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    • 82. 发明授权
    • Electrophotographic photoreceptor
    • 电子照相机
    • US5073467A
    • 1991-12-17
    • US420505
    • 1989-10-11
    • Eiichi KatoKazuo Ishii
    • Eiichi KatoKazuo Ishii
    • G03G5/05
    • G03G5/0589G03G5/0592
    • An electrophotographic photoreceptor comprising a support having provided thereon at least one photoconductive layer containing at least inorganic photoconductive particles and a binder resin, wherein the binder resin comprises(A) at least one resin having a weight average molecular weight of from 1.times.10.sup.3 to 2.times.10.sup.4 with at least one substituent selected from the group consisting of (i) --PO.sub.3 H.sub.2, (ii) --SO.sub.3 H, (iii) --COOH, (iv) ##STR1## and (B) at least one copolymer resin comprising a monofunctional macromonomer and a monomer, said monofunctional macromonomer having a weight average molecular weight of not more than 2.times.10.sup.4, said macromonomer containing at least one polymerization component represented by formula (b-2) or (b-3): ##STR2## with a polymerizable double bond-containing group represented by formula (b-1) being bonded to only one of terminals of the main chain thereof, ##STR3## and said monomer is represented by formula (b-4): ##STR4## The photoreceptor exhibits excellent electrostatic characteristics, image formation as well as printing suitability irrespective of variations in environmental conditions or the kind of sensitizing dyes used in combination with the photoreceptor.
    • 85. 发明授权
    • Liquid developer for electrostatic photography
    • 静电摄影用液体显影剂
    • US5041352A
    • 1991-08-20
    • US473535
    • 1990-02-01
    • Eiichi KatoKazuo IshiiHideyuki Hattori
    • Eiichi KatoKazuo IshiiHideyuki Hattori
    • G03G9/13
    • G03G9/131G03G9/133
    • A liquid developer for electrostatic photography comprising a resin dispersed in a non-aqueous solvent having an electric resistance of at least 10.sup.9 .OMEGA.cm and a dielectric constant of not higher than 3.5, wherein the dispersed resin is a polymer resin obtained by polymerizing a solution containing at least one monofunctional monomer (A) which is soluble in the aforesaid non-aqueous solvent but become insoluble after being polymerized, in the presence of a dispersion-stabilizing resin which is soluble in the aforesaid non-aqueous solvent and at least one oligomer (B) having a number average molecular weight of not more than 1.times.10.sup.4 and having at least one polar group selected from a carboxy group, a sulfo group, a hydroxy group, a formyl group, an amino group, a phosphono group, and ##STR1## wherein R.sup.0 represents a hydrocarbon group or --OR.sup.1, (wherein R.sup.1 represents a hydrocarbon group) bonded to only one terminal of the main chain of a polymer composed of a recurring unit represented by following formula (II): ##STR2## wherein V.sup.1, R.sup.2, a.sup.1 and a.sup.2 are as defined in the specification. The liquid developer is excellent in dispersion stability, re-dispersibility, and fixability, and also is capable of forming an offset printing plate having excellent ink-receptivitiy for printing ink and excellent printing durability by electrophotography.
    • 一种用于静电照相的液体显影剂,其包含分散在电阻至少为10 9Ω·cm,介电常数不高于3.5的非水溶剂中的树脂,其中所述分散树脂是通过聚合含有 至少一种在可溶于上述非水溶剂的分散稳定树脂和至少一种低聚物的存在下,其可溶于前述非水溶剂但在聚合后变得不溶的单官能单体(A) B)数均分子量不大于1×10 4,并且具有至少一个选自羧基,磺基,羟基,甲酰基,氨基,膦酰基的极性基团, 其中R 0表示烃基或-OR 1(其中R 1表示烃基),其仅与由以重复单元表示的重复单元组成的聚合物的主链的仅一个末端键合 下式(II):其中V1,R2,a1和a2如说明书中所定义。 液体显影剂的分散稳定性,再分散性和定影性优异,并且还能够形成具有优异的用于印刷油墨的油墨接受性和通过电子照相术获得优异印刷耐久性的胶版印刷版。
    • 88. 发明授权
    • Liquid developer for electrostatic photography
    • US4618557A
    • 1986-10-21
    • US763112
    • 1985-08-07
    • Shigeyuki DanKazuo IshiiEiichi KatoHidefumi Sera
    • Shigeyuki DanKazuo IshiiEiichi KatoHidefumi Sera
    • G03G9/12G03G9/13
    • G03G9/131
    • An liquid developer for electrostatic photography is described, comprising a carrier liquid having an electric resistance of at least 10.sup.9 .OMEGA..multidot.cm and a dielectric constant of not more than 3.5, and a resin dispersed therein, said resin being obtained by polymerizing a monomer, which is soluble in said carrier liquid but becomes insoluble upon being polymerized, in the presence of at least one kind of a soluble dispersion stabilizing resin, said soluble dispersion stabilizing resin being a copolymer containing at least recurring units represented by following formulae (IIIa) and (IIIb) obtained by applying a reaction for introducing an unsaturated bond into a copolymer obtained by polymerizing a monomer represented by formula (I) and a monomer represented by formula (III) ##STR1## wherein in formula (I), V represents --O--, --S--, --CO--, --CO.sub.2 --, --SO.sub.2 --, --OCO--, --CONH--, --CONR'-- (wherein R' represents a hydrocarbon group), --NHCO--, NHCO.sub.2 --, or --NHCONH--; X represents --CO.sub.2 H, --COCl, --OH, --SH, --NH.sub.2, --NCO, or --SO.sub.2 CH.sub.2 CH.sub.2 Cl; W represents a hydrocarbon group linking said atomic group V and said atomic group X directly or through a hetero atom, or W represents a chemical bond; and a.sub.1, a.sub.2, and a.sub.3 each represents a hydrogen atom, a hydrocarbon group, a carboxy group, or a carboxy group through a hydrocarbon group;in formula (II), Y represents --O--, --S--, --CO--, --CO.sub.2 --, --SO.sub.2 --, --OCO--, CONH--, --CONR"-- (wherein R" represents a hydrocarbon group), --NHCO--, --NHCO.sub.2 --, or --NHCONH--; R represents a hydrocarbon group; and b.sub.1, b.sub.2, and b.sub.3 each represents a hydrocarbon atom, a hydrocarbon group, a carboxy group, or a carboxy group through a hydrocarbon group;in formula (IIIa), a.sub.1, a.sub.2, a.sub.3, V, and W have the same meanings as defined for formula (I); X' represents --CO.sub.2 --, --COS--, --SCO--, --CONH--, --OCO--, --NHCO--, --NHCONH--, --SO.sub.2 --, --O--, or --S--; Z represents a hydrocarbon group linking said atomic group X' and unsaturated bond directly or through a hetero atom, or Z represents a chemical bond; the total number of atoms of the main chain portion of atomic group --V--W--X'--Z-- must, however, be at least 9; and d.sub.1, d.sub.2, and d.sub.3 each represents a hydrocarbon atom, a hydrocarbon group, a carboxy group, or a carboxy group through a hydrocarbon group; andin formula (IIIb), b.sub.1, b.sub.2, b.sub.3, Y, and R have the same meanings as defined for formula (II).