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    • 90. 发明授权
    • Deposition of metals on electrically conductive, polymeric carriers
    • 在导电的聚合物载体上沉积金属
    • US4560593A
    • 1985-12-24
    • US662546
    • 1984-10-19
    • Herbert NaarmannVolker MunchKlaus Penzien
    • Herbert NaarmannVolker MunchKlaus Penzien
    • C23C14/14C23C18/16C23C18/31C23C18/34C23C18/38C23C18/44C23C18/52C25D5/56H05K3/18C23C3/02
    • C23C18/52C25D5/56H05K3/181
    • A process for depositing metals onto electrically conductive, polymeric carriers, wherein a finely divided metal M having a standard potential E.sub.o of >-2 V is deposited, from a solution of a metal cation compound of the formula (I) ##EQU1## where M', L.sup.1, L.sup.2, L.sup.3, L.sup.4, l, m, n, o, and p are as defined in the claims, in an aprotic polar or non-polar solvent, onto a polymeric, electrically conductive carrier of the formula (II) ##EQU2## where M" is Li, Na, K, Rb or Cs,P is P=--CH--, --C.sub.6 H.sub.4 --, --C.sub.4 H.sub.2 S--, --C.sub.6 H.sub.4 S--, --C.sub.4 H.sub.2 O--, --C.sub.4 H.sub.2 NH-- --C.sub.6 H.sub.4 O-- or --C.sub.5 H.sub.3 N--y is from 0.001 to 0.6 andx is from 5 to 1,000, or onto a polymeric, electrically conductive carrier of the formula (III)[(P)(X).sub.y ].sub.x (III)whereP is one of the groups listed for formula (II), X is ClO.sub.4.sup..crclbar., AsF.sub.6.sup..crclbar., PF.sub.6.sup..crclbar., SbF.sub.6.sup..crclbar., BF.sub.4.sup..crclbar., HSO.sub.4.sup..crclbar., CF.sub.3 SO.sub.3.sup..crclbar. or Br.sup..crclbar.,y is from 0.001 to 0.6 andx is from 5 to 1,000, by reduction, preferably at from -100.degree. to +100.degree. C. The electrically conductive, polymeric systems can be employed in the electrical industry for the production of solar cells, for converting and fixing radiation, and for the production of electric and magnetic switches and electrical storage devices, and can also be used as heterogeneous catalysts and to provide an antistatic finish on plastics.
    • 一种将金属沉积在导电聚合物载体上的方法,其中从式(I)的化学式(I)的化学式(I)的化学物质中沉积出具有> -2V的标准电位Eo的细碎金属M(I )其中M',L1,L2,L3,L4,l,m,n,o和p如权利要求中所定义,在非质子传递极性或非极性溶剂中, (II)其中M“是Li,Na,K,Rb或Cs,P是P = -CH-,-C6H4-,-C4H2S-,-C6H4S-, -C 4 H 2 O-,-C 4 H 2 NH-C 6 H 4 O-或-C 5 H 3 N-y为0.001至0.6,x为5至1,000,或通式(III)[(P)(X)y)的聚合导电载体上 ] x(III)其中P是式(II)中所列的基团之一,X是ClO 4( - ),AsF 6( - ),PF 6( - ),SbF 6( - ),BF 4( - ),HSO 4 ,CF 3 SO 3( - )或Br( - ),y为0.001至0.6,x为5至1,000,通过还原,优选为-100至+ 100℃。可使用导电聚合体系 在电气工业中用于生产太阳能电池,用于转换和固定辐射,以及用于生产电磁开关和蓄电装置,并且还可以用作非均相催化剂并在塑料上提供抗静电涂饰。