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    • 82. 发明申请
    • LITHIUM TITANATE AND METHOD OF FORMING THE SAME
    • 钛酸钛及其形成方法
    • WO2007120607A3
    • 2008-07-17
    • PCT/US2007008753
    • 2007-04-10
    • ENERDEL INCGORSHKOV VADIMVOLKOV OLEG
    • GORSHKOV VADIMVOLKOV OLEG
    • C01G23/04H01M4/48H01M4/485H01M10/052H01M10/36
    • C01G23/005C01P2002/77C01P2006/40H01M4/485H01M10/052Y02T10/7011
    • A lithium titanate has the following formula: Li 4 Ti 5 O 12-X wherein x is greater than O. The lithium titanate is formed by providing a mixture of titanium dioxide and a lithium-based component. The mixture is sintered in a gaseous atmosphere comprising a reducing agent to form the lithium titanate having the above formula. A lithium-based cell includes an electrolyte, an anode, and a cathode, with at least one of the anode and the cathode comprising the lithium titanate having the above formula. The lithium titanate is deficient of oxygen, which increases electronic conductivity of the lithium titanate by at least three orders over electronic conductivity of a stoichiometric lithium titanate, while avoiding loss of reversible electric power- generating capacity that typically occurs when doping is used to replace titanium in the lithium titanate with atoms that provide higher electronic conductivity.
    • 钛酸锂具有下式:其中X大于0,其中x大于O.钛酸锂由下式形成:钛/ 提供二氧化钛和锂基组分的混合物。 将混合物在包含还原剂的气态气氛中烧结以形成具有上式的钛酸锂。 锂基电池包括电解质,阳极和阴极,阳极和阴极中的至少一个包含具有上式的钛酸锂。 钛酸锂缺乏氧,这使得钛酸锂的电子导电率比化学计量的钛酸锂的电子传导性提高了至少三倍,同时避免了当掺杂用于替代钛时典型地发生的可逆发电能力的损失 在具有提供更高电导率的原子的钛酸锂中。