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81. 发明公开

EP1641842A2 POLYMERIZATION AND OLIGOMERIZATION CATALYST WITH TRIDENTATE OR TETRADENTATE LIGAND 审中-公开
标题翻译：聚合或低聚催化剂与三或四配位体
公开(公告)号：EP1641842A2
公开(公告)日：2006-04-05
申请号：EP04753541.4
申请日：2004-05-27
申请人： ExxonMobil Chemical Patents Inc.
发明人： SOLAN, Gregory, A. , DAVIES, Christopher, J.
IPC分类号： C08F10/00 , C07F15/02 , C07F15/04 , C07F15/06 , B01J23/75 , B01J27/128
CPC分类号： C07C2/32 , B01J31/143 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2531/26 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C07C11/02 , C08F2500/02 , C08F4/60089 , C08F4/7042 , C08F4/50 , C08F4/7081
摘要： This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9 or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3-C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3-C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoamionic ligand, or two X may join together to form a bidentale dianionic ligand.

82. 发明授权

EP1187856B1 TRANSITION METAL COMPLEXES AND OLEFIN POLYMERIZATION PROCESS 有权
标题翻译：过渡金属络合物和烯烃聚合
公开(公告)号：EP1187856B1
公开(公告)日：2003-09-10
申请号：EP00919456.4
申请日：2000-03-17
申请人： Dow Global Technologies Inc.
发明人： DEVORE, David, D. , FENG, Shaoguang, S. , FRAZIER, Kevin, A. , PATTON, Jasson, T.
IPC分类号： C08F10/00 , C08F4/60 , C07F5/00 , C07F7/00 , C07F9/00 , C07F11/00 , C07F13/00 , C07F15/00
CPC分类号： C08F10/06 , C07F5/003 , C07F7/006 , C07F9/005 , C07F11/005 , C07F13/005 , C07F15/025 , C08F10/00 , C08F110/06 , C08F4/619 , C08F4/52 , C08F4/64089 , C08F4/69224 , C08F4/68224 , C08F4/60089 , C08F2500/03 , C08F2500/15 , C08F4/7042
摘要： Metal complexes comprising a polydentate chelating group, catalysts and polymerization processes using the same for the polymerization of olefins, especially propylene, are disclosed.

83. 发明公开

EP1159307A1 POLYMERISATION PROCESS 有权
标题翻译：聚合工艺
公开(公告)号：EP1159307A1
公开(公告)日：2001-12-05
申请号：EP99973040.1
申请日：1999-11-16
申请人： BP Chemicals Limited , BP CHEMICALS S.N.C.
发明人： BERARDI, Alain , SPEAKMAN, John, Gabriel
IPC分类号： C08F4/70 , C08F10/00
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , Y10S526/901 , C08F4/025 , C08F2500/12 , C08F2500/07 , C08F2500/18 , C08F2500/24 , C08F4/60089 , C08F4/7042
摘要： A process for the polymerisation of 1-olefins is disclosed which comprises the steps of a) preparing a prepolymer-based catalyst by contacting one or more 1-olefins with a catalyst system, and b) contacting the prepolymer-based catalyst with one or more 1-olefins, wherein the catalyst system comprises (1) a compound of formula (I) wherein M is Fe[II] , Fe[III], Co[I], Co[II], Co[III], Mn[I], Mn[II], Mn[III], Mn[IV], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R?1, R2, R3, R4, R5, R6 and R7¿ are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; and when any two or more of R1 -R7 are hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; optionally (2) an activator, and also optionally (3) a compound of the formula AlR¿3?, where each R is independently C1-C12 alkyl or halo.
摘要翻译：公开了用于聚合1-烯烃的方法，其包括以下步骤：a）通过使一种或多种1-烯烃与催化剂体系接触来制备预聚物基催化剂，和b）使预聚物基催化剂与一种或多种其中所述催化剂体系包含（1）其中M为Fe [II]，Fe [III]，Co [I]，Co [II]，Co [III]，Mn [I ]，Mn [II]，Mn [III]，Mn [IV]，Ru [II]，Ru [III]或Ru [IV] X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R1，R2，R3，R4，R5，R6和R7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基; 并且当R1-R7中的任何两个或更多个是烃基，取代的烃基，杂烃基或取代的杂烃基时，所述两个或更多个可以连接形成一个或多个环状取代基; 任选地（2）活化剂，并且任选地（3）式AlR 3'的化合物，其中每个R独立地为C 1 -C 12烷基或卤素。

84. 发明公开

EP1062251A1 POLYMERISATION CATALYST 有权
标题翻译：聚合催化剂
公开(公告)号：EP1062251A1
公开(公告)日：2000-12-27
申请号：EP99907757.1
申请日：1999-03-10
申请人： BP Chemicals Limited
发明人： KIMBERLEY, Brian Stephen , PRATT, David
IPC分类号： C08F4/70 , C08F10/00
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/04 , C08F4/61904 , C08F2500/04 , C08F2500/12 , C08F2500/07 , C08F210/14 , C08F2500/10 , C08F2500/03 , C08F2500/26 , C08F4/60089 , C08F4/7042 , C08F4/025
摘要： A catalyst suitable for the polymerisation of 1-olefins is disclosed, comprising (1) a nitrogen-containing iron compound having Formula Z, and (2) an activating quantity of an activator compound selected from organoaluminium compounds and hydrocarbylboron compounds wherein X represents an atom or group covalently or ionically bonded to the Fe and b is the valency of the atom or group X, characterised in that the catalyst is supported on (3) a solid particulate support material.

85. 发明公开

EP1015501A1 POLYMERISATION CATALYSTS 有权
标题翻译：聚合催化剂
公开(公告)号：EP1015501A1
公开(公告)日：2000-07-05
申请号：EP98940461.1
申请日：1998-09-02
申请人： BP Chemicals Limited
发明人： BRITOVSEK, George, Johan, Peter , DORER, Birgit, Angelika , GIBSON, Vernon, Charles , KIMBERLEY, Brian, Stephen , SOLAN, Gregory, Adam
IPC分类号： C08F4/70 , C07D213/53 , C07F15/02 , C07F15/06 , C08F10/00
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/04 , C08F4/61904 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F210/14 , C08F2500/10 , C08F2500/26 , C08F2500/03 , C08F4/60089 , C08F4/7042 , C08F4/6546
摘要： Catalyst systems useful for the polymerisation of 1-olefins are disclosed, which contain nitrogen-containing transition metal compounds comprising the skeletal unit depicted in Formula (B), wherein M is Fe[II], Fe[III], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R?1, R2, R3, R4 and R6¿ are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; R?5 and R7¿ are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl.
摘要翻译：公开了用于1-烯烃聚合的催化剂体系，其含有包含式（B）中描述的骨架单元的含氮过渡金属化合物，其中M为Fe [II]，Fe [III]，Ru [II] Ru [III]或Ru [IV]; X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R1，R2，R3，R4和R6独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基; R 5和R 7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基。

86. 发明公开

KR1020070015407A 올레핀 중합용 촉매계, 이의 제법 및 용도 有权
标题翻译：用于烯烃聚合的催化剂体系，其生产和使用
公开(公告)号：KR1020070015407A
公开(公告)日：2007-02-02
申请号：KR1020067022137
申请日：2005-04-21
申请人： 바젤 폴리올레핀 게엠베하
发明人： 미한,샤람 , 슈미츠,하랄트
IPC分类号： C08F4/6592 , C08F4/65 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F110/02 , Y10S526/943 , C08F2/34 , C08F4/61904 , C08F4/65916 , C08F4/025 , C08F4/60089 , C08F4/69224 , C08F4/7042
摘要： Process for producing a catalyst system, which comprises the following steps: A) provision of a mixture of at least two different organic transition metal compounds, at least one hydrolyzed organoaluminum compound and a solvent and impregnation of a dry porous support component with the mixture from step A), with the total volume of the mixture being from 0.6 to 1.5 times the total pore volume of the support component, and also catalyst systems obtainable in this way and their use for olefin polymerization. ® KIPO & WIPO 2007
摘要翻译：制备催化剂体系的方法，其包括以下步骤：A）提供至少两种不同的有机过渡金属化合物，至少一种水解的有机铝化合物和溶剂的混合物，并将干燥的多孔载体组分浸渍步骤A），混合物的总体积为载体组分的总孔体积的0.6-1.5倍，以及可以以这种方式获得的催化剂体系及其在烯烃聚合中的用途。 ®KIPO＆WIPO 2007

87. 发明公开

KR1020010023690A 중합 촉매 失效
公开(公告)号：KR1020010023690A
公开(公告)日：2001-03-26
申请号：KR1020007002343
申请日：1998-09-02
申请人： 비피 케미칼즈 리미티드
发明人： 브리토브섹죠지조한피터 , 도러버짓안젤리카 , 깁슨버논찰스 , 킴벌리브라이언스티븐 , 솔란그레고리아담
IPC分类号： C08F4/70
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/04 , C08F4/61904 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F210/14 , C08F2500/10 , C08F2500/26 , C08F2500/03 , C08F4/60089 , C08F4/7042 , C08F4/6546
摘要： 하기화학식 B 에나타난골격단위를포함하는질소함유전이금속화합물을함유하는, 1-올레핀의중합에유용한촉매계가기재되어있다: [화학식 B] [여기서, M 은 Fe[II], Fe[III], Ru[II], Ru[III] 또는 Ru[IV] 이고; X 는전이금속 M 에공유결합또는이온결합된원자또는기를나타내고; T 는전이금속 M 의산화상태이고, b 는원자또는기 X 의원자가이고; R, R, R, R및 R은독립적으로수소, 할로겐, 히드로카르빌, 치환된히드로카르빌, 헤테로히드로카르빌또는치환된헤테로히드로카르빌로부터선택된다].

88. 发明授权

KR101157062B1 비스-이미노 피리디닐 전이 금속 촉매 성분들을 사용하는에틸렌 중합 반응 失效
标题翻译：乙烯聚合使用双 - 亚氨基吡啶衍生物金属催化剂组分
公开(公告)号：KR101157062B1
公开(公告)日：2012-06-21
申请号：KR1020067007776
申请日：2004-09-17
申请人： 피나 테크놀러지, 인코포레이티드
发明人： 아바스,라자비 , 마린,블라드미르 , 로페즈,마르가리토
IPC分类号： C08F4/00 , C08F4/46 , C08F10/02
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F2410/04 , C08F2500/04 , C08F210/14 , C08F4/60089 , C08F4/7042
摘要： Ethylene polymerization processes employing bis-imino pyridinyl transition metal components which exhibit C2, C2v or Cs symmetry. Catalyst components of the same or different symmetries may be employed to control polymerization characteristics and characteristics of the resulting polymer products such as polymer yield and polymer molecular weight. The transition metal catalyst component is characterized by the formula: wherein M is a Group 4-11 transition metal, n is an integer within the range of 1-3, Q is a halogen or a C 1 -C 2 alkyl group, and PY is a pyridinyl group which is coordinated with M through the nitrogen atom of the pyridinyl group. Further, with respect to formula (I), A is a methyl group, a phenyl group, or a substituted phenyl group and B 1 and B 2 are the same or different aromatic groups depending on the symmetry of the catalyst component. The catalyst component and an activating co-catalyst component are contacted with ethylene in a polymerization reaction zone which is free of hydrogen or contains hydrogen in an amount which is less than 5 mole % of the ethylene under polymerization conditions to produce a polymer product which can be a ethylene homopolymer or a copolymer of ethylene and C 3+ alpha olefin, specifically an ethylene-propylene copolymer.

89. 发明公开

KR1020060107518A 디이민 리간드, 금속 화합물, 올레핀 중합 반응 과정 失效
标题翻译：金属配体，金属化合物，烯烃聚合方法
公开(公告)号：KR1020060107518A
公开(公告)日：2006-10-13
申请号：KR1020067007775
申请日：2004-09-17
申请人： 피나 테크놀러지, 인코포레이티드
发明人： 아바스,라자비 , 마린,블라드미르 , 로페즈,마르가리토
IPC分类号： C08F4/00 , C08F10/00 , C08F4/80 , C08F4/60
CPC分类号： B01J31/1815 , B01J2231/122 , B01J2531/842 , C07F15/025 , C08F10/00 , C08F110/02 , C08F2500/12 , C08F2500/04 , C08F2500/20 , C08F2500/19 , C08F2500/17 , C08F4/60089 , C08F4/7042
摘要： Catalyst compositions having Cs symmetry and processes utilizing Cs symmetric catalyst components for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. Monomers, which are polymerized or copolymerized include ethylene, C3+ alpha olefins and substituted vinyl compounds, such as styrene and vinyl chloride. The catalyst component is characterized by the formula (I) wherein M is a Group 4-11 transition metal, n is an integer of from 1-3, Q is halogen or a C1 - C2 alkyl group, PY is a pyridinyl group, R' and R" are each C1 - C20 hydrocarbyl group, A 1 is a mononuclear aromatic group, and A2 is a polynuclear aromatic group, such as a terphenyl group. The catalyst component is used with an activating co-catalyst component such as an alumoxane. Also disclosed is a process for the preparation of a pyridinyl-linked bis- amino ligand suitable for use in forming the catalyst component.
摘要翻译：具有Cs对称性的催化剂组合物和利用Cs对称催化剂组分用于烯属不饱和单体聚合以产生聚合物（包括共聚物或均聚物）的方法。聚合或共聚的单体包括乙烯，C 3+α-烯烃和取代的乙烯基化合物，例如苯乙烯和氯乙烯。催化剂组分的特征在于式（I）其中M为4-11族过渡金属，n为1-3的整数，Q为卤素或C1-C2烷基，PY为吡啶基，R '和R“分别为C 1〜C 20烃基，A 1为单核芳香族基团，A2为三联苯等多元芳香族基团，催化剂成分与活性助催化剂成分还公开了一种制备适合用于形成催化剂组分的吡啶基连接的双 - 氨基配位体的方法。

90. 发明公开

EP1684901A4 DIIMINE LIGAND, METAL COMPOUND, OLEFIN POLYMERIZATION PROCESS 有权
标题翻译：二亚胺配体，金属化合物，烯烃聚合
公开(公告)号：EP1684901A4
公开(公告)日：2008-09-03
申请号：EP04784548
申请日：2004-09-17
申请人： FINA TECHNOLOGY
发明人： ABBAS RAZAVI , MARIN VLADIMIR , LOPEZ MARGARITO
IPC分类号： B01J31/00 , B01J31/18 , C07F1/08 , C07F1/10 , C07F9/00 , C07F11/00 , C07F13/00 , C07F15/00 , C07F15/02 , C07F17/00 , C08F4/06 , C08F4/44 , C08F10/00 , C08F110/02
CPC分类号： B01J31/1815 , B01J2231/122 , B01J2531/842 , C07F15/025 , C08F10/00 , C08F110/02 , C08F2500/12 , C08F2500/04 , C08F2500/20 , C08F2500/19 , C08F2500/17 , C08F4/60089 , C08F4/7042
摘要： Catalyst compositions having Cs symmetry and processes utilizing Cs symmetric catalyst components for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. Monomers, which are polymerized or copolymerized include ethylene, C3+ alpha olefins and substituted vinyl compounds, such as styrene and vinyl chloride. The catalyst component is characterized by the formula (I) wherein M is a Group 4-11 transition metal, n is an integer of from 1-3, Q is halogen or a C1 - C2 alkyl group, PY is a pyridinyl group, R' and R' are each C1 - C20 hydrocarbyl group, A1 is a mononuclear aromatic group, and A2 is a polynuclear aromatic group, such as a terphenyl group. The catalyst component is used with an activating co-catalyst component such as an alumoxane. Also disclosed is a process for the preparation of a pyridinyl-linked bis-amino ligand suitable for use in forming the catalyst component.

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