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    • 85. 发明授权
    • Polymer compositions having improved constancy of properties
    • 具有改善的性能恒定性的聚合物组合物
    • US06767962B2
    • 2004-07-27
    • US10206638
    • 2002-07-26
    • Herbert EichenauerVera BuchholzEckhard Wenz
    • Herbert EichenauerVera BuchholzEckhard Wenz
    • C08L5100
    • C08L51/04C08F279/02C08F279/04C08F285/00C08L25/12C08L35/00C08L55/02C08L2666/24C08L51/00C08L2666/02
    • A thermoplastic molding composition that contains a plurality of graft rubbers is disclosed. A first graft rubber is a product of emulsion polymerization of a mixture containing styrene and acrylonitrile in the presence of butadiene polymer latex (A) having an average particle diameter (d50) of 80 to 220 nm. An additional graft rubber is a product of emulsion polymerization of a mixture containing styrene and acrylonitrile in the presence of butadiene polymer latex (B) having an average particle diameter (d50) of 350 to 650 nm. The butadiene polymer latex (A) is the product of seed polymerization in which seed is butadiene polymer latex having a median particle diameter of 10 to 100 nm, and the butadiene polymer latex (B) is the product of agglomeration in which butadiene polymer latex (A) is the starting latex.
    • 公开了一种含有多个接枝橡胶的热塑性模塑组合物。 在平均粒径(d50)为80〜220nm的丁二烯聚合物胶乳(A)的存在下,第一接枝橡胶是含有苯乙烯和丙烯腈的混合物的乳液聚合的产物。 在平均粒径(d50)为350〜650nm的丁二烯聚合物胶乳(B)的存在下,另外的接枝橡胶是含有苯乙烯和丙烯腈的混合物的乳液聚合的产物。 丁二烯聚合物胶乳(A)是种子聚合的产物,其中种子是中值粒径为10-100nm的丁二烯聚合物胶乳,丁二烯聚合物胶乳(B)是其中丁二烯聚合物胶乳( A)是起始胶乳。
    • 86. 发明授权
    • ABS compositions having improved combinations of properties
    • 具有改进的性能组合的ABS组合物
    • US06727319B2
    • 2004-04-27
    • US10242991
    • 2002-09-13
    • Herbert Eichenauer
    • Herbert Eichenauer
    • C08L3300
    • C08L51/04C08L2666/24
    • A thermoplastic molding composition having an improved profile of properties is disclosed. The composition contains A) a graft rubber that is a product of free-radical emulsion polymerization of vinyl monomers in the presence of rubber a) that is present in latex form and having a glass transition temperature below 0° C., using at least one peroxydisulfate compound as an initiator, and B) a graft rubber that is a product of free-radical emulsion polymerization of vinyl monomers in the presence of at least one rubber b) that is present in latex form and having a glass transition temperature below 0° C., using at least one redox system as an initiator, and C) at least one graft polymer, that is a product of solution, bulk or suspension polymerization of a grafted phase that contains a member selected from the group consisting of styrene and acrylonitrile in a weight ratio of 90:10 to 50:50 therebetween, in the presence of a rubber, and wherein the weight ratio of introduced graft monomers to introduced rubber is 50:50 to 97:3.
    • 公开了具有改进的特性轮廓的热塑性模塑组合物。 组合物包含A)在橡胶存在下乙烯基单体的自由基乳液聚合的产物的接枝橡胶a),其以胶乳形式存在并且玻璃化转变温度低于0℃,使用至少一种 过氧化二硫酸酯化合物作为引发剂,和B)在至少一种橡胶b)存在下乙烯基单体的自由基乳液聚合的产物的接枝橡胶,b)以胶乳形式存在并且玻璃化转变温度低于0° 使用至少一种氧化还原体系作为引发剂,和C)至少一种接枝聚合物,其是接枝相的溶液,本体或悬浮聚合的产物,其含有选自苯乙烯和丙烯腈的成员 在橡胶存在下,其重量比为90:10至50:50,其中引入的接枝单体与引入的橡胶的重量比为50:50至97:3。
    • 87. 发明授权
    • Thermoplastic molding compositions containing additive mixtures
    • 含有添加剂混合物的热塑性成型组合物
    • US06656889B2
    • 2003-12-02
    • US09955785
    • 2001-09-18
    • Herbert Eichenauer
    • Herbert Eichenauer
    • C08K500
    • C08L25/04C08K5/01C08K5/098C08K5/20C08K5/372C08L25/12C08L51/04C08L55/02C08L2666/24C08L2666/04
    • A thermoplastic molding composition comprising A) a thermopolastic polymer, e.g., a copolymer of styrene and acyrlonitrile, B) a graft copolymer, e.g., a graft copolymer of styrene, acrylonitrile and polybutadiene, and C) an additive mixture is described. The additive mixture C) comprises a combination of at least three components selected from components (I), (II), (III) and (IV). Component (I) contains carboxylic acid metal salt groups, e.g., magnesium stearate. Component (II) contains both carboxylic acid ester linkages and thio linkages, e.g., esters of &bgr;-thiodipropionic acid with monhydric alcohols. Component (III) contains amide linkages, e.g., ethylenediamine bisstearyl amide. Component (IV) is a compound that is different than components (I)-(III), e.g., a low molecular weight styrene/acrylonitrile copolymer. Also described are molded articles prepared from the thermoplastic molding composition of the present invention.
    • 一种热塑性模塑组合物,其包含A)热弹性聚合物,例如苯乙烯和丙烯腈的共聚物,B)接枝共聚物,例如苯乙烯,丙烯腈和聚丁二烯的接枝共聚物,和C)添加剂混合物。 添加剂混合物C)包含选自组分(I),(II),(III)和(IV)的至少三种组分的组合。 组分(I)含有羧酸金属盐基团,例如硬脂酸镁。 组分(II)含有羧酸酯键和硫键,例如β-硫代二丙酸与一元醇的酯。 组分(III)含有酰胺键,例如乙二胺双硬脂酰胺。 组分(IV)是不同于组分(I) - (III)的化合物,例如低分子量苯乙烯/丙烯腈共聚物。 还描述了由本发明的热塑性模塑组合物制备的模塑制品。