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81. 发明授权

US08426659B2 Vinyl terminated higher olefin polymers and methods to produce thereof 有权
标题翻译：乙烯基封端的较高级烯烃聚合物及其生产方法
公开(公告)号：US08426659B2
公开(公告)日：2013-04-23
申请号：US13072288
申请日：2011-03-25
申请人： Matthew W. Holtcamp , Charles J. Ruff , Donna J. Crowther , John R. Hagadorn , Patrick Brant
发明人： Matthew W. Holtcamp , Charles J. Ruff , Donna J. Crowther , John R. Hagadorn , Patrick Brant
IPC分类号： C10M107/10 , C10M143/08
CPC分类号： C08F10/14 , C08F4/65908 , C08F4/65925 , C08F110/14 , C08F210/14 , C08F4/65927
摘要： This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by 1H NMR) including of one or more C4 to C40 higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.
摘要翻译：本发明涉及具有至少200g / mol（通过1 H NMR测量）的Mn的高级烯烃乙烯基封端聚合物，其包含一个或多个C 4至C 40高级烯烃衍生单元，其中高级烯烃乙烯基封端聚合物基本上不含丙烯单位; 并且其中所述较高级烯烃聚合物具有至少5％的烯丙基链末端及其生产方法。这些乙烯基封端的较高级烯烃聚合物可以任选地包括乙烯衍生的单元。

82. 发明授权

US08399724B2 Vinyl terminated higher olefin copolymers and methods to produce thereof 有权
标题翻译：乙烯基封端的较高级烯烃共聚物及其制备方法
公开(公告)号：US08399724B2
公开(公告)日：2013-03-19
申请号：US13072249
申请日：2011-03-25
申请人： Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
发明人： Donna J. Crowther , Matthew W. Holtcamp , John R. Hagadorn , Charles J. Ruff , George Rodriguez , Patrick Brant
IPC分类号： C08F210/06 , C08F210/14 , C08F4/6592 , C10M107/06
CPC分类号： C08F232/08 , C08F210/14 , Y10S526/943 , C08F210/06 , C08F2500/02
摘要： This invention relates to a vinyl terminated higher olefin copolymer having an Mn of 300 g/mol or more (measured by 1H NMR) comprising: (i) from about 20 to about 99.9 mol % of at least one C5 to C40 higher olefin monomer; and (ii) from about 0.1 to about 80 mol % of propylene; wherein the higher olefin copolymer has at least 40% allyl chain ends. The copolymer may also have an isobutyl chain end to allyl chain end ratio of less than 0.7:1 and/or an allyl chain end to vinylidene chain end ratio of greater than 2:1.
摘要翻译：本发明涉及Mn为300g / mol或更高（通过1 H NMR测量）的乙烯基封端的高级烯烃共聚物，其包含：（i）约20-约99.9mol％的至少一种C 5至C 40高级烯烃单体; 和（ii）约0.1至约80mol％的丙烯; 其中所述较高级烯烃共聚物具有至少40％的烯丙基链端。该共聚物也可以具有小于0.7:1的异丁基链端与烯丙基链末端比和/或烯丙基链端与亚乙烯基链末端比大于2:1。

83. 发明申请

US20130035442A1 ELASTIC PROPYLENE-ALPHA-OLEFIN COPOLYMER COMPOSITIONS AND PROCESSES TO PRODUCE THEM 有权
标题翻译：弹性丙烯-α-烯烃共聚物组合物及其生产方法
公开(公告)号：US20130035442A1
公开(公告)日：2013-02-07
申请号：US13198201
申请日：2011-08-04
申请人： Andy Haishung Tsou , Gabor Kiss , Robert Patrick Reynolds, JR. , John W. Chu , Alan Anthony Galuska , Patrick Brant , Donald Andrew Winesett
发明人： Andy Haishung Tsou , Gabor Kiss , Robert Patrick Reynolds, JR. , John W. Chu , Alan Anthony Galuska , Patrick Brant , Donald Andrew Winesett
IPC分类号： C08L53/00 , C08L23/12 , C08F2/01 , C08F299/00 , C08F210/18
CPC分类号： C08L23/10 , C08F4/65908 , C08L23/142 , C08L23/16 , C08F210/06 , C08F210/16 , C08F2500/12 , C08F2500/20 , C08F2500/21 , C08F4/65927
摘要： Provided are elastic propylene-alpha olefin blocky copolymers. In one form, the elastic propylene-alpha olefin blocky copolymer includes an α-olefin content from 12 to 25 wt % and having a propylene crystallinity less than 30 J/g, a Tm −45° C., wherein said copolymer has blocky propylene segments with r1r2 greater than 1.5, and a process for producing such copolymer.
摘要翻译：提供弹性丙烯-α烯烃嵌段共聚物。在一种形式中，弹性丙烯-α烯烃嵌段共聚物包括12至25重量％的α-烯烃含量，丙烯结晶度小于30J / g，Tm <100℃和Tg> -45℃ 其中所述共聚物具有r1r2大于1.5的嵌段丙烯链段，以及这种共聚物的制备方法。

84. 发明授权

US08338020B2 Multi-layer microporous film 有权
标题翻译：多层微孔膜
公开(公告)号：US08338020B2
公开(公告)日：2012-12-25
申请号：US13322647
申请日：2010-06-08
申请人： Takeshi Ishihara , Satoshi Miyaoka , Koichi Kono , Patrick Brant
发明人： Takeshi Ishihara , Satoshi Miyaoka , Koichi Kono , Patrick Brant
IPC分类号： H01M2/18
CPC分类号： H01M2/16 , B01D69/12 , B01D71/26 , B32B27/08 , B32B27/18 , B32B27/32 , B32B2250/242 , B32B2270/00 , B32B2307/30 , B32B2307/308 , B32B2307/50 , B32B2307/714 , B32B2307/724 , B32B2457/10 , H01M2/145 , H01M2/1686 , H01M10/0525 , Y02E60/12 , Y02T10/7011 , Y10T428/249978
摘要： Embodiments of the invention relate to microporous membranes that include first and second layers. The first layer includes ≦20.0 wt. % polymethylpentene and the second layer includes a compatibilizer. The invention also relates to methods for making such membranes and the use of such membranes as battery separator film.
摘要翻译：本发明的实施方案涉及包括第一和第二层的微孔膜。第一层包括＆nlE; 20.0wt。％的聚甲基戊烯，第二层包括增容剂。本发明还涉及制造这种膜的方法以及使用这种膜作为电池隔膜。

85. 发明申请

US20120245312A1 Vinyl Terminated Higher Olefin Polymers and Methods to Produce Thereof 有权
标题翻译：乙烯基终止的高级烯烃聚合物及其生产方法
公开(公告)号：US20120245312A1
公开(公告)日：2012-09-27
申请号：US13072288
申请日：2011-03-25
申请人： Matthew W. Holtcamp , Charles J. Ruff , Donna J. Crowther , John R. Hagadorn , Patrick Brant
发明人： Matthew W. Holtcamp , Charles J. Ruff , Donna J. Crowther , John R. Hagadorn , Patrick Brant
IPC分类号： C08F10/14 , C08F4/76
CPC分类号： C08F10/14 , C08F4/65908 , C08F4/65925 , C08F110/14 , C08F210/14 , C08F4/65927
摘要： This invention relates to higher olefin vinyl terminated polymers having an Mn of at least 200 g/mol (measured by 1H NMR) including of one or more C4 to C40 higher olefin derived units, where the higher olefin vinyl terminated polymer comprises substantially no propylene derived units; and wherein the higher olefin polymer has at least 5% allyl chain ends and processes for the production thereof. These vinyl terminated higher olefin polymers may optionally include ethylene derived units.
摘要翻译：本发明涉及具有至少200g / mol（通过1 H NMR测量）的Mn的高级烯烃乙烯基封端聚合物，其包含一个或多个C 4至C 40高级烯烃衍生单元，其中高级烯烃乙烯基封端聚合物基本上不含丙烯单位; 并且其中所述较高级烯烃聚合物具有至少5％的烯丙基链末端及其生产方法。这些乙烯基封端的较高级烯烃聚合物可以任选地包括乙烯衍生的单元。

86. 发明申请

US20120245276A1 Amine Functionalized Polyolefin and Methods for Preparation Thereof 有权
标题翻译：胺官能化聚烯烃及其制备方法
公开(公告)号：US20120245276A1
公开(公告)日：2012-09-27
申请号：US13072189
申请日：2011-03-25
申请人： John R. Hagadorn , Donna J. Crowther , Renuka N. Ganesh , Patrick Brant
发明人： John R. Hagadorn , Donna J. Crowther , Renuka N. Ganesh , Patrick Brant
IPC分类号： C08L39/00 , C08L23/36 , C08F8/32
CPC分类号： C08L23/10 , C08L23/36 , C08L51/06
摘要： This invention relates to a process to functionalize polyolefins comprising contacting a transition metal amide catalyst with an amine (preferably a secondary amine), and one or more vinyl terminated materials, preferably one or more vinyl terminated polyolefins. This invention further relates to the amine-functionalized polyolefins produced thereby.
摘要翻译：本发明涉及官能化聚烯烃的方法，包括使过渡金属酰胺催化剂与胺（优选仲胺）和一种或多种乙烯基封端的材料，优选一种或多种乙烯基封端的聚烯烃相接触。本发明还涉及由其制备的胺官能化的聚烯烃。

87. 发明申请

US20120088149A1 MICROPOROUS MEMBRANES, METHODS FOR MAKING SUCH MEMBRANES, AND THE USE OF SUCH MEMBRANES AS BATTERY SEPARATOR FILM 有权
标题翻译：微孔膜，制造这种膜的方法以及作为电池分离膜的这种膜的使用
公开(公告)号：US20120088149A1
公开(公告)日：2012-04-12
申请号：US13322631
申请日：2010-06-08
申请人： Takeshi Ishihara , Satoshi Miyaoka , Koichi Kono , Patrick Brant
发明人： Takeshi Ishihara , Satoshi Miyaoka , Koichi Kono , Patrick Brant
IPC分类号： H01M2/16 , H01M10/26 , B29C47/00
CPC分类号： H01M2/1653 , H01M2/145 , H01M2/1686 , H01M10/0525 , Y02T10/7011 , Y10T428/249978 , Y10T428/249993
摘要： The present invention relates to microporous membranes comprising polymer and having well-balanced permeability and heat shrinkage, especially heat shrinkage at elevated temperature. The invention also relates to methods for making such membranes, and the use of such membranes as battery separator film in, e.g., lithium ion secondary batteries.
摘要翻译：本发明涉及包含聚合物并且具有良好平衡的渗透性和热收缩性，特别是在升高的温度下的热收缩的微孔膜。本发明还涉及制造这种膜的方法，以及在例如锂离子二次电池中使用这种膜作为电池隔膜。

88. 发明授权

US08143352B2 Process for fluid phase in-line blending of polymers 有权
标题翻译：流体相在线共混聚合物的方法
公开(公告)号：US08143352B2
公开(公告)日：2012-03-27
申请号：US12002509
申请日：2007-12-17
申请人： Gabor Kiss , Patrick Brant , Robert Patrick Reynolds, Jr. , Robert Charles Portnoy , David B. Dunaway
发明人： Gabor Kiss , Patrick Brant , Robert Patrick Reynolds, Jr. , Robert Charles Portnoy , David B. Dunaway
IPC分类号： C08F2/04 , C08F2/06
CPC分类号： C08F10/06 , C08F210/06 , C08F2/00 , C08F2/01 , C08F2/06 , C08F210/14 , C08F2500/15 , C08F2500/12 , C08F2500/20 , C08F210/16 , C08F210/08
摘要： A process for fluid phase in-line blending of polymers. The process includes providing two or more reactor trains configured in parallel and a separator for product blending and product-feed separation; contacting in at least one of the parallel reactor trains olefin monomers having three or more carbon atoms, catalyst systems, optional comonomers, optional scavengers, and optional inert diluents or inert solvents, at a temperature above the solid-fluid phase transition temperature of the polymerization system and a pressure no lower than 10 MPa below the cloud point pressure of the polymerization system and less than 1500 MPa; forming a reactor effluent including a homogeneous fluid phase polymer-monomer mixture in each parallel reactor train; combining the reactor effluent from each parallel reactor; passing the combined reactor effluent through the separator; maintaining the temperature and pressure within the separator above the solid-fluid phase transition point but below the cloud point pressure and temperature to form a fluid-fluid two-phase system including a polymer-rich blend phase and a monomer-rich phase; and separating the monomer-rich phase from the polymer-rich blend phase. The separated monomer-rich phase is recycled to the polymerization reactor bank. The polymer-rich blend phase is conveyed to a downstream finishing stage for further monomer stripping, drying and/or pelletizing to form a polymer product blend.
摘要翻译：流体相在线共混聚合物的方法。该方法包括提供两个或更多个平行配置的反应器列和用于产物混合和产物进料分离的分离器; 在高于聚合物的固体 - 流体相转变温度的温度下，在至少一个平行的反应器列中具有三个或更多个碳原子的烯烃单体，催化剂体系，任选的共聚单体，任选的清除剂和任选的惰性稀释剂或惰性溶剂接触系统，低于聚合体系浊点压力10MPa以下的压力小于1500MPa; 在每个平行的反应器列中形成包含均相流体相聚合物 - 单体混合物的反应器流出物; 将来自每个平行反应器的反应器流出物混合; 将合并的反应器流出物通过分离器; 将分离器内的温度和压力保持在固体 - 流体相转变点之上但低于浊点压力和温度，以形成包括富含聚合物的共混相和富单体相的流体 - 流体两相系统; 并从富含聚合物的混合相中分离富含单体的相。将分离的富单体相再循环至聚合反应器组。将富含聚合物的共混相输送到下游整理阶段以进一步进行单体汽提，干燥和/或造粒以形成聚合物产物共混物。

89. 发明申请

US20120052362A1 THERMOPLASTIC FILM, METHODS FOR MAKING SUCH FILM, AND THE USE OF SUCH FILM AS BATTERY SEPARATOR FILM 审中-公开
标题翻译：热塑性薄膜，制造这种薄膜的方法以及作为电池分离膜的这种薄膜的使用
公开(公告)号：US20120052362A1
公开(公告)日：2012-03-01
申请号：US13264045
申请日：2010-04-07
申请人： Derek Thurman , Patrick Brant , Kazuhiro Yamada , Koichi Kono
发明人： Derek Thurman , Patrick Brant , Kazuhiro Yamada , Koichi Kono
IPC分类号： H01M2/16 , B32B27/32 , B29C70/18 , B32B5/02
CPC分类号： B32B5/22 , B32B5/022 , B32B5/26 , B32B7/12 , B32B27/08 , B32B27/12 , B32B27/18 , B32B27/302 , B32B27/306 , B32B27/308 , B32B27/32 , B32B2255/00 , B32B2255/20 , B32B2262/0253 , B32B2270/00 , B32B2307/30 , B32B2307/50 , B32B2307/54 , B32B2307/714 , B32B2307/724 , B32B2457/10 , H01M2/162 , H01M2/1653 , H01M2/1666 , H01M10/0525 , Y10T442/659 , Y10T442/674 , Y10T442/678
摘要： A thermoplastic film including a microporous polymeric membrane; and a non-woven web comprising a plurality of fibers, the web being bonded to the microporous polymeric membrane, wherein the fibers comprise oxidation-protective polymer having an MFR ≧2.0×102.
摘要翻译：包括微孔聚合物膜的热塑性膜; 以及包含多个纤维的无纺网，所述纤维网被结合到所述微孔聚合物膜上，其中所述纤维包含具有MFR≥2.0×102的氧化保护性聚合物。

90. 发明申请

US20120028131A1 MICROPOROUS MEMBRANES, METHODS FOR MAKING SUCH MEMBRANES, AND THE USE OF SUCH MEMBRANES AS BATTERY SEPARATOR FILM 有权
标题翻译：微孔膜，制造这种膜的方法以及作为电池分离膜的这种膜的使用
公开(公告)号：US20120028131A1
公开(公告)日：2012-02-02
申请号：US13260643
申请日：2010-03-05
申请人： Takeshi Ishihara , Satoshi Miyaoka , Koichi Kono , Donna J. Crowther , Patrick Brant
发明人： Takeshi Ishihara , Satoshi Miyaoka , Koichi Kono , Donna J. Crowther , Patrick Brant
IPC分类号： H01M2/16 , B29C47/00 , H01M10/26 , H01M4/64 , H01M10/02
CPC分类号： B01D71/26 , B01D71/76 , B29C47/00 , B32B27/32 , H01M2/14 , H01M2/16 , H01M2/164 , H01M2/1653
摘要： The invention relates to microporous membranes comprising polymer and having well-balanced permeability, shutdown temperature, and pin puncture strength. The invention also relates to methods for making such membranes, and the use of such membranes as battery separator film in, e.g., lithium ion secondary batteries. The membrane has a shutdown temperature
摘要翻译：本发明涉及包含聚合物并具有良好平衡渗透性，关闭温度和针穿刺强度的微孔膜。本发明还涉及制造这种膜的方法，以及在例如锂离子二次电池中使用这种膜作为电池隔膜。膜的关闭温度<130.5°C

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