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81. 发明授权

US5648549A Process for the preparation of secondary arylphosphines 失效
标题翻译：二芳基膦的制备方法
公开(公告)号：US5648549A
公开(公告)日：1997-07-15
申请号：US683532
申请日：1996-07-15
申请人： Hans-Jerg Kleiner
发明人： Hans-Jerg Kleiner
IPC分类号： B01J27/125 , B01J27/138 , C07B61/00 , C07F9/50
CPC分类号： C07F9/505
摘要： The invention relates to a process for the preparation of secondary phosphines of the formula (I) ##STR1## in which R.sup.1 to R.sup.6 independently of one another are hydrogen, halogen, (C.sub.1 -C.sub.6)-alkyl or (C.sub.1 -C.sub.6)-alkoxy, wherein secondary phosphine oxides of the formula (II) ##STR2## are reacted with Lewis acids as catalysts, at elevated temperature, and the secondary phosphines of the formula (I) formed are distilled off under reduced pressure.
摘要翻译：本发明涉及一种制备式（I）的次膦的方法，它们是氢，卤素，（C 1 -C 6） - 烷基或（C 1 -C 6） - 烷氧基，其中式（II）的仲氧化膦）在升高的温度下，将（II）与路易斯酸作为催化剂反应，形成的式（I）的次膦在减压下蒸馏除去。

82. 发明授权

US5600006A Bis(diarylalkyl)phosphines 失效
标题翻译：双（二芳基烷基）膦
公开(公告)号：US5600006A
公开(公告)日：1997-02-04
申请号：US337959
申请日：1994-11-10
申请人： Dieter Regnat , Hans-Jerg Kleiner
发明人： Dieter Regnat , Hans-Jerg Kleiner
IPC分类号： C07F9/50 , C07F9/53 , C07F9/02
CPC分类号： C07F9/5027 , C07F9/509
摘要： The invention relates to novel 2,2'-bis [bis(aryl)phosphinomethyl]-1,1'-binaphthyls of the formula ##STR1## in which Ar.sup.2 is a phenyl radical, R' is an alkyl radical having 1 to 4 carbon atoms, CF.sub.3, fluorine, chlorine or bromine, and n is 1 or 2.
摘要翻译：本发明涉及具有1-4个碳原子的烷基，CF 3，氟，氯或溴的新的2,2'-双[双（芳基）膦基甲基] -1,1'-联萘，n为1 或2。

83. 发明授权

US5510554A Process for preparing 1,1'-binaphthyls 失效
标题翻译：制备1,1'-联萘的方法
公开(公告)号：US5510554A
公开(公告)日：1996-04-23
申请号：US337983
申请日：1994-11-14
申请人： Dieter Regnat , Hans-Jerg Kleiner
发明人： Dieter Regnat , Hans-Jerg Kleiner
IPC分类号： B01J31/24 , C07B61/00 , C07C1/32 , C07C15/58 , C07C41/18 , C07C43/20 , C07C209/68 , C07C211/57 , C07C2/84
CPC分类号： C07C209/68 , C07C1/326
摘要： In the preparation of 1,1'-binaphthyls substituted in the 2,2'-positions (and optionally substituted in one or more of positions 3 to 7 and/or 3' to 7'), a 1-halo-2-substituted naphthalene is reacted with a 2-substituted-1-naphthyl-magnesium halide in the presence of a catalyst. The catalyst comprises palladium and a phosphine ligand. Typical phosphine ligands include triphenylphosphine, 1,4-bis(diphenylphosphino)butane, 2,2'-bis(diphenylphosphinomethoxy)-1,1'-binaphthyl, and tetrakis(triphonylphosphine).
摘要翻译：在2,2'位取代的1,1'-联萘的制备（并且任选在一个或多个3至7和/或3'至7'中被取代），1-卤代-2-取代在催化剂存在下，萘与2-取代-1-萘基卤化镁反应。催化剂包括钯和膦配体。典型的膦配体包括三苯基膦，1,4-双（二苯基膦基）丁烷，2,2'-双（二苯基膦基甲氧基）-1,1'-联萘和四（三辛基膦）。

84. 发明授权

US5498797A Bis(phosphinozlkoxy)biaryl compounds and a process for their preparation 失效
标题翻译：双（膦酰基烷氧基）联芳基化合物及其制备方法
公开(公告)号：US5498797A
公开(公告)日：1996-03-12
申请号：US338033
申请日：1994-11-14
申请人： Dieter Regnat , Hans-Jerg Kleiner
发明人： Dieter Regnat , Hans-Jerg Kleiner
IPC分类号： C07F9/50 , C07F9/53 , C07F9/02
CPC分类号： C07F9/5004 , C07F9/5304
摘要： The present invention relates to phosphorus compounds of the formula ##STR1## in the (RS), (R) and (S) forms, in which Ar.sup.1 --Ar.sup.1 is a bipheny1 radical, 1-phenylnaphthyl radical or 1,1'-binaphthyl radical, each R', if present, independently of the others, is F, an alkyl or alkoxy radical each having 1 to 8 carbon atoms, m is an integer from 0 to 4, k is an integer from I to 4, Ar.sup.2 is a phenyl radical, each R", if present, is, independently of the others, F, Cl, CF.sub.3, SO.sub.3 H, SO.sub.3, SO.sub.3 Me (Me is Li, Na, K), a dialkylamino radical having 2 to 8 carbon atoms, an alkyl or alkoxy radical each having 1 to 8 carbon atoms and n is an integer from 0 to 5, and to a process for their preparation.
摘要翻译：本发明涉及（RS），（R）和（S）形式的式（I）的磷化合物，其中Ar1-Ar1是联苯基，1-苯基萘基或1,1' - 联萘基，如果存在，每个R'独立地为F，每个具有1至8个碳原子的烷基或烷氧基，m为0至4的整数，k为I至4的整数， Ar 2是苯基，如果存在，每个R“独立地是F，Cl，CF 3，SO 3 H，SO 3，SO 3 Me（Me是Li，Na，K），具有2至8个碳的二烷基氨基原子，各自具有1至8个碳原子的烷基或烷氧基，n为0至5的整数，以及其制备方法。

85. 发明授权

US5281640A Diarylphosphinous acid aryl esters, a process for their preparation and their use for stabilizing plastics 失效
标题翻译：二芳基次膦酸芳基酯，其制备方法及其用于稳定塑料的用途
公开(公告)号：US5281640A
公开(公告)日：1994-01-25
申请号：US920112
申请日：1992-07-24
申请人： Dieter Regnat , Manfred Bohshar , Hans-Jerg Kleiner , Gerhard Pfahler
发明人： Dieter Regnat , Manfred Bohshar , Hans-Jerg Kleiner , Gerhard Pfahler
IPC分类号： C07F9/46 , C08K5/09 , C08K5/10 , C08K5/53 , C08K5/5377 , C08L23/00
CPC分类号： C07F9/46 , C08K5/5377
摘要： Diarylphosphinous acid aryl esters are made by the disclosed process. These compounds are useful for stabilizing plastics, in particular polymerization plastics, and hence can be incorporated into a plastic molding composition.
摘要翻译：二芳基次膦酸芳基酯通过公开的方法制备。这些化合物可用于稳定塑料，特别是聚合塑料，因此可以掺入塑料模塑组合物中。

86. 发明授权

US5081078A Sinterable ceramic powder, process for its preparation, silicon nitride ceramic manufactured therefrom, process for its manufacture and its use 失效
标题翻译：可烧结陶瓷粉末，其制备方法，其制造的硅酸盐陶瓷，其制造方法及其用途
公开(公告)号：US5081078A
公开(公告)日：1992-01-14
申请号：US443881
申请日：1989-11-30
申请人： Marcellus Peuckert , Martin Bruck , Thomas Gerdau , Hans-Jerg Kleiner , Tilo Vaahs , Fritz Aldinger
发明人： Marcellus Peuckert , Martin Bruck , Thomas Gerdau , Hans-Jerg Kleiner , Tilo Vaahs , Fritz Aldinger
IPC分类号： C01B21/068 , C04B35/589 , C04B35/593 , C08G77/48 , C08G77/62
CPC分类号： C04B35/589 , C04B35/5935
摘要： The invention relates to a novel sinterable ceramic powder, to its preparation, to its processing to form silicon nitride ceramic and to said material itself and its use. The sinterable ceramic powder is prepared by dissolving the polysilazane of formula (I)[CH.sub.3 SiHNH].sub.n [CH.sub.3 SiN].sub.nwhere n is about 10 to 12, in an organic solvent, suspending a pulverulent sinter aid in this solution and then evaporating the solvent and pyrolyzing the residue in an inert gas atmosphere at 500.degree. to 1600.degree. C.The resulting ceramic powder can be used to form a shaped article and then to manufacture silicon nitride ceramic by sintering. It is also possible, however, to form a shaped article from the as yet unpyrolyzed residue obtained after evaporation of the solvent, and then to pyrolyze and sinter said article.The ceramic obtained can be used to manufacture components subject to high mechanical, thermal and corrosive stress.
摘要翻译：本发明涉及一种新型的可烧结陶瓷粉末，用于其制备，以形成氮化硅陶瓷的加工以及所述材料本身及其用途。可烧结陶瓷粉末是通过在有机溶剂中溶解式（I）[CH3SiHNH] n [CH3SiN] n的聚硅氮烷[N，N-二甲基甲酰胺] n [CH3SiN] n，其中n为约10〜12，将粉状烧结助剂悬浮在该溶液中，然后蒸发溶剂，在惰性气体气氛中在500〜1600℃下热解残渣。得到的陶瓷粉末可用于形成成形制品，然后通过烧结制造氮化硅陶瓷。然而，也可以从蒸发溶剂后获得的仍然未裂解的残余物形成成型制品，然后热解并烧结所述制品。获得的陶瓷可用于制造受到高机械，热和腐蚀应力的部件。

87. 发明授权

US5075266A Process for the production of ceramic material containing silicon nitride from polymeric hydridochlorosilazanes 失效
标题翻译：从聚合氯化石蜡生产含有硝酸硅的陶瓷材料的工艺
公开(公告)号：US5075266A
公开(公告)日：1991-12-24
申请号：US381501
申请日：1989-07-18
申请人： Thomas Gerdau , Hans-Jerg Kleiner , Martin Bruck , Marcellus Peuckert , Fritz Aldinger
发明人： Thomas Gerdau , Hans-Jerg Kleiner , Martin Bruck , Marcellus Peuckert , Fritz Aldinger
IPC分类号： C01B21/068 , C04B35/589 , C08G77/48 , C08G77/62 , C08L83/16 , D01F9/10
CPC分类号： C08L83/16 , C04B35/589
摘要： The invention relates to a process for the production of ceramic material containing silicon nitride, such as fibers, coatings or moldings. In this process, polymeric hydridochlorosilazanes are rendered infusible at a temperature below their softening point by treatment with gaseous NH.sub.3 and are then pyrolyzed in an atmosphere containing NH.sub.3 at 700.degree. to 1500.degree. C. Fibers, coatings or moldings containing silicon nitride are produced by first producing appropriate structures from a melt of the polymeric hydridochlorosilazane and then rendering them infusible and pyrolyzing them.
摘要翻译：本发明涉及生产含有氮化硅的陶瓷材料的方法，例如纤维，涂层或模制品。在此过程中，聚合氯化硅烷可以通过用气态NH 3处理而在低于其软化点的温度下熔化，然后在含有氮气的气氛中在700°至1500°C下热解。含有氮化硅的纤维，涂层或模制品首先通过从聚合氯代硅氮烷的熔体中产生适当的结构，然后使它们不熔融并热解。

88. 发明授权

US5066623A Polymeric hydridosilazanes and processes for their preparation, and their use 失效
标题翻译：聚合氢氧化物及其制备方法及其使用
公开(公告)号：US5066623A
公开(公告)日：1991-11-19
申请号：US491534
申请日：1990-03-12
申请人： Thomas Gerdau , Hans-Jerg Kleiner , Marcellus Peuckert , Martin Bruck , Fritz Aldinger
发明人： Thomas Gerdau , Hans-Jerg Kleiner , Marcellus Peuckert , Martin Bruck , Fritz Aldinger
IPC分类号： C04B35/589 , C08G77/48 , C08G77/62
CPC分类号： C04B35/589 , C08G77/62
摘要： The invention relates to novel polymeric hydridosilazanes, processes for their preparation and their use for the preparation of ceramic material containing silicon nitride. To prepare the polymeric hydridosilazanes, polymeric hydridochlorosilazanes are reacted with NH.sub.3. To prepare the ceramic material containing silicon nitride, the polymeric hydridosilazanes are then pyrolyzed.

89. 发明授权

US5043474A Optically active rhodium complexes of 3,4-bis(diarylphosphino)pyrrolidines and their use for the preparation of phosphinothricin by asymmetric hydrogenation 失效
标题翻译： 3,4-双（二芳基膦基）吡咯烷的光学活性铑络合物及其用于通过不对称氢化制备膦丝菌素
公开(公告)号：US5043474A
公开(公告)日：1991-08-27
申请号：US466217
申请日：1990-01-17
申请人： Wolf-Dieter Muller , Hans-Jerg Kleiner
发明人： Wolf-Dieter Muller , Hans-Jerg Kleiner
IPC分类号： C07F9/30 , C07F9/572 , C07F15/00 , C08G18/10 , C08G18/28 , C08G18/83 , C08G65/32 , C08G65/329
CPC分类号： C08G65/329 , C07F15/008 , C07F9/301 , C07F9/5726 , C08G18/10 , C08G18/288
摘要： The invention relates to rhodium complexes of the formula[A--O--(CH.sub.2 CH.sub.2 O).sub.n --A].sup.2+ 2X.sup.- (Ia)and[A--O--(CH.sub.2 CH.sub.2 O).sub.m --CH.sub.3 ].sup.+ X.sup.-(Ib)in whichn=5-1,000,m=5-250,X.sup.- denotes a tetrafluoroborate, hexafluorophosphate or per-chlorate anion,A denotes a radical of the formula ##STR1## (en).sub.2 denotes two molecules of a monoolefin or one molecule of a diolefinAr denotes phenyl or phenyl which is substituted by one or two alkyl groups having 1 or 2 carbon atoms andR.sup.1 denotes an arylene or alkylene bridge,and their use for the preparation of L-phosphinothricin and its derivatives by enantioselective catalytic hydrogenation of 2,3-dehydrophosphinothricin (derivatives).

90. 发明授权

US4960919A Process for the preparation of alkyl alkenylphosphinates 失效
标题翻译：烯基亚磷酸烷基酯的制备方法
公开(公告)号：US4960919A
公开(公告)日：1990-10-02
申请号：US311527
申请日：1989-02-16
申请人： Hans-Jerg Kleiner , Gunter Roscher
发明人： Hans-Jerg Kleiner , Gunter Roscher
IPC分类号： C07B61/00 , B01J31/02 , C07F9/32
CPC分类号： C07F9/3217
摘要： A process for the preparation of alkyl esters of alkenylphosphinic acid, having the general formula I ##STR1## wherein R.sup.1 represents H or CH.sub.3, R.sup.2 alkyl having from 1 to 4 carbon atoms or phenyl and R.sup.3 alkyl having from 1 to 8 carbon atoms, which comprises cleaving an alkyl ester of 2-acetoxyethyl phosphinic acid, having the general formula II ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 have the meaning indicated above, in contact with a liquid catalytically acting medium and at a partial pressure of the total of the components of the reaction system in the range of from 1 to 500 mbar, and drawing off the resulting alkyl esters of alkenyl phosphinic acid and other volatile reaction products.The invention also relates to compounds of the formula I ##STR3## wherein (a) R.sup.1 represents H, R.sup.2 represents alkyl having from 1 to 4 carbon atoms or phenyl and R.sup.3 represents isobutyl or alkyl having from 5 to 8 carbon atoms, or(b) R.sup.1 represents CH.sub.3, R.sup.2 represents alkyl having from 1 to 4 carbon atoms or phenyl and R.sup.3 represents alkyl having from 1 to 8 carbon atoms.
摘要翻译：制备具有通式I（I）的烯基次膦酸的烷基酯的方法，其中R 1表示H或CH 3，具有1至4个碳原子的R 2烷基或具有1至8个碳的R 3烷基原子，其包括裂解2-乙酰氧基乙基次膦酸的烷基酯，具有通式II（II）其中R1，R2和R3具有上述含义，与液体催化作用介质接触，并且部分地将反应体系的组分的总量的压力在1至500毫巴范围内，并抽出所得的链烯基次膦酸和其它挥发性反应产物的烷基酯。本发明还涉及式I的化合物（I），其中（a）R 1表示H，R 2表示具有1至4个碳原子的烷基或苯基，R 3表示异丁基或具有5至8个碳原子的烷基，或（b）R 1表示CH 3，R 2表示具有1至4个碳原子的烷基或苯基，R 3表示具有1至8个碳原子的烷基。

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