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81. 发明授权

US5780668A X-ray opaque dental materials 失效
标题翻译： X光透镜牙科材料
公开(公告)号：US5780668A
公开(公告)日：1998-07-14
申请号：US450812
申请日：1995-05-25
申请人： Volker Rheinberger , Norbert Moszner , Ulrich Salz
发明人： Volker Rheinberger , Norbert Moszner , Ulrich Salz
IPC分类号： A61K6/083 , C07C69/76 , C07C69/78 , C07C69/84 , C07C69/92 , C07C229/54 , C07C229/56 , C07C229/60 , C07C229/64 , C07C233/54 , C07C233/69 , C07C233/75 , C08F20/26 , C08F20/30 , C08F20/34 , C08F20/36 , C08F220/30 , C08F290/00 , C08F290/06 , C07C69/767 , A61C5/08 , C07C235/42 , C07C235/88
CPC分类号： A61K6/083 , C07C233/54 , C07C69/76 , C08F220/30
摘要： X-ray opaque esters or amides of iodosubstituted benzoic acid according to formula I and polymers and dental materials produced therefrom. ##STR1## R.sup.1 =hydrogen or C.sub.1 to C.sub.3 alkyl, preferably H or CH.sub.3 ; R.sup.2 =straight-chain or branched C.sub.1 to C.sub.6 alkylene, oxyalkylene or arylene, preferably C.sub.2 to C.sub.4 alkylene and particularly preferably --CH.sub.2 --CH.sub.2 -- and --CH.sub.2 CH(--)CH.sub.2 --; X=O or NH, preferably O; R.sup.3 -R.sup.7 =at least 3 iodine substituents, preferably in R.sup.3, R.sup.4 and R.sup.6 or R.sup.3, R.sup.5 and R.sup.7 position, the other groups are hydrogen, C.sub.1 to C.sub.6 alkyl, C.sub.1 to C.sub.6 alkoxy, --Cl, --Br, --OH, --NH.sub.2, --N(C.sub.1 to C.sub.6 alkyl).sub.2 or --NH--CO--(C.sub.1 to C.sub.6 alkyl), preferably R.sup.3, R.sup.4, and R.sup.6 are=I and R.sup.5 and R.sup.7 =H, or R.sup.3, R.sup.5 and R.sup.7 =I and R.sup.4 and R.sup.6 =--NH(COCH.sub.3); n=1, 2 or 3, preferably 1 or 2. The benzoic acid esters and amides according to the invention can be well polymerized radically or anionically, the polymers are well soluble in the usual dental monomers. Dental materials produced from the monomers or polymers are characterized in that the X-ray opaque component is bonded covalently into the polymeric matrix material and cannot therefore be washed out. Furthermore, excellent X-ray opacity can be achieved without using fillers.
摘要翻译：根据式I的碘取代苯甲酸的X-射线不透明酯或酰胺和由其制备的聚合物和牙科材料。式I R1 =氢或C1至C3烷基，优选H或CH3; R2 =直链或支链C1至C6亚烷基，氧化烯或亚芳基，优选C2至C4亚烷基，特别优选-CH2-CH2-和-CH2CH（ - ）CH2-; X = O或NH，优选O; R3-R7 =至少3个碘取代基，优选在R3，R4和R6或R3，R5和R7位置，其他基团是氢，C1至C6烷基，C1至C6烷氧基，-Cl，-Br，-OH， -NH 2，-N（C 1至C 6烷基）2或-NH-CO-（C 1至C 6烷基），优选R 3，R 4和R 6为= I且R 5和R 7 = H，或R 3，R 5和R 7 = 和R 4和R 6 = -NH（COCH 3）; n = 1,2或3，优选1或2.根据本发明的苯甲酸酯和酰胺可以完全聚合或阴离子聚合，这些聚合物在通常的牙科单体中很好地溶解。由单体或聚合物生产的牙科材料的特征在于，X射线不透明组分共价键合到聚合物基体材料中，因此不能被洗掉。此外，可以在不使用填料的情况下实现优异的X射线不透明度。

82. 发明授权

US5432130A Opalescent glass 失效
标题翻译：乳白色玻璃
公开(公告)号：US5432130A
公开(公告)日：1995-07-11
申请号：US225719
申请日：1994-04-11
申请人： Volker Rheinberger , Wolfram Hoeland , Martin Frank
发明人： Volker Rheinberger , Wolfram Hoeland , Martin Frank
IPC分类号： A61K6/06 , C03C3/097 , C03C4/00 , C03C3/083
CPC分类号： C03C4/005 , A61K6/0005 , A61K6/0094 , A61K6/0215 , A61K6/0235 , A61K6/024 , A61K6/025 , A61K6/0276 , C03C3/097
摘要： An opalescent glass is described which is characterized by a continuous glass phase and a discontinuous glass phase dispersed therein, and which can be used as dental material or as a constituent of dental materials.
摘要翻译：描述了一种乳白色玻璃，其特征在于连续玻璃相和分散在其中的不连续玻璃相，并且其可以用作牙科材料或作为牙科材料的成分。

83. 发明授权

US09320686B2 Dental materials based on compounds having debonding-on-demand properties 有权
公开(公告)号：US09320686B2
公开(公告)日：2016-04-26
申请号：US14343300
申请日：2012-09-10
申请人： Norbert Moszner , Thomas Hirt , Kai Rist , Ulrich Salz , Christoph Weder , Gina Fiore , Christian Heinzmann , Volker Rheinberger
发明人： Norbert Moszner , Thomas Hirt , Kai Rist , Ulrich Salz , Christoph Weder , Gina Fiore , Christian Heinzmann , Volker Rheinberger
IPC分类号： A61K6/083 , A61C7/00 , A61K6/00 , C07D239/47 , C07F3/06 , C08F122/22
CPC分类号： A61K6/0835 , A61K6/0002 , A61K6/0023 , A61K6/083 , C07D239/47 , C07F3/06 , C08F122/22 , C08L33/00
摘要： The invention relates to a dental restorative material which comprises a thermolabile compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]l Formula I, in which T represents a thermolabile unit which contains at least one thermolabile group based on non-covalent interactions, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2═CR1—CO—O— and CH2═CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing or represent —O—, —S—, CO—O—, —O—CO—, —CO—NR3— or —NR3—CO—, R, R1, R2 and R3 in each case independently represent H or a C1-C7 alkyl radical, k and l in each case independently are 0, 1, 2 or 3 and m and n in each case independently are 1, 2 or 3.

84. 发明授权

US08436070B2 Pasty polymerizable dental compounds and method for producing the same 有权
标题翻译：可口合成牙科用化合物及其制造方法
公开(公告)号：US08436070B2
公开(公告)日：2013-05-07
申请号：US12310185
申请日：2009-06-30
申请人： Volker Rheinberger , Axel Kammann
发明人： Volker Rheinberger , Axel Kammann
IPC分类号： C08F2/46 , C08L81/06
摘要： The present invention relates to a material for dental products comprising a mixture of at least one polymerizable monomer and at least one polymer based on polysulfones which is preswollen in a portion of the polymerizable monomer.
摘要翻译：本发明涉及一种用于牙科用品的材料，其包含至少一种可聚合单体和至少一种基于聚砜的聚合物的混合物，该聚合物在可聚合单体的一部分中被预溶胀。

85. 发明授权

US07851515B2 Hydrolysis-stable self-etching single-component dental adhesive 有权
标题翻译：水解稳定自腐蚀单组份牙科粘合剂
公开(公告)号：US07851515B2
公开(公告)日：2010-12-14
申请号：US11212065
申请日：2005-08-25
申请人： Ulrich Salz , Angela Mucke , Jorg Zimmermann , Norbert Moszner , Frank Zeuner , Volker Rheinberger
发明人： Ulrich Salz , Angela Mucke , Jorg Zimmermann , Norbert Moszner , Frank Zeuner , Volker Rheinberger
IPC分类号： C07F9/06 , C07F9/113 , C07F9/143 , A61K6/083 , A61K6/08 , A61K6/00 , A61C5/00 , C08F20/58 , C08F220/54
CPC分类号： A61K6/083 , A61K6/0017 , A61K6/0023 , A61K6/0835 , C08L33/00
摘要： Dental composition containing (i) at least one acid (meth)acrylamide monomer which has two or more polymerizable groups, (ii) at least one acid monomer which has only one polymerizable group and (iii) at least one polymerization initiator.
摘要翻译：含有（i）至少一种具有两个或多个可聚合基团的酸（甲基）丙烯酰胺单体，（ii）至少一种仅具有一个可聚合基团的酸单体和（iii）至少一种聚合引发剂）的牙科组合物。

86. 发明授权

US07553881B2 Dental materials based on radically polymerizable macromers with antimicrobial effect 有权
标题翻译：基于可自由基聚合的大分子单体的牙科材料具有抗菌作用
公开(公告)号：US07553881B2
公开(公告)日：2009-06-30
申请号：US11502420
申请日：2006-08-11
申请人： Ulrich Salz , Jörg Zimmermann , Dirk Poppe , Volker Rheinberger , Jörg Tiller , Christian Waschinski
发明人： Ulrich Salz , Jörg Zimmermann , Dirk Poppe , Volker Rheinberger , Jörg Tiller , Christian Waschinski
IPC分类号： A61K6/083 , C08F26/06
CPC分类号： A61K6/0017 , A61K6/0023 , A61K6/083 , A61K6/09 , C08L33/00 , C08L75/16
摘要： Dental material which contains at least one compound of the formula [PG]m—R1—Z—SP—Y—R2—[WG]p, in which m=1, 2 or 3; p=1, 2 or 3; R1=is absent, a linear or branched C1 to C20 alkylene radical which can be interrupted one or more times by O, S, NH, SiR′, CONH CONR′, COO and/or OCONH, a substituted or unsubstituted, aromatic C6 to C14 radical or a combination thereof R2=is absent, a linear or branched C1 to C20 alkylene radical which can be interrupted one or more times by O, S, NH, SiR′, CONH CONR′, COO and/or OCONH, a substituted or unsubstituted, aromatic C6 to C14 radical or a combination thereof; PG=a radically polymerizable group; SP=a polymeric spacer which is selected from polyethylene glycol, polypropylene glycol, polyglycerol, polyalkyloxazoline, polyethyleneimine, polyacrylic acid, polymethacrylic acid, polyvinyl alcohol, polyvinyl acetate, poly-(2-hydroxyethyl)acrylate, poly-(2-hydroxyethyl)methacrylate groups, hydrophilic polypeptide groups and copolymers of the corresponding monomers; WG=antimicrobially active group; Z=is absent, O, S, an ester, amide or urethane group; Y=is absent, O, S, an ester, amide or urethane group, and which has a molecular weight of at least 1,000.
摘要翻译：含有至少一种式[PG] m -R1-Z-SP-Y-R2- [WG] p化合物的牙科材料，其中m = 1,2或3; p = 1,2或3; R 1 =不存在，可被O，S，NH，SiR'，CONH CONR'，COO和/或OCONH间隔一次或多次的直链或支链C1至C20亚烷基，取代或未取代的芳族C6至 C 14基团或其组合，R 2 =不存在，可被O，S，NH，SiR'，CONH CONR'，COO和/或OCONH间隔一次或多次的直链或支链C 1至C 20亚烷基，或未取代的芳族C 6至C 14基团或其组合; PG =自由基聚合性基团; SP =选自聚乙二醇，聚丙二醇，聚甘油，聚烷基恶唑啉，聚乙烯亚胺，聚丙烯酸，聚甲基丙烯酸，聚乙烯醇，聚乙酸乙烯酯，聚（2-羟乙基）丙烯酸酯，聚（2-羟乙基）甲基丙烯酸酯基团，亲水性多肽基团和相应单体的共聚物; WG =抗微生物活性组; Z =不存在，O，S，酯，酰胺或氨基甲酸酯基; Y =不存在，O，S，酯，酰胺或氨基甲酸酯基，其分子量至少为1,000。

87. 发明申请

US20090136901A1 Method and System for Preparing Dental Restorations 有权
标题翻译：牙齿修复准备方法与系统
公开(公告)号：US20090136901A1
公开(公告)日：2009-05-28
申请号：US12055818
申请日：2008-03-26
申请人： Vittorio Cadario , Harald Burke , Marcel Schweiger , Volker Rheinberger
发明人： Vittorio Cadario , Harald Burke , Marcel Schweiger , Volker Rheinberger
IPC分类号： A61C13/08
CPC分类号： A61C13/0022 , A61C13/082 , A61C13/206
摘要： The present invention relates to a method and a system for preparing dental restorations from ceramic or polymeric material to achieve color and opacity gradients simulating natural dentition, wherein an ingot of ceramic or polymeric material is entirely or partially forced through a system of channels in a press mold into a mold cavity in the press mold, wherein the mold cavity corresponds to a dental restoration.
摘要翻译：本发明涉及一种用于从陶瓷或聚合材料制备牙科修复体以实现模拟天然牙列的颜色和不透明度梯度的方法和系统，其中陶瓷或聚合材料的锭完全或部分地被迫通过压机中的通道系统模具成型在模具中的模腔中，其中模腔对应于牙修复体。

88. 发明申请

US20080319104A1 Hardening Dental Materials Featuring Adjustable Translucence 审中-公开
标题翻译：硬化牙科材料具有可调节的半透明度
公开(公告)号：US20080319104A1
公开(公告)日：2008-12-25
申请号：US11547939
申请日：2005-04-06
申请人： Simone Klapdohr , Norbert Moszner , Karin Vogel , Volker Rheinberger , Peter Burtscher
发明人： Simone Klapdohr , Norbert Moszner , Karin Vogel , Volker Rheinberger , Peter Burtscher
IPC分类号： A61K6/08
CPC分类号： A61K6/0023 , A61K6/0005 , A61K6/083 , C08L33/00
摘要： The present invention relates to a curable dental material having adjustable translucence and high opalescence containing I. at least one monomer or one monomer mixture having a refractive index of
摘要翻译：本发明涉及一种具有可调节的半透明度和高乳光性的可固化牙科材料，其含有I至少一种单体或一种具有折射率<1.45的单体混合物，II。至少一种乳白色填料的折射率<1.45，III。进一步的常规填料或填料混合物和IV。聚合引发剂，稳定剂，染料或这些物质中的一种或多种的混合物。

89. 发明授权

US07101942B2 Dental materials based on metal oxide clusters 有权
标题翻译：基于金属氧化物簇的牙科材料
公开(公告)号：US07101942B2
公开(公告)日：2006-09-05
申请号：US10053460
申请日：2002-01-18
申请人： Norbert Moszner , Thomas Völkel , Volker Rheinberger , Ulrich Schubert
发明人： Norbert Moszner , Thomas Völkel , Volker Rheinberger , Ulrich Schubert
IPC分类号： C08F30/04
CPC分类号： A61K6/083 , A61K6/0017 , A61K6/0023 , C08L33/00
摘要： Dental material containing a cluster according to the general formula [(M1)a(M2)bOc(OH)d(OR)e(L-Sp-Z)f] (I) in which M1, M2, independently of each other, stand in each case for a metal atom of the IIIrd or Vth main groups or the Ist to VIIIth sub-groups of the periodic table; R is an alkyl group with 1 to 6 carbon atoms; L is a co-ordinating group with 2 to 6 complexing centres; Sp is a spacer group or is absent; Z is a polymerizable group; c is a number from 1 to 30; d, e, independently of each other, are in each case a number from 1 to 30; f is a number from 2 to 30, any charge of the cluster (I) present being equalized by counterions.
摘要翻译：含有根据通式[（M 1））的簇的牙科材料[（M 2））B O （OH）n（OR）e（L-Sp-Z）F（ⅰ）在（ⅰ）中其中M 1，M 2，2彼此独立地代表IIIrd或Vth主族或第I至VIII族的金属原子周期表; R是具有1至6个碳原子的烷基; L是一个有2到6个络心中心的协调小组; Sp是间隔基团或不存在; Z是可聚合基团; c是从1到30的数字; d，e彼此独立地在每种情况下为1至30的数; f是从2到30的数字，存在的群集（I）的任何费用由抵抗衡平衡。

90. 发明申请

US20060135719A1 Self-etching dental materials based on (METH) acrylamide phosphates 有权
标题翻译：基于（METH）丙烯酰胺磷酸盐的自蚀牙科材料
公开(公告)号：US20060135719A1
公开(公告)日：2006-06-22
申请号：US11211938
申请日：2005-08-25
申请人： Norbert Moszner , Iris Lamparth , Frank Zeuner , Ulrich Salz , Angela Mucke , Jorg Zimmermann , Jorg Angermann , Volker Rheinberger
发明人： Norbert Moszner , Iris Lamparth , Frank Zeuner , Ulrich Salz , Angela Mucke , Jorg Zimmermann , Jorg Angermann , Volker Rheinberger
IPC分类号： C08F120/54
CPC分类号： A61K6/0017 , A61K6/0023 , A61K6/0029 , A61K6/083 , A61K6/09 , C08L33/26 , C08L33/04 , C08L75/04
摘要： Polymerizable dental material, characterized in that it contains at least one (meth)acrylamide phosphate of the following general formula (I): in which R1 is H or CH3; R2 is H or a C1-C4 alkyl radical or forms together with the nitrogen atom to which it is bonded and one or more atoms which belong to R3 or R3′ a heterocyclic ring; R3, R3′ independently of each other are a linear or branched aliphatic C1-C50 radical with a valency of m+n or p+n, an aromatic C6-C18 radical with a valency of m+n or p+n, or a cycloaliphatic, araliphatic or heterocyclic C3-C18 radical with a valency of m+n or p+n, wherein the carbon chains of the radical or radicals can be interrupted by O, S, CONR4, OCONH, or form together with one or more atoms which belong to R2 and the nitrogen atom, to which the R2 is bonded a heterocyclic ring, R3′ being H if p=0, and R4 being H, C1-C10 alkyl, C6-C12 aryl, C6-C10 aralkyl or a bicylic C4-C12 radical; n is 1, 2, 3 or 4 if p=0, and is 1 or 2 if p≠0; m is 1, 2, 3 or 4; p is 0, 1, 2, 3 or 4; x is 0 or S.
摘要翻译：可聚合的牙科材料，其特征在于它含有至少一种下列通式（I）的（甲基）丙烯酰胺磷酸酯：其中R 1是H或CH 3; R 2是H或C 1 -C 4烷基，或与其键合的氮原子一起形成一个或多个属于R 3或R 3'杂原子的杂原子; R 3，R 3，R 3'彼此独立地是直链或支链的脂族C 1 -C 50 - 基团具有m + n或p + n的化合价，m + n或p + n的芳族C 6 -C 18 - 基团，或脂环族基团，芳烷基或杂环C 3 -C 18 - 基团，其价态为m + n或p + n，其中基团或基团的碳链可以被O， S，CONR 4，OCONH，或与一个或多个属于R 2的原子和氮原子一起形成，R 2 O 2 >键合杂环，如果p = 0，则R 3'为H，R 4为H，C 1 -C 3 C 10 -C 12烷基，C 6 -C 12芳基，C 6 -C 10芳烷基或C 6 -C 12烷基二元C 4 -C 12 - 基团; 如果p = 0，则n为1,2,3或4，如果p <0，则为1或2; m为1,2,3或4; p是0，1，2，3或4; x是0或S.

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