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    • 85. 发明授权
    • 3-phenylpropionic acid derivatives
    • 3-苯基丙酸衍生物
    • US5013354A
    • 1991-05-07
    • US217167
    • 1988-07-11
    • Barbara SchwalgePeter PlathKarl EickenNorbert MeyerBruno Wuerzer
    • Barbara SchwalgePeter PlathKarl EickenNorbert MeyerBruno Wuerzer
    • A01N37/32A01N37/36A01N37/42A01N43/08A01N43/10A01N43/16A01N43/18A01N53/00C07D209/48
    • C07D209/48A01N37/32A01N37/36A01N37/42A01N43/08A01N43/10A01N43/16A01N43/18A01N53/00
    • 3-phenylpropionic acid derivatives of the general formula I ##STR1## where R.sup.1 is hydrogen or halogen, R.sup.2 is halogen, R.sup.3 is unsubstituted or halogen-, C.sub.1 -C.sub.4 -alkoxy- or C.sub.1 -C.sub.4 -alkylthio-substituted C.sub.2 -C.sub.6 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl-substituted C.sub.1 -C.sub.6 -alkyl, further C.sub.5 -C.sub.7 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl or, together with R.sup.4, a C.sub.2 -C.sub.4 -alkylene chain, R.sup.4 is hydrogen or unsubstituted or halogen-, C.sub.1 -C.sub.4 -alkoxy-, C.sub.1 -C.sub.4 -alkylthio- or C.sub.5 -C.sub.7 -cycloalkyl-substituted C.sub.1 -C.sub.6 -alkyl; C.sub.3 -C.sub.7 -cycloalkyl; unsubstituted or halogen-substituted C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl or halogen or R.sup.4, together with R.sup.5 and the carbon atom of this substituent, is C.sub.3 -C.sub.6 -cycloalkyl which may be interrupted by an oxygen or a sulfur atom, R.sup.5 is unsubstituted C.sub.1 -C.sub.6 -alkyl or halogen-, C.sub.1 -C.sub.4 -alkoxy- or C.sub. 1 -C.sub.4 -alkylthio-substituted C.sub.2 -C.sub.6 -alkyl; cyano or acyl (COR.sup.6) or alkoxycarbonyl (CO.sub.2 R.sup.7), R.sup.6 denoting C.sub.1 -C.sub.6 -alkyl or, together with R.sup.4, a C.sub.3 -C.sub.5 -alkylene chain and R.sup.7 denoting unsubstituted or halogen-, C.sub.1 -C.sub.4 -alkoxy- or C.sub.1 -C.sub.4 -alkylthio-substituted C.sub.2 -C.sub.6 -alkyl or unsubstituted or C.sub.5 -C.sub.7 -cycloalkyl-substituted C.sub.1 -C.sub.6 -alkyl, further C.sub.5 -C.sub.7 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, with the proviso that R.sup.1 and R.sup.4 do not simultaneously denote hydrogen when R.sup.5 is cyano or CO.sub.2 R.sup.7, processes for their manufacture, and their use as herbicides.
    • 其中R 1是氢或卤素,R 2是卤素,R 3是未取代的或卤素,C 1 -C 4 - 烷氧基 - 或C 1 -C 4 - 烷硫基取代的C 2 -C 6 - 烷基,C 5 -C 7 - 环烷基取代的C 1 -C 6 - 烷基,另外的C 5 -C 7 - 环烷基,C 3 -C 6 - 烯基或C 3 -C 6 - 炔基,或与R 4一起形成C 2 -C 4亚烷基链,R 4是氢 或未取代的或卤素,C 1 -C 4 - 烷氧基 - ,C 1 -C 4 - 烷硫基 - 或C 5 -C 7 - 环烷基取代的C 1 -C 6 - 烷基; C 3 -C 7 - 环烷基; 未取代的或卤素取代的C 3 -C 6 - 烯基或C 3 -C 6 - 炔基或卤素或R 4与R 5和该取代基的碳原子一起是可被氧或硫原子间隔的C 3 -C 6 - 环烷基, R 5是未取代的C 1 -C 6烷基或卤素,C 1 -C 4 - 烷氧基 - 或C 1 -C 4 - 烷硫基取代的C 2 -C 6 - 烷基; 氰基或酰基(COR 6)或烷氧基羰基(CO 2 R 7),R 6表示C 1 -C 6 - 烷基或与R 4一起为C 3 -C 5亚烷基链,R 7表示未取代或卤素,C 1 -C 4 - 烷氧基 - 或C 1 -C 4 - 烷硫基取代的C 2 -C 6 - 烷基或未取代的C 5 -C 7环烷基取代的C 1 -C 6烷基,另外C 5 -C 7 - 环烷基,C 3 -C 6 - 烯基或C 3 -C 6炔基,条件是R 1和 当R 5为氰基或CO 2 R 7时,R 4不同时表示氢,其制备方法及其作为除草剂的用途。
    • 90. 发明授权
    • Preparation of thiazolo (2,3-b) zuinazolones
    • 噻唑(2,3-b)唑胺酮的制备
    • US5030727A
    • 1991-07-09
    • US508495
    • 1990-04-12
    • Gerhard HamprechtGuenther SeyboldNorbert MeyerBruno Wuerzer
    • Gerhard HamprechtGuenther SeyboldNorbert MeyerBruno Wuerzer
    • A01N43/90C07D277/32C07D513/04
    • C07D513/04A01N43/90
    • The process of manufacturing thiazolo-(2,3-b)-quinoazolones of the formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are defined in the disclosure, wherein either a) an anthranilamide derivative of the formula II ##STR2## where R.sup.5 and R.sup.6 are hydrogen or C.sub.1 -C.sub.4 -alkyl, is reacted with a thiazole derivative of the formula III ##STR3## where X is fluorine, chlorine, bormine, alkylsulfonyl or arylsulfonyl, or b) for certain radicals R.sup.4' from the group R.sup.4 - a thiazolo-(2,3-b)-quinazolone of the general formula IV ##STR4## is reacted with a nucleophile R.sup.4' -H, where R.sup.4' is alkoxy, alkylthio or unsubstituted or halogen-, alkyl-, haloalkyl-, nitro- or alkoxy-substituted phenoxy or thiophenyl, or an alkali metal, alkaline earth metal or ammonium salt of an alcohol.
    • 制备式I的噻唑并(2,3-b) - 喹唑啉酮的方法,其中R 1,R 2,R 3和R 4在本公开内容中定义,其中a)式II的邻氨基苯甲酰胺衍生物 其中R 5和R 6是氢或C 1 -C 4 - 烷基与式III的噻唑衍生物(III)反应,其中X是氟,氯,甲酚,烷基磺酰基或芳基磺酰基,或b )通式IV(IV)的噻唑并(2,3-b) - 喹唑酮的一些基团R4'与亲核试剂R4'-H反应,其中R4'是烷氧基, 烷硫基或未取代的或卤素,烷基 - ,卤代烷基 - ,硝基 - 或烷氧基取代的苯氧基或噻吩基,或醇的碱金属,碱土金属或铵盐。