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    • 81. 发明授权
    • Apparatus for measuring total surface area of a portion of catalytic
metal particles
    • 用于测量一部分催化金属颗粒的总表面积的装置
    • US5908993A
    • 1999-06-01
    • US898816
    • 1997-07-23
    • Shinichi TakeshimaToshiaki Tanaka
    • Shinichi TakeshimaToshiaki Tanaka
    • B01J32/00G01N15/08G01N15/00
    • G01N15/0893
    • According to the present invention, there is provided an apparatus for measuring total surface area of a portion of catalytic metal particles carried on the surfaces of pores in a carrier of a catalyst, comprising a device for supplying the pores with a first gas under a predetermined pressure to mask the surfaces of the catalytic metal particles carried on a first portion of the surfaces of said pores, which first portion has a radius less than a radius determined by the predetermined pressure of said first gas and a device for supplying said pores with a second gas which is to be adsorbed on the surfaces of said catalytic metal particles carried on a second portion of the surfaces of said pores, which second portion has a radius equal to or greater than the radius determined by the predetermined pressure, and is not masked by said first gas. Also included is a processor for calculating total surface area of said catalytic metal particles carried on said second portion of the surfaces of said pores by an amount which is adsorbed on said surfaces of said catalytic metal particles.
    • 根据本发明,提供了一种用于测量承载在催化剂载体的孔表面上的一部分催化金属颗粒的总表面积的装置,包括用于在预定的温度下向第一气体供应孔的装置 所述第一部分具有小于由所述第一气体的预定压力确定的半径的半径的载体,所述第一部分的所述孔的第一部分上承载的催化金属颗粒的表面的压力和用于向所述孔提供 第二气体被吸附在所述催化金属颗粒的表面上,所述表面承载在所述孔的表面的第二部分上,该第二部分具有等于或大于由预定压力确定的半径的半径,并且不被掩蔽 通过所述第一气体。 还包括一种处理器,用于计算在所述孔的所述第二部分表面上承载的所述催化金属颗粒的总表面积,该表面积被吸附在所述催化金属颗粒的所述表面上的量。
    • 89. 发明授权
    • Method of saccharification and separation for plant fiber materials
    • 植物纤维材料糖化分离方法
    • US08486197B2
    • 2013-07-16
    • US12674427
    • 2008-08-29
    • Shinichi TakeshimaTakeshi Kikuchi
    • Shinichi TakeshimaTakeshi Kikuchi
    • C13K1/02
    • C13K1/02
    • A method of saccharification and separation for plant fiber materials is provided. The method includes hydrolyzing cellulose contained in the plant fiber materials using a cluster acid catalyst in a pseudo-molten state to produce saccharide. The method further includes a first separation step of separating a mixture containing an aqueous saccharide solution in which at least a portion of the saccharide produced is dissolved, a cluster acid organic solvent solution, and residues into a solid content containing the residues and a liquid content containing the aqueous saccharide solution and the cluster acid catalyst solvent solution. The method further includes a second separation step of dehydrating the liquid content by a dehydration means capable of absorbing water through chemical absorption to deposit the saccharide in the aqueous saccharide solution, and separating a solid content containing the saccharide from a liquid content containing the cluster acid catalyst and the organic solvent.
    • 提供了一种用于植物纤维材料的糖化和分离的方法。 该方法包括使用模拟熔融状态的簇酸催化剂水解包含在植物纤维材料中的纤维素以产生糖。 所述方法还包括第一分离步骤,其将含有至少一部分所生成的糖的糖水溶液,簇酸有机溶剂溶液和残留物的混合物分离成含有残留物和液体含量的固体含量 含有糖水溶液和簇酸催化剂溶剂溶液。 该方法还包括第二分离步骤,其通过能够通过化学吸收吸收水分的脱水装置使所述液体含量脱水以将糖沉积在糖水溶液中,并将含有糖的固体含量与含有所述聚集酸的液体含量分离 催化剂和有机溶剂。
    • 90. 发明授权
    • Method for glycosylating and separating plant fiber material
    • 糖基化和分离植物纤维材料的方法
    • US08460472B2
    • 2013-06-11
    • US12995809
    • 2009-06-02
    • Shinichi TakeshimaTakeshi Kikuchi
    • Shinichi TakeshimaTakeshi Kikuchi
    • C13K1/02
    • C13K1/02
    • The invention relates to a method for hydrolyzing a plant fiber material and producing and separating a saccharide including glucose. The method of the invention includes a hydrolysis process of using a cluster acid catalyst in a pseudo-molten state to hydrolyze cellulose contained in the plant fiber material and produce glucose. In the hydrolysis process, the cluster acid catalyst and a first amount of the plant fiber material that increases a viscosity of the cluster acid catalyst in a pseudo-molten state when added to the cluster acid catalyst in a pseudo-molten state are heated and mixed, and a second amount of the plant fiber material is then further added when the decrease in viscosity of the heated mixture occurs.
    • 本发明涉及水解植物纤维材料并生产和分离包括葡萄糖的糖类的方法。 本发明的方法包括使用假熔融状态的簇酸催化剂水解纤维素中所含的纤维素并产生葡萄糖的水解方法。 在水解过程中,将加入到熔融状态的聚氨酯催化剂中的模拟熔融状态下的聚氨酯酸催化剂的粘度增加的簇酸催化剂和第一量的植物纤维材料加热混合 然后当加热的混合物的粘度降低时,进一步添加第二量的植物纤维材料。