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    • 85. 发明授权
    • Precursor compositions and processes for MOCVD of barrier materials in semiconductor manufacturing
    • 半导体制造中阻挡材料的MOCVD的前体组成和工艺
    • US07208427B2
    • 2007-04-24
    • US10643110
    • 2003-08-18
    • Jeffrey F. RoederChongying XuBryan C. HendrixThomas H. Baum
    • Jeffrey F. RoederChongying XuBryan C. HendrixThomas H. Baum
    • H01L21/31H01L21/469
    • C23C16/45553C07F7/10C07F9/005C07F11/005C23C16/34C23C16/345C23C16/45525H01L21/28556H01L21/28562H01L21/76801H01L21/76841
    • Metalorganic precursors of the formula: (R1R2N)a−bMXb wherein: M is the precursor metal center, selected from the group of Ta, Ti, W, Nb, Si, Al and B; a is a number equal to the valence of M; 1≦b≦(a−1); R1 and R2 can be the same as or different from one another, and are each independently selected from the group of H, C1–C4 alkyl, C3–C6 cycloalkyl, and R03Si, where each R0 can be the same or different and each R0 is independently selected from H and C1–C4 alkyl; and X is selected from the group of chlorine, fluorine, bromine and iodine. Precursors of such formula are useful for chemical vapor deposition (MOCVD) of conductive barrier materials in the manufacture of microelectronic device structures, e.g., by atomic layer chemical vapor deposition on a substrate bearing nitrogen-containing surface functionality. Further described is a method of forming Si3N4 on a substrate at low temperature, e.g., using atomic layer chemical vapor deposition (ALCVD).
    • 式中的金属有机前体:<?in-line-formula description =“In-line Formulas”end =“lead”?>(R 1 R 2 N N) 其中:M是前体金属中心,其选自下列的化合物:其中:M是前体金属中心, Ta,Ti,W,Nb,Si,Al和B组; a是等于M的化合价数; 1 <= b <=(A-1); R 1和R 2可以彼此相同或不同,并且各自独立地选自H,C 1〜 C 1 -C 4烷基,C 3 -C 6环烷基和R 0〜3个 > Si,其中每个R 0可以相同或不同,并且每个R 0独立地选自H和C 1 -C 3 > 4 烷基; X选自氯,氟,溴和碘。 这种配方的前体可用于制造微电子器件结构中的导电阻挡材料的化学气相沉积(MOCVD),例如通过在含有氮的表面官能团的基底上的原子层化学气相沉积。 进一步描述了在低温下,例如使用原子层化学气相沉积(ALCVD)在衬底上形成Si 3 N 4 N 4的方法。
    • 90. 发明授权
    • Treatment of supercritical fluid utilized in semiconductor manufacturing applications
    • 半导体制造应用中超临界流体的处理
    • US06735978B1
    • 2004-05-18
    • US10364558
    • 2003-02-11
    • Glenn M. TomMichael B. KorzenskiEliodor G. GhenciuChongying XuThomas H. Baum
    • Glenn M. TomMichael B. KorzenskiEliodor G. GhenciuChongying XuThomas H. Baum
    • F25D100
    • C01B32/50Y02P20/544
    • A system and process for utilization and disposition of a supercritical fluid composition, in which a supercritical fluid (SCF) composition is used in an SCF-using process facility such as a semiconductor manufacturing plant. The supercritical fluid composition is withdrawn from the process facility containing at least one component that is extraneous with respect to the further disposition of the supercritical fluid composition. The withdrawn supercritical fluid composition is converted to a pressurized liquid, which is treated to at least partially remove the extraneous component(s) therefrom. The extraneous component(s)-depleted pressurized liquid in its further disposition can be reconverted to a supercritical state for recycle to the SCF-using process facility, or it can be gasified and discharged to the atmosphere in the case of supercritical fluids such as CO2.
    • 一种用于利用和处置超临界流体组合物的系统和方法,其中超临界流体(SCF)组合物在诸如半导体制造厂的SCF使用过程设备中使用。 超临界流体组合物从处理设备中取出,其中含有至少一种相对于超临界流体组合物的进一步处置是无关的组分。 将取出的超临界流体组合物转化为加压液体,其被处理以至少部分地从其中除去外来成分。 在其进一步的处置中,去除加压液体的外来成分可以再转化为超临界状态,以再循环至使用SCF的工艺设备,或者在超临界流体如CO2的情况下,可将其气化并排放到大气中 。