：1997-03-18
申请号：US634115
申请日：1996-04-17
申请人： John B. Bates
发明人： John B. Bates
IPC分类号： H01M2/20 , H01M4/04 , H01M6/40 , H01M6/42 , H01M10/36 , H01M10/02
CPC分类号： H01M10/0562 , H01M4/0447 , H01M6/40 , H01M2/20 , H01M6/42
摘要： Rechargeable lithium batteries which employ characteristics of thin-film batteries can be used to satisfy power requirements within a relatively broad range. Thin-film battery cells utilizing a film of anode material, a film of cathode material and an electrolyte of an amorphous lithium phosphorus oxynitride can be connected in series or parallel relationship for the purpose of withdrawing electrical power simultaneously from the cells. In addition, such battery cells which employ a lithium intercalation compound as its cathode material can be connected in a manner suitable for supplying power for the operation of an electric vehicle. Still further, by incorporating within the battery cell a relatively thick cathode of a lithium intercalation compound, a relatively thick anode of lithium and an electrolyte film of lithium phosphorus oxynitride, the battery cell is rendered capable of supplying power for any of a number of consumer products, such as a laptop computer or a cellular telephone.
摘要翻译：可以使用采用薄膜电池特性的可充电锂电池来满足在较宽范围内的功率要求。利用阳极材料膜，阴极材料膜和非晶态磷酸氢氧化锂的电解质的薄膜电池可以串联或并联连接，以便同时从电池中取出电力。此外，采用锂嵌入化合物作为其阴极材料的这种电池单元可以以适于为电动车辆的操作供电的方式连接。此外，通过在电池单元内结合锂嵌入化合物的相对厚的阴极，锂的相对厚的阳极和磷酸氢氧化锂的电解质膜，电池单元能够为多个消费者中的任何一个供电产品，例如膝上型计算机或蜂窝电话。

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