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    • 82. 发明授权
    • Diketopyrrolopyrrole cocrystals with high transparency
    • 具有高透明度的二酮吡咯并吡咯共晶体
    • US08318052B2
    • 2012-11-27
    • US12526922
    • 2008-01-17
    • Matthias Ganschow
    • Matthias Ganschow
    • F21V9/00G02B5/02G02C7/10G02F1/361G03B11/00C08K5/00C09D11/00C07D243/08G03G9/00
    • C07D487/04C09B57/004C09B67/0039
    • The present invention relates to a pigment composition composed of compounds of the formula (I), (II) and (III) with a novel crystal modification, to their preparation and to the use of this novel product as a pigment. For many applications of organic pigments, for example the coloring of metallic lacquers or the use thereof in color filters, a very high transparency is required. To produce color filters, for example, particularly fine pigments are used, in order to substantially rule out the particle scattering which leads to a lowering of the contrast ratio. The commercially available products, however, do not always meet all requirements of the art. More particularly, there was a need for improvement with regard to the transparency and the associated fineness of the pigment crystals, and also the color purity (chroma).
    • 本发明涉及一种由式(I),(II)和(III)的化合物组成的颜料组合物及其制备方法和该新产品作为颜料的用途。 对于有机颜料的许多应用,例如金属漆的着色或其在滤色器中的应用,需要非常高的透明度。 为了生产滤色器,例如使用特别细的颜料,以便基本排除导致对比度降低的颗粒散射。 然而,市售产品并不总是满足本领域的所有要求。 更具体地,需要改进颜料晶体的透明度和相关细度,以及色纯度(色度)。
    • 86. 发明授权
    • Process for the preparation of diketopyrrolopyrroles
    • 二酮吡咯并吡咯的制备方法
    • US07326793B2
    • 2008-02-05
    • US10485840
    • 2002-09-03
    • Colin MortonDavid Macdonald SmithVincent Ruffieux
    • Colin MortonDavid Macdonald SmithVincent Ruffieux
    • C07D403/04C07D401/04C07D487/04
    • C07D487/04C07D491/04C09B57/004C09B67/0039C09K11/06C09K2211/1011C09K2211/1033C09K2211/1044
    • The present invention relates to a process for the preparation of diketopyrrolopyrroles of the formula (I), wherein A1, A2, A3 and A4 are as defined in the description of the present invention, to new diketopyrrolopyrroles of the general formula I obtainable by the process, and the use of the new diketopyrrolopyrroles of the general formula I for the preparation of inks, colorants, pigmented plastics for coatings, non-impact-printing material, color filters, cosmetics, polymeric ink particles, toners, dye lasers and electroluminescent devices, or as fluorescent markers for immunoassays and fluorescent tracers for leak detection of fluids. Furthermore the present invention relates to diketopyrrolopyrrole analogues of the general formula (II), wherein A1, A2 and A3 are defined in the description of the present invention, which are intermediates in the process for the preparation of diketopyrrolopyrroles of the formula I and can be used as crystal growth regulators
    • 本发明涉及一种制备式(I)的二酮吡咯并吡咯的方法,其中A1,A2,A3和A4如本发明的描述所定义,可通过该方法获得的通式I的新二酮吡咯并吡咯 ,以及使用通式I的新二酮吡咯并吡咯制备油墨,着色剂,涂料着色塑料,非冲击印刷材料,滤色器,化妆品,聚合物油墨颗粒,调色剂,染料激光和电致发光装置, 或用作免疫测定的荧光标记物和荧光示踪剂,用于检测流体。 此外,本发明涉及通式(II)的二酮吡咯并吡咯类似物,其中A1,A2和A3在本发明的说明书中定义,其是制备式I的二酮吡咯并吡咯吡咯的方法中的中间体,并且可以是 用作晶体生长调节剂
    • 88. 发明申请
    • Process for the preparation of diketopyrrolopyrroles
    • 二酮吡咯并吡咯的制备方法
    • US20040171847A1
    • 2004-09-02
    • US10485840
    • 2004-02-04
    • Colin MortonDavid Macdonald SmithVincent Ruffieux
    • C07D487/02
    • C07D487/04C07D491/04C09B57/004C09B67/0039C09K11/06C09K2211/1011C09K2211/1033C09K2211/1044
    • The present invention relates to a process for the preparation of diketopyrrolopyrroles of the formula (I), wherein A1, A2, A3 and A4 are as defined in the description of the present invention, to new diketopyrrolopyrroles of the general formula I obtainable by the process, and the use of the new diketopyrrolopyrroles of the general formula I for the preparation of inks, colorants, pigmented plastics for coatings, non-impact-printing material, color filters, cosmetics, polymeric ink particles, toners, dye lasers and electroluminescent devices, or as fluorescent markers for immunoassays and fluorescent tracers for leak detection of fluids. Furthermore the present invention relates to diketopyrrolopyrrole analogues of the general formula (II), wherein A1, A2 and A3 are defined in the description of the present invention, which are intermediates in the process for the preparation of diketopyrrolopyrroles of the formula I and can be used as crystal growth regulators. 1
    • 本发明涉及一种制备式(I)的二酮吡咯并吡咯的方法,其中A1,A2,A3和A4如本发明的描述所定义,可通过该方法获得的通式I的新二酮吡咯并吡咯 ,以及使用通式I的新二酮吡咯并吡咯制备油墨,着色剂,涂料着色塑料,非冲击印刷材料,滤色器,化妆品,聚合物油墨颗粒,调色剂,染料激光和电致发光装置, 或用作免疫测定的荧光标记物和荧光示踪剂,用于检测流体。 此外,本发明涉及通式(II)的二酮吡咯并吡咯类似物,其中A1,A2和A3在本发明的说明书中定义,其是制备式I的二酮吡咯并吡咯吡咯的方法中的中间体,并且可以是 用作晶体生长调节剂。
    • 89. 发明授权
    • Preparation of alkylthio- and/or arylthio-substituted diketo-diaryl-pyrrolopyrroles
    • 烷硫基 - 和/或芳硫基取代的二酮 - 二芳基 - 吡咯并吡咯的制备
    • US06576768B1
    • 2003-06-10
    • US09294483
    • 1999-04-20
    • Zhimin HaoAlain Claude RochatNancy Schlöder-Tebaldi
    • Zhimin HaoAlain Claude RochatNancy Schlöder-Tebaldi
    • C07D48704
    • C09B57/004C08K5/3415C09B67/0039
    • Preparation of alkylthio and/or arylthio-substituted diketo-diaryl-pyrrolopyrroles (DPPs) of the formula Ia and dithio-bridged bis-diketo-diaryl-pyrrolopyrroles (bis-DPPs) of the formula Ib in which in formula Ia G is phenyl substituted by at least one arylthio or alkylthio group, and G1 is G or a carbocyclic or heterocyclic radical, by reacting a haloaryl with a thiol or thiolate, and in formula Ib G5 is a phenylene, G6 is G1 but not G, and G7 is alkylene, cycloalkylene or phenylene, by reacting two haloaryls with a dithiol or dithiolate, which comprises reacting a thiol or thiolate with a halo-diketo-diaryl-pyrrolopyrrole (“halo-DPP”) of the formula IIa in which G2 is a halogenated phenyl group and G3 is G2 or G1, or reacting a dithiol or dithiolate with two halo-diketo-diaryl-pyrrolopyrroles (“halo-DPPs”) of the formula IIb in which Hal is halogen such as fluorine, chlorine, bromine or iodine, and G6 is G1, and also novel DPPs and also bis-DPPs, compositions comprising the DPPs of the formula Ia prepared in accordance with the invention, and their uses.
    • 式Ia的烷硫基和/或芳硫基取代的二酮 - 二芳基 - 吡咯并吡咯(DPP)和式Ibin中的二硫桥联的双 - 二酮 - 二芳基 - 吡咯并吡咯(bis-DPP),其中在式IaG中是被 至少一个芳硫基或烷硫基,并且G 1是G或碳环或杂环基团,通过卤代芳基与硫醇或硫醇盐反应,并且在式Ib中G5是亚苯基,G6是G1而不是G,G7是亚烷基,亚环烷基 或亚苯基,通过使两个卤代芳基与二硫醇或二硫醇盐反应,其包括使硫醇或硫醇盐与式IIain的卤代二酮 - 二芳基 - 吡咯并吡咯(“卤代DPP”)反应,其中G2是卤代苯基,G3是 或二硫醇或二硫醇盐与二卤代二酮 - 二芳基吡咯并吡咯(“卤代DPP”)反应,其中Hal是卤素如氟,氯,溴或碘,G6是G1,和 还有新的DPP和双DPP,包含f的DPP的组合物 根据本发明制备的组织Ia及其用途。