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    • 89. 发明授权
    • Fluorochemical composition and method of treatment of a substrate therewith to render substrate oil- and/or water repellent
    • 含氟化合物组合物及其基质的处理方法以使底物具有油和/或拒水性
    • US07470741B2
    • 2008-12-30
    • US10444879
    • 2003-05-23
    • Rudolf J. Dams
    • Rudolf J. Dams
    • C08K3/00
    • D06M15/277C03C17/28C03C17/30C08F8/42C08K5/54C09D133/16C09D143/04D06M2200/11C08F14/18C08L33/16C08L2666/44
    • The present invention provides a fluorochemical composition comprising: (a) one or more fluorochemical oligomers derivable from a free radical polymerization of one or more fluorinated monomers and optionally one or more non-fluorinated monomers in the presence of a chain transfer agent, said fluorochemical oligomer being free of acid groups and comprising one or more groups of the formula: -M1(R)q(Y)p−q−1  (I) wherein M1 is selected from the group consisting of Si, Ti, Zr, B, Al, Ge, V, Pb, Sn and Zn, R represents a non-hydrolysable group, Y represents a hydrolysable group, q is 0, 1 or 2, p equals the valence of M1 and is 3 or 4 and p−q−1 is at least 1; (b) one or more non-fluorinated compounds of an element M2 selected from the group consisting of Si, Ti, Zr, B, Al, Ge, V, Pb, Sn and Zn and having at least two hydrolysable groups per molecule in an amount sufficient to form a polycondensation product upon reaction with said fluorochemical oligomer (a); (c) water; and (d) an organic solvent in an amount sufficient to dissolve and/or disperse components (a), (b) and (c). The invention also provides compositions comprising condensates of components (a) and (b) of the above composition and a method of treatment of substrates therewith.
    • 本发明提供一种含氟化合物组合物,其包含:(a)一种或多种衍生自一种或多种氟化单体和任选的一种或多种非氟化单体在链转移剂存在下的自由基聚合的含氟低聚物,所述含氟低聚物 没有酸基并且包含一个或多个下式的基团:<?in-line-formula description =“In-line Formulas”end =“lead”→M1(R)q(Y)pq-1( 其中M1选自Si,Ti,Zr,B,Al,Ge,V,Pb,Sn中的一种。 和Zn,R表示不可水解基团,Y表示可水解基团,q表示0,1或2,p表示M1的化合价,为3或4,pq-1为至少1; (b)一种或多种选自Si,Ti,Zr,B,Al,Ge,V,Pb,Sn和Zn的元素M2的非氟化化合物,并且在每个分子中具有至少两个可水解基团 足以在与所述含氟低聚物(a)反应时形成缩聚产物; (c)水; 和(d)足以溶解和/或分散组分(a),(b)和(c)的量的有机溶剂。 本发明还提供了包含上述组合物的组分(a)和(b)的缩合物的组合物和其处理底物的方法。