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    • 84. 发明授权
    • Treatment fluids containing biodegradable chelating agents and methods for use thereof
    • 含有可生物降解的螯合剂的处理液及其使用方法
    • US09120964B2
    • 2015-09-01
    • US13094248
    • 2011-04-26
    • Enrique A. ReyesThomas D. Welton
    • Enrique A. ReyesThomas D. Welton
    • C09K8/528C02F5/12C09K8/68C09K8/74C09K8/78C09K8/84C09K8/86
    • C09K8/528C02F5/12C09K8/68C09K8/74C09K8/78C09K8/845C09K8/86Y02W10/37
    • Treatment fluids containing biodegradable chelating agents can be used in various treatment methods. The methods can comprise providing a treatment fluid that comprises an aqueous base fluid and a chelating agent composition, and introducing the treatment fluid into at least a portion of a subterranean formation. The treatment fluids can also be used for treatment of pipes or tubing such as, for example, well bore pipes or tubing penetrating a subterranean formation and above-ground pipelines. Illustrative biodegradable chelating agents include, but are not limited to, glutamic acid diacetic acid, methylglycine diacetic acid, β-alanine diacetic acid, S,S-ethylenediaminedisuccinic acid, iminodisuccinic acid, hydroxyiminodisuccinic acid, any salt thereof, any derivative thereof, and any combination thereof. The treatment fluids can optionally comprise an acid, which can include hydrofluoric acid or a hydrofluoric acid generating compound.
    • 含有可生物降解的螯合剂的处理液可用于各种处理方法中。 所述方法可以包括提供包含含水基础流体和螯合剂组合物的处理流体,并将处理流体引入至地下地层的至少一部分中。 处理流体还可以用于管道或管道的处理,例如井眼管道或穿透地下地层和地上管道的管道。 示例性可生物降解螯合剂包括但不限于谷氨酸二乙酸,甲基甘氨酸二乙酸,β-丙氨酸二乙酸,S,S-乙二胺二琥珀酸,亚氨基二琥珀酸,羟基亚氨基二琥珀酸,其任何盐,其任何衍生物,和 其任何组合。 处理流体可以任选地包含酸,其可以包括氢氟酸或产生氢氟酸的化合物。
    • 85. 发明授权
    • Increasing fracture complexity in ultra-low permeable subterranean formation using degradable particulate
    • 使用可降解颗粒增加超低渗透地层的裂缝复杂性
    • US08853137B2
    • 2014-10-07
    • US13017611
    • 2011-01-31
    • Bradley L. ToddThomas D. Welton
    • Bradley L. ToddThomas D. Welton
    • C09K8/60C09K8/68E21B43/267E21B43/26C09K8/80C09K8/516C09K8/92C09K8/03C09K8/536C09K8/72
    • C09K8/03C09K8/516C09K8/536C09K8/72C09K8/80C09K8/92E21B43/267Y10S507/922Y10S507/924
    • A method of increasing the fracture complexity in a treatment zone of a subterranean formation is provided. The subterranean formation is characterized by having a matrix permeability less than 1.0 microDarcy. The method includes the step of pumping one or more fracturing fluids into a far-field region of a treatment zone of the subterranean formation at a rate and pressure above the fracture pressure of the treatment zone. A first fracturing fluid of the one or more fracturing fluids includes a first solid particulate, wherein: (a) the first solid particulate includes a particle size distribution for bridging the pore throats of a proppant pack previously formed or to be formed in the treatment zone; and (b) the first solid particulate comprises a degradable material. In an embodiment, the first solid particulate is in an insufficient amount in the first fracturing fluid to increase the packed volume fraction of any region of the proppant pack to greater than 73%. Similar methods using stepwise fracturing fluids and remedial fracturing treatments are provided.
    • 提供了一种增加地下地层处理区的断裂复杂性的方法。 地层的特征在于具有小于1.0微加仑的基质渗透性。 该方法包括以高于处理区的断裂压力的速率和压力将一个或多个压裂流体泵送到地层的处理区的远场区域的步骤。 一个或多个压裂流体的第一压裂流体包括第一固体颗粒,其中:(a)第一固体颗粒包括用于桥接预先形成或将要在处理区中形成的支撑剂组的孔喉的粒度分布 ; 和(b)第一固体颗粒包含可降解材料。 在一个实施方案中,第一固体颗粒在第一压裂流体中的量不足以将支撑剂组的任何区域的填充体积分数增加至大于73%。 提供了使用逐步压裂流体和补救压裂处理的类似方法。
    • 88. 发明授权
    • Carboxylic acid and oxidizer clean-up compositions and associated methods of use in subterranean applications
    • 羧酸和氧化剂清除组合物及其在地下应用中的相关方法
    • US08470747B2
    • 2013-06-25
    • US12254307
    • 2008-10-20
    • Thomas D. WeltonRichard W. PaulsJeff T. Fleming
    • Thomas D. WeltonRichard W. PaulsJeff T. Fleming
    • C09K8/52
    • C09K8/68C09K8/524C09K8/56C09K8/685C09K2208/26
    • Of the many methods provided herein, one method of reducing the viscosity of a viscosified treatment fluid includes: providing a clean-up composition comprising a carboxylic acid; providing a chlorite-based breaker system; providing a viscosified treatment fluid; placing the viscosified treatment fluid in a subterranean formation via a well bore penetrating the subterranean formation; contacting the viscosified treatment fluid with the clean-up composition; contacting the viscosified treatment fluid with the chlorite-based breaker; and allowing the viscosity of the viscosified treatment fluid to reduce. Also provided herein are methods that include a method of reducing polymeric residue from a subterranean formation that includes: placing a clean-up composition and a chlorite-based breaker system in a subterranean formation in contact with an amount of polymeric residue; and allowing the amount of polymeric residue present in the formation to be reduced.
    • 在本文提供的许多方法中,降低稠化处理流体的粘度的一种方法包括:提供包含羧酸的清理组合物; 提供一种基于亚氯酸盐的断路器系统; 提供稠化处理液; 通过穿透地下地层的井眼将粘稠处理流体置于地下地层中; 使所述增稠处理流体与所述清理组合物接触; 使稠化处理液与亚氯酸盐类破碎剂接触; 并且允许粘稠处理液的粘度降低。 本文还提供了包括从地下地层中还原聚合物残余物的方法的方法,其包括:将清理组合物和基于亚氯酸盐的破碎剂体系放置在与一定量的聚合物残留物接触的地层中; 并且允许存在于地层中的聚合物残余物的量减少。